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Chinese Journal of Materials Research  2015, Vol. 29 Issue (10): 751-756    DOI: 10.11901/1005.3093.2015.023
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Electric Conductivity and Corrosion Resistance of Amorphous Carbon Films Prepared by Direct Current Magnetron Sputtering on 304 Stainless Steel
Haifeng ZHANG1,2,Dong ZHANG2,Xiaowei LI2,Congda LU1,Peiling KE2,Aiying WANG2,**()
1. College of mechanical engineering, Zhejiang University of Technology, Hangzhou 310004, China
2. Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
Cite this article: 

Haifeng ZHANG,Dong ZHANG,Xiaowei LI,Congda LU,Peiling KE,Aiying WANG. Electric Conductivity and Corrosion Resistance of Amorphous Carbon Films Prepared by Direct Current Magnetron Sputtering on 304 Stainless Steel. Chinese Journal of Materials Research, 2015, 29(10): 751-756.

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Abstract  

The conductive amorphous carbon films were deposited on the 304SS by conventional direct current magnetron sputtering. The effect of substrate bias on the microstructure and property of amorphous carbon films were mainly investigated. The results show that the electrical conductivity and corrosion resistance are improved significantly for the carbon films coated stainless steel in comparison to the untreated ones. Specifically, when the substrate bias was -200 V the contact resistance was about 16.65 mΩcm2, which may be ascribed to the highest fraction of sp2 bonds under the normal compacting force of the fuel cells at 1.5 MPa. The corrosion potential of the carbon films coated stainless steel significantly increased in the simulated PEM fuel cells environment, while the corrosion current density obviously decreased, especially when the bias was -200 V the carbon film performs the best corrosion resistance, which may be attributed to its best compactness, for this case the corrosion current density is 1.22×10-8 A/cm2 and the corrosion potential is 0.25 V.

Key words:  inorganic non-metallic materials      PEM fuel cells      amorphous carbon films      magnetron sputtering      contact resistance      corrosion resistance     
Received:  14 January 2015     
Fund: *Supported by National Nature Science Foundation of China Nos. 51175472 & 51522106, Ningbo Municipal Natural Science Foundation No. 2015A610083, and Ningbo Municipal Key Technologies R&D Program No. 2014B10032.

URL: 

https://www.cjmr.org/EN/10.11901/1005.3093.2015.023     OR     https://www.cjmr.org/EN/Y2015/V29/I10/751

Fig.1  Schematic illustration of the test for interfacial contact resistance
Fig.2  SEM images of the carbon films deposited under different biases
Fig.3  AFM images of amorphous carbon films deposited under different biases
Fig.4  Raman spectra (a) and fitted G peak position, ID/IG, and FWHM (G) (b) of the carbon films under different biases
Fig.5  Electrical resistivity of carbon films under different biases and graphite
Fig.6  Contact resistance of SS304 and amorphous carbon films with Toray carbon paper under different compaction force
Fig.7  Polarization curves of SS304 and amorphous carbon films under different biases in the simulated corrosion environment
Fig.8  Schematic illustration of the corrosion mechanism of the carbon films coated on SS304 substrate
Fig.9  Contact angle values of SS304 and amorphous carbon films with water
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