Crystallization Process of Zr55Al10Ni5Cu30 Bulk Metallic Glasses with Different Microstructure

doi:10.11901/1005.3093.2014.069

Chinese Journal of Materials Research

2014, Vol. 28

Issue (6): 427-432 DOI: 10.11901/1005.3093.2014.069

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Crystallization Process of Zr₅₅Al₁₀Ni₅Cu₃₀ Bulk Metallic Glasses with Different Microstructure

Honghong YAN,Yong HU(

),Yongtang LI,Zhijie YAN,Dawen ZHAO,Yina GUO

Shanxi Key Laboratory of Metallic Materials Forming Theory and Technology, School of Materials Science and Engineering, Taiyuan University of Science and Technology, Taiyuan 030024

Cite this article:

Honghong YAN,Yong HU,Yongtang LI,Zhijie YAN,Dawen ZHAO,Yina GUO. Crystallization Process of Zr₅₅Al₁₀Ni₅Cu₃₀ Bulk Metallic Glasses with Different Microstructure. Chinese Journal of Materials Research, 2014, 28(6): 427-432.

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Abstract

The crystallization process of the as-cast and as-rolled Zr₅₅Al₁₀Ni₅Cu₃₀ bulk metallic glasses, which have similar crystallization fraction and crystallization activation energy but different microstructure, was inverstigated by means of differential scanning calorimeter (DSC) with isothermal and continuous heating. The results show that the two metallic glasses exhibit similar crystallization rate in the initial stage of crystallization (until 30 min), while the crystallization rate of the as-rolled one is faster than that of the as-cast one in the later stage of crystallization (after 30 min); however, according to JMA equation, the crystallization activation energy deduced from crystallization onset temperature T_x and crystallization peak temperature T_p can not give a comprehensive explanation on the thermal stability of metallic glasses. In addition, the weakening of atomic binding forces and strengthening of short range order in the shear bands may decrease the thermal stability and therewith enhance the crystallization rate of the as-rolled Zr₅₅Al₁₀Ni₅Cu₃₀ metallic glass.

Key words: metallic materials metallic glass crystallization process microstructure

Received: 11 February 2014

Fund: *Supported by National Natural Science Foundation of China No. 51204118, Program for the Top Young Academic Leaders of Higher Learning Institutions of Shanxi (2013), Research Project Supported by Shanxi Scholarship Council of China No. 2013-094, Natural Science Foundation of Shanxi Province Nos. 2011021020-1 and 2012021018-3.

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	Honghong YAN
	Yong HU
	Yongtang LI
	Zhijie YAN
	Dawen ZHAO
	Yina GUO

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https://www.cjmr.org/EN/10.11901/1005.3093.2014.069 OR https://www.cjmr.org/EN/Y2014/V28/I6/427

Fig.1 XRD patterns of the as-cast Zr₅₅Al₁₀Ni₅Cu₃₀ specimen and that rolled up to e = 95%

Fig.2 HRTEM images of the as-cast Zr₅₅Al₁₀Ni₅Cu₃₀ specimen (a) and that rolled up to e = 95% (b)

Fig.3 DSC curves of the as-cast Zr₅₅Al₁₀Ni₅Cu₃₀ specimen and that rolled up to e = 95% at a heating rate of 20 K/min (a) whole curves, (b) magnified curves

Table 1 Thermodynamic parameters of the as-cast Zr₅₅Al₁₀Ni₅Cu₃₀ specimen and that rolled up to e = 95% at a heating rate of 20 K/min^[13]

Fig.4 DSC curves of the as-cast Zr₅₅Al₁₀Ni₅Cu₃₀ specimen (a) and that rolled up to e = 95% (b) after annealing at 715 K for various time, and the heating rate is 20 K/min and the time dependence of the enthalpy of the exothermic event for the both specimens (c)

Table 2 Crystallization fractions of the as-cast Zr₅₅Al₁₀Ni₅Cu₃₀ specimen and that rolled up to e = 95% after annealed at 715 K with different time

1	W. H. Wang,Metallic glasses family traits, Nature Materials, 11, 275(2012)
2	Y. Chen, M. Q. Jiang, L. H. Dai,Collective evolution dynamics of multiple shear bands in bulk metallic glasses, International Journal of Plasticity, 50, 18(2013)
3	NIE Yingshi,LI Wen, LI Dengke, ZHANG Bo, ZHU Zhengwang, Microstructure and properties of Fe-based amorphous alloy coating deposited by electro-spark deposition process, Chinese Journal of Materials Research, 27(1), 75(2013)
3	(聂英石, 李文, 李登科, 张波, 朱正旺, 电火花沉积Fe48Cr16Mo15C17B4非晶合金涂层的微观组织和性能, 材料研究学报, 27(1), 75(2013))
4	L. Hu, F. Ye,Crystallization kinetics of Ca65Mg15Zn20 bulk metallic glass, Journal of Alloys and Compounds, 557, 160(2013)
5	J. C. Qiao, J. M. Pelletier, H. C. Kou, X. Zhou,Modification of atomic mobility in a Ti-based bulk metallic glass by plastic deformation or thermal annealing, Intermetallics, 28, 128(2012)
6	Q. P. Cao, J. F. Li, J. Z. Jiang, Y. H. Zhou,Microstructure and stored energy evolutions during rolling of Cu60Zr20Ti20 bulk metallic glass, Journal of Non-Crystalline Solids, 354, 5353(2008)
7	H. H. Yan, Y. Hu, Z. J. Yan, X. H. Zheng, Y. T. Li,Microstructure Evolution of Zr50Cu18Ni17Al10Ti5 Bulk Metallic Glass during Cold-rolling, Journal of Materials Science and Technology, 28(8), 756(2012)
8	A. Inoue, T. Zhang,Fabrication of bulk glassy Zr55Al10Ni5Cu30 alloy of 30 mm in diameter by a suction casting method, Materials Transactions, JIM, 37(2), 185(1996)
9	ZHANG Qingsheng,DENG Yufu, HE Lianlong, ZHANG Haifeng, DING Bingzhe, HU Zhuangqi, Isothermal nanocrystallization of Zr55Al10Ni5Cu30 bulk amorphous alloy near the glass transition temperature, Acta Metallurgica Sinica, 39(3), 301(2003)
9	(张庆生, 邓玉福, 贺连龙, 张海峰, 丁炳哲, 胡壮麒, Zr55Al10Ni5Cu30块体非晶合金靠近玻璃转变点的等温纳米晶化, 金属学报, 39(3), 301(2003))
10	M. F. De Oliveira, C. S. Kiminami, W. J. B. Filho,Effect of oxide particles on the crystallisation behaviour of Zr55Al10Ni5Cu30 alloy, Materials Science and Engineering A, 304, 665(2001)
11	J. Zhang, K. Q. Qiu, A. M. Wang, H. F. Zhang, M. X. Quan, Z. Q. Hu, Pressure-induced nanocrystallization of Zr55Al10Ni5Cu30 bulk metallic glass, Journal of Materials Research, 17(11), 2935(2002)
12	J. Zhang, H. F. Zhang, M. X. Quan, Z. Q. Hu, Effect of pressure on crystallization process of Zr55Al10Ni5Cu30 bulk metallic glass, Materials Letters, 58, 1379(2004)
13	Y. Hu, J. F. Li, P. N. Zhang, Y. H. Zhou,Effect of cold rolling on glass transition of Zr55Al10Ni5Cu30 bulk metallic glass, Transactions of Nonferrous Metals Society of China, 20, 78(2010)
14	HU Qiao,LIN Xin, YANG Gaolin, HUANG Weidong, LI Jinfu, Crystallization behavior of Zr55Al10Ni5Cu30 amorphous alloys with different morphologies and thermal history conditions, Acta Metallurgica Sinica, 48(12), 1467(2012)
14	(胡桥, 林鑫, 杨高林, 黄卫东, 李金富, 不同形态和热历史条件下Zr55Al10Ni5Cu30非晶合金的晶化行为, 金属学报, 48(12), 1467(2012))
15	Y. Hu, J. F. Li, P.N. Zhang, Y. H. Zhou,Crystallization behavior of Zr55Al10Cu30Ni5 bulk metallic glass rolled at room temperature, Journal of Materials Science and Technology, 26(2), 177(2010)
16	Z. J. Yan, J. F. Li, H. H. Wang, S. R. He, Y. H. Zhou,Effect of the repeated melting of mother ingot on the stability of icosahedralphase precipitated from Zr-Al-Ni-Cu-Ag glass, Science in China Series E: Technological Sciences, 46(6), 639(2003)
17	Q. P. Cao, J. F. Li, Y. H. Zhou, A. Horsewell, J. Z. Jiang,Effect of rolling deformation on the microstructure of bulk Cu60Zr20Ti20 metallic glass and its crystallization, Acta Materialia, 54, 4373(2006)
18	HU Yong,Microstructure and mechanical behaviors of Zr55Al10Ni5Cu30 bulk metallic glass, Dissertation for the Degree of Ph.D, Shanghai Jiao Tong University(2010)
18	(胡勇,Zr55Al10Ni5Cu30块体非晶合金的微观结构与力学行为, 博士学位论文, 上海交通大学(2010))
19	A. T. W. Kempen, F. Sommer, E. J. Mittemeijer,Determination and interpretation of isothermal and non-isothermal transformation kinetics; The effective activation energies in terms of nucleation and growth, Journal of Materials Science, 37, 1321(2002)
20	L. Liu, Z. F. Wu, J. Zhang,Crystallization kinetics of Zr55Cu30Al10Ni5 bulk amorphous alloy, Journal of Alloys and Compounds, 339, 90(2002)
21	W. H. Wang, Y. X. Zhuang, M. X. Pan, Y. S. Yao, Glass transition behavior, crystallization kinetics, and microstructure change of Zr41Ti14Cu12.5Ni10Be22.5 bulk metallic glass under high pressure, Journal of Applied Physics, 88(7), 3914(2000)
22	J. W. Liu, Q. P. Cao, L. Y. Chen, X. D. Wang, J. Z. Jiang,Shear band evolution and hardness change in cold-rolled bulk metallic glasses, Acta Materialia, 58, 4827(2010)

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