WO3/Pt和NiO电极电致变色器件的性能

doi:10.11901/1005.3093.2023.464

材料研究学报

2024, Vol. 38

Issue (8): 569-575 DOI: 10.11901/1005.3093.2023.464

研究论文

本期目录 | 过刊浏览

WO₃/Pt和NiO电极电致变色器件的性能

郝子恒¹, 郑刘梦晗², 张妮¹, 蒋恩桐², 王国政²(

), 杨继凯²(

)

^1.微光夜视技术重点实验室西安 710065
^2.长春理工大学物理学院长春 130022

Color-changing Performance of Electrochromic Devices Based on WO₃/Pt-NiO Electrodes

HAO Ziheng¹, ZHENG Liumenghan², ZHANG Ni¹, JIANG Entong², WANG Guozheng²(

), YANG Jikai²(

)

^1.Science and Technology on Low-Light-Level Night Vision Laboratory, Xi'an 710065, China
^2.School of Physics, Changchun University of Science and Technology, Changchun 130022, China

引用本文:

郝子恒, 郑刘梦晗, 张妮, 蒋恩桐, 王国政, 杨继凯. WO₃/Pt和NiO电极电致变色器件的性能[J]. 材料研究学报, 2024, 38(8): 569-575.
Ziheng HAO, Liumenghan ZHENG, Ni ZHANG, Entong JIANG, Guozheng WANG, Jikai YANG. Color-changing Performance of Electrochromic Devices Based on WO₃/Pt-NiO Electrodes[J]. Chinese Journal of Materials Research, 2024, 38(8): 569-575.

全文: PDF(6269 KB) HTML

摘要:

将水热法和电沉积相结合制备WO₃/Pt复合薄膜并表征其组成、微结构和性能，将其作为阴极制做了WO₃/Pt-NiO电致变色器件并测试其性能。结果表明，WO₃/Pt-NiO电致变色器件具有较为迅速的时间响应 (着色/褪色的为29.62/18.84 s)和适当的光调制范围(630 nm处为47%)。这种WO₃/Pt-NiO电致变色器件，具有大光调制、高着色效率和高开关速度等性能。

关键词 ：复合材料, 变色性能, 电致变色, WO₃/Pt复合薄膜

Abstract：

The application of electrochromic devices (ECDs) in smart windows provides new solutions for energy conservation and environmental protection. WO₃/Pt composite films for electrochromic cathodes were prepared through a combination of hydrothermal and electrodeposition methods. WO₃/Pt composite films of different deposition times were characterized and their electrochromic properties were examined. Next, NiO thin films were prepared by electrodeposition as electrochromic anodes. WO₃/Pt-NiO electrochromic devices were constructed with WO₃/Pt composite films and NiO films as color changing cathodes and anodes, respectively. The WO₃/Pt-NiO electrochromic device has a relatively fast response time (coloring/fading rate of 18.84/29.62 s) and a good optical modulation range (47% at 630 nm). Its designed ECD has the characteristics of large optical modulation, high coloring efficiency, and fast switching speed. These characteristics make WO₃/Pt-NiO electrochromic devices a very promising candidate for smart windows in lighting control and energy-saving applications, and their use as color-changing smart windows has broad application prospects in fields such as architecture, aircraft, and automobiles.

Key words： composites color-change performance electrochromism WO₃/Pt composite film

收稿日期: 2023-09-16

ZTFLH:

TB333

基金资助:国家自然科学基金(51502023);吉林省科技厅项目(20200201077JC);吉林省教育厅项目(JJKH20210800KJ);重庆自然科学基金(CSTB2022NSCQ-MSX0751)

通讯作者: 王国政，教授，wguozheng@163.com，研究方向为光电子技术
杨继凯，副教授，jikaiyang0625@163.com，研究方向为光电成像与器件、光催化、稀土发光材料

Corresponding author: WANG Guozheng, Tel: 13704361080, E-mail: wguozheng@163.com;
YANG Jikai, Tel: 15144163608, E-mail: jikaiyang0625@163.com

作者简介: 郝子恒，男，1990年生，硕士

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https://www.cjmr.org/CN/10.11901/1005.3093.2023.464 或 https://www.cjmr.org/CN/Y2024/V38/I8/569

图1 电致变色器件的结构和原理

图2 WO3/Pt-40 s和NiO薄膜的XRD谱和NiO薄膜的XPS全谱

图3 WO3、WO3/Pt-40 s、WO3/Pt-80 s和NiO膜的SEM形貌

图4 WO3/Pt-40 s和WO3/Pt-80 s复合薄膜局部的EDS能谱

图5 WO3、WO3/Pt-40 s和WO3/Pt-80 s薄膜的循环伏安曲线、注入和抽取电荷变化曲线、透射光谱、光学透过率响应、着色效率和奈奎斯特曲线

表1 WO3和WO3/Pt薄膜的电致变色性能

图6 WO3-NiO器件和WO3/Pt-NiO器件的注入和抽取电荷变化曲线、透射光谱、光学透过率响应、和着色效率曲线

表2 WO3-NiO和WO3/Pt-NiO电致变色器件的电致变色性能

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