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材料研究学报  2026, Vol. 40 Issue (9): 641-652    DOI: 10.11901/1005.3093.2026.135
  研究论文 本期目录 | 过刊浏览 |
稀土Ce对渗碳齿轮钢摩擦磨损性能的影响
何一梅1,2, 付志豪1, 杨超云1,2(), 刘航1, 刘朋1, 李星1, 石帅3, 赵燕青3, 栾义坤1,2(), 李殿中1,2
1.中国科学技术大学材料科学与工程学院 沈阳 110016
2.中国科学院金属研究所 沈阳材料科学国家研究中心 沈阳 110016
3.河北钢铁集团有限公司 石家庄 050400
Effect of Rare Earth Ce Addition on Friction and Wear Property of Carburized Gear Steel 18CrNiMo7-6
HE Yimei1,2, FU Zhihao1, YANG Chaoyun1,2(), LIU Hang1, LIU Peng1, LI Xing1, SHI Shuai3, ZHAO Yanqing3, LUAN Yikun1,2(), LI Dianzhong1,2
1.School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China
2.Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
3.HBIS Group Co., Ltd., Shijiazhuang 050400, China
引用本文:

何一梅, 付志豪, 杨超云, 刘航, 刘朋, 李星, 石帅, 赵燕青, 栾义坤, 李殿中. 稀土Ce对渗碳齿轮钢摩擦磨损性能的影响[J]. 材料研究学报, 2026, 40(9): 641-652.
Yimei HE, Zhihao FU, Chaoyun YANG, Hang LIU, Peng LIU, Xing LI, Shuai SHI, Yanqing ZHAO, Yikun LUAN, Dianzhong LI. Effect of Rare Earth Ce Addition on Friction and Wear Property of Carburized Gear Steel 18CrNiMo7-6[J]. Chinese Journal of Materials Research, 2026, 40(9): 641-652.

全文: PDF(25940 KB)   HTML
摘要: 

冶炼三种不同稀土Ce含量的18CrNiMo7-6齿轮钢,将其保温和正火处理后渗碳并进行油润滑滑动摩擦磨损实验。使用接触式轮廓仪、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、透射菊池衍射(TKD)和X射线光电子能谱(XPS)等手段表征其磨损轨迹表面的形貌、次表层组织的演变以及磨面氧化膜的组成和分布,研究了稀土Ce对这种齿轮钢摩擦磨损性能的影响,揭示其摩擦磨损行为以及耐磨性能提高的机制。结果表明,稀土Ce能降低渗碳齿轮钢的磨粒磨损,改善稳定磨损阶段的摩擦磨损行为,将磨粒磨损和氧化磨损机制转变为以氧化磨损为主的磨损机制,使其耐磨性显著提高。与不含稀土的渗碳齿轮钢相比,含0.0078%和0.0126% Ce (质量分数)的渗碳齿轮钢磨损体积分别降低了55.3%和49.2%。Ce使钢的耐磨性提高,可归因于渗碳层硬度的提高和夹杂物状态的改变。Ce提高了渗碳齿轮钢表层的硬度,降低了次表层的塑性变形,有利于生成氧化膜使氧化磨损性能提高。随着Ce含量的提高,渗碳齿轮钢的表面硬度随之提高、次表层的变形减小。因夹杂物数量的增加和尺寸的增大而生成薄且小的块状氧化膜使这种钢的耐磨性能提高程度下降。

关键词 : 金属材料,  稀土,  重载齿轮钢,  摩擦磨损,  氧化膜    
Abstract:

Heavy-duty gears used in rail transit and wind power sectors often require carburizing treatment to enhance their wear resistance during service. However, conventional carburizing processes face certain limitations in improving efficiency. Studies have shown when the rare earth (RE) elements are involved in some way, the carburizing atmosphere may be modified, thus increase the carburizing efficiency, and further enhance the wear resistance of the steels. Nevertheless, most existing research has focused on introducing exogenous RE elements into the steel surface during the carburizing process, while the effect of RE addition during steelmaking on the wear resistance of carburized gear steel remains insufficiently explored. In this study, 18CrNiMo7-6 gear steels with different Ce addition were prepared and subjected successively to heat treating at 1150 oC for 6 h, forging at 900 oC to 1150 oC, normalizing treatment at 880 oC for 2 h and followed by carburizing, quenching and tempering etc. Then the effect of RE addition on their friction and wear behavior was characterized via oil-lubricated sliding wear tester, contact profilometry, white light interferometry, scanning electron microscopy, transmission electron microscopy, transmission Kikuchi diffraction, and X-ray photoelectron spectroscopy, in terms of the surface morphology, subsurface microstructure evolution, and oxide scale composition on wear tracks. The results indicate that Ce addition can effectively mitigate the abrasive wear and improve the friction and wear behavior of the carburized gear steels during the steady-state wear stage, transforming the wear mechanism from a coexistence of abrasive wear and oxidative wear to oxidative wear-dominated mechanism, thereby significantly enhancing the wear resistance of carburized gear steel. Compared with carburized gear steel without RE, the wear volume of the carburized gear steels with 0.0078%Ce and 0.0126%Ce (mass fraction) is reduced by 55.3% and 49.2%, respectively. The improved wear resistance after Ce addition may be attributed to the increased hardness of the carburized layer and the modification of inclusion in the steels. The low surface hardness of the steel without RE may facilitate severe abrasive wear and pronounced subsurface plastic deformation, which readily leads to oxide scale fragmentation. Ce addition may be conductive to increasing the surface hardness of carburized gear steels, alleviating the subsurface plastic deformation, facilitating the formation of compact oxide scale, and consequently enhancing the oxidative wear resistance. Nevertheless, with the increasing Ce content, the continuously increased surface hardness results in further suppression of subsurface deformation, and there exists an increase in inclusion population and size. These two factors lead to the formation of thin, discontinuously distributed oxide scales, thereby compromising the wear resistance.

Key words: metallic materials    rare earth    heavy-duty gear steel    friction and wear    oxide film
收稿日期: 2026-03-06     
ZTFLH:  TG142.12  
基金资助:国家科技重大专项(2025ZD0617900);国家自然科学基金(52404354);国家自然科学基金(52501193)
通讯作者: 杨超云,助理研究员,cyyang14s@imr.ac.cn,研究方向为稀土在高强钢中的作用机理;
栾义坤,研究员,ykluan@imr.ac.cn,研究方向为稀土特殊钢与核心基础零部件
Corresponding author: YANG Chaoyun, Tel: (024) 23971973, E-mail: cyyang14s@imr.ac.cn;
LUAN Yikun, Tel: (024) 23971973, E-mail: ykluan@imr.ac.cn
作者简介: 何一梅,女,2001年生,硕士生
SamplesCCrNiMoSiMnPSOCeFe
0RE0.181.691.600.290.320.740.0030.00160.00070Bal.
78RE0.171.711.600.290.320.730.0030.00150.00070.0078Bal.
126RE0.181.701.600.290.320.740.0030.00130.00080.0126Bal.
表1  实验钢的化学成分
图1  重载齿轮钢渗碳和热处理工艺示意图
图2  往复摩擦磨损实验装置示意图
图3  渗层的碳浓度和硬度梯度分布和渗碳表层的组织以及夹杂物的SEM照片和统计结果
图4  实验钢的摩擦系数和磨损体积
图5  磨痕表面的WLI形貌与对应的截面轮廓
图6  磨痕表面的OM图
图7  磨痕表面的SEM图像和O元素的EDS分析结果
图8  磨痕次表面组织的透射明场像和对应的SAED花样及磨痕截面近表层的TEM明场像和O元素EDS分析结果
图9  磨痕次表面组织的TKD分析
图10  表面氧化膜的XPS全谱和Fe的精细谱
图11  磨痕表面氧化膜溅射10 s后的Fe 2p精细谱分峰拟合结果
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