EB-PVD制备的CoCrAlY涂层的喷丸强化

doi:10.11901/1005.3093.2017.303

材料研究学报

2018, Vol. 32

Issue (7): 525-532 DOI: 10.11901/1005.3093.2017.303

研究论文

本期目录 | 过刊浏览

EB-PVD制备的CoCrAlY涂层的喷丸强化

何利民¹(

), 邓仲华^1,², 黄光宏¹, 常振东¹, 刘其斌²

1 北京航空材料研究院表面工程研究所北京 100095
2 贵州大学材料与冶金学院贵阳 550025

Shot Peening Process of CoCrAlY Coatings Prepared by EB-PVD

Limin HE¹(

), Zhonghua DENG^1,², Guanghong HUANG¹, Zhendong CHANG¹, Qibin LIU²

1 Research Institute of Surface Engineering, Beijing Institute of Aeronautical Materials, Beijing 100095, China
2 College of Materials and Metallurgy, Guizhou University, Guiyang 550025, China

引用本文:

何利民, 邓仲华, 黄光宏, 常振东, 刘其斌. EB-PVD制备的CoCrAlY涂层的喷丸强化[J]. 材料研究学报, 2018, 32(7): 525-532.
Limin HE, Zhonghua DENG, Guanghong HUANG, Zhendong CHANG, Qibin LIU. Shot Peening Process of CoCrAlY Coatings Prepared by EB-PVD[J]. Chinese Journal of Materials Research, 2018, 32(7): 525-532.

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摘要:

使用强度为0.1 N、0.2 N、0.3 N以及0.45 N的喷丸对用EB-PVD制备的CoCrAlY涂层进行表面强化,观察了喷丸强化前后涂层的表面形貌,测量了喷丸前后涂层的表面粗糙度、表面残余应力、涂层的厚度和截面硬度,对比分析了喷丸前后涂层物相变化以及涂层高温氧化性能。结果表明：当喷丸强度为0.2 N时,CoCrAlY涂层的抗高温氧化性能大幅度提高。喷丸强度大于等于0.45 N时涂层出现破损,抗高温氧化性能降低。适当强度的喷丸能降低CoCrAlY涂层表面的粗糙度,提高涂层的致密度,改善物相结构,进而提高其抗高温氧化性能。喷丸强度大于等于0.3 N时CoCrAlY涂层表面出现鳞状突出物,Al氧化物在此处择优生长,Al氧化膜因应力集中而破裂,降低涂层的使用寿命。

关键词 ：材料表面与界面, 喷丸, EB-PVD, CoCrAlY涂层, 高温氧化性能, 塑性变形

Abstract：

In order to investigate the isothermal oxidation performance of CoCrAlY coatings prepared by EB-PVD after high energy shot peening process with different intensity, the CoCrAlY coatings on high temperature alloy DZ466 were surface shot peened with intensity of 0.1 N, 0.2 N, 0.3 N and 0.45 N. The shot peened coatings were characterized in terms of surface morphology, surface roughness, surface residual stress, thickness and cross-sectional hardness and phase composition, as well as isothermal oxidation behavior in air at 1050℃. Results show that the isothermal oxidation resistance of CoCrAlY coating prepared by EB-PVD is greatly improved after surface shot peening with intensity of 0.1 N. When the shot peening intensity is greater than or equal to 0.45 N, the coating is damaged, which degrades the isothermal oxidation performance of the CoCrAlY coating. The suitable shot peening intensity can decrease the surface roughness, whilst increase the density and change the phase composition of the CoCrAlY coating, and so that lead to the improvement of isothermal oxidation performance of the CoCrAlY coating. When the shot peening intensity is greater than or equal to 0.3 N, scale-shaped bulges formed on the surface of CoCrAlY coating, resulting in preferential growth of Al-oxide there. Because of the rupture of Al-oxide film induced by stress concentration in this place, the service life of coating is degraded.

Key words： surface and interface in the materials shot peening EB-PVD CoCrAlY coating isothermal oxidation performance mechanical deformation

收稿日期: 2017-06-14

ZTFLH:

TG146.2

基金资助:国家高技术研究发展计划(2015AA034403)和贵州省科技合作计划(黔科合LH[2015]7650)

作者简介:

作者简介何利民,男,1967年生,研究员

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https://www.cjmr.org/CN/10.11901/1005.3093.2017.303 或 https://www.cjmr.org/CN/Y2018/V32/I7/525

表1 DZ466、CoCrAlY靶材与粘结层的化学成分(质量分数, %)

表2 CoCrAlY涂层的喷丸强化的实验方案

图1 EB-PVD制备CoCrAlY涂层的截面形貌和表面形貌

图2 表面喷丸后CoCrAlY涂层在1050℃的氧化动力学曲线

图3 不同强度喷丸后CoCrAlY涂层的表面形貌

图4 喷丸强化后CoCrAlY涂层的表面粗糙度

图5 不同强度喷丸后CoCrAlY涂层的残余应力

图6 不同喷丸强度对CoCrAlY涂层厚度与截面硬度的影响：(a)涂层厚度变化(b)涂层截面硬度变化

图7 表面喷丸强化前后CoCrAlY涂层的XRD图谱

图8 表面喷丸前后的CoCrAlY涂层在1100℃高温氧化近300 h后的截面形貌

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