Effect of Applied Voltage on Performance of Anodic Oxidation Films of TiO2 on TC4 Alloy

doi:10.11901/1005.3093.2015.12.895

Chinese Journal of Materials Research

2015, Vol. 29

Issue (12): 895-903 DOI: 10.11901/1005.3093.2015.12.895

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Effect of Applied Voltage on Performance of Anodic Oxidation Films of TiO₂ on TC4 Alloy

Jikang YAN^1,²,Gang YANG^1,^**(

),Wanxia TANG^1,²,Yunfeng WU¹,Shuming FANG¹,Zhe SHI³

1. Kunming Metallurgical Research Institute, Kunming 650031, China
2. Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China
3. Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China

Cite this article:

Jikang YAN,Gang YANG,Wanxia TANG,Yunfeng WU,Shuming FANG,Zhe SHI. Effect of Applied Voltage on Performance of Anodic Oxidation Films of TiO₂ on TC4 Alloy. Chinese Journal of Materials Research, 2015, 29(12): 895-903.

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Abstract

Anodic oxidation films of TiO₂ were prepared on titanium alloys Ti-6Al-4V(TC4) in an electrolyte system of oxalate, silicate and phosphate hybrid by means of anodic oxidation with TC4 as anode and stainless steel as cathode. Then the crystallographic structure, three-dimensional topography, microstructure and bioactivity of the prepared TiO₂ films were characterized by means of X-ray diffractometer, X-ray photoelectron spectroscopy, AFM and scanning electron microscope etc. The results show that the applied voltage has almost no effect on the crystal structure of TiO₂ films which are amorphous. There exist certain amount of pores and convex particles with ca.1.3 μm in diameter on the surface of rough TiO₂ film prepared by an applied voltage of 30 V. With the increasing applied voltage, the convex particles on TiO₂ films are slowly dismissed due to the field assisted dissolution. There are many nanopores of ca. 240 nm in diameter on the films without convex particles when the applied voltage is 100 V. There are many hydroxyls and micro/nano structures on the surface of anodic oxidation films on TC4 titanium alloy, which is useful for the enhancement of bioactivities and bone growth characteristics of the formed TiO₂ oxide films.

Key words: inorganic non-metallic materials TC4 titanium alloy anodic oxidation surface treatment TiO2 oxide film

Received: 05 December 2014

Fund: *Supported by National Natural Science Foundation of China No.51362017 and the Major Science and Technology Projects in Yunnan Province No.2012ZE008

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	Jikang YAN
	Gang YANG
	Wanxia TANG
	Yunfeng WU
	Shuming FANG
	Zhe SHI

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https://www.cjmr.org/EN/10.11901/1005.3093.2015.12.895 OR https://www.cjmr.org/EN/Y2015/V29/I12/895

Fig.1 XRD spectra of films on TC4 by anode oxidation at different oxidation voltage

Table 1 Chemical state and atomic percent of O1s in anode oxidation films on TC4 at 80 V

Fig.2 XPS spectra of anode oxidation films on TC4 at 80 V

Fig.3 High-resolution XPS spectra of films on TC4

Fig.4 SEM images of surface of films on TC4 for different oxygen voltage, (a) 30 V, (b) 70 V, (c) 100 V

Fig.5 SEM images of pore structure of films on TC4, (a) 30 V, (b) 70 V, (c) 100 V

Fig.6 AFM images for 3D surface morphology of oxide films on TC4, (a) 30 V, (b)70 V, (c)100 V

Fig.7 Microstructure and chemical composition of oxide ceramic films on titanium alloy TC4 by anode oxidation at oxidation voltage 30 V, (a) second electron image and point analysis positions of EDS, (b) backscattered electron image and point analysis positions of EDS, (c) EDS of oxide titanium film, (d) EDS of precipitated phase on oxide titanium film

Table 2 Chemical composition of films on TC4 by anode oxidation (%, atomic fraction)

Fig.8 X-ray of anode oxidation TC4 implant-containing rabbit femora at 24 weeks after embedded in rabbit femora, (a) 30 V, (b)70 V, (c) 100 V

Fig.9 Surface structure and chemical composition of anode oxidation TC4 implant at 24 weeks after embedded in rabbit femora, (a) 30 V-SEM, (b) 70 V-SEM, (c) 100 V-SEM, (d) 30 V-EDS, (e) 70 V-EDS, (f) 100 V-EDS

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