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材料研究学报  2012, Vol. 26 Issue (1): 21-25    
  研究论文 本期目录 | 过刊浏览 |
不锈钢表面阴极微弧电沉积氧化铝膜层的性能
薛文斌1,2, 金乾1, 杜建成1,2, 华铭1,2, 吴晓玲1,2
1.北京师范大学核科学与技术学院射线束技术与材料改性教育部重点实验室 北京 100875
2.北京市辐射中心 北京 100875
Preparation and Characterization of Alumina Coating on Stainless Steel by Cathodic Microarc Electrodeposition
XUE Wenbin1,2, JIN Qian1, DU Jiancheng1,2, HUA Ming1,2, WU Xiaoling1,2
1.Key Laboratory for Beam Technology and Materials Modification of Ministry of Education, College of Nuclear Science and Technology, Beijing Normal University, Beijing 100875
2.Beijing Radiation Center, Beijing 100875
引用本文:

薛文斌 金乾 杜建成 华铭 吴晓玲. 不锈钢表面阴极微弧电沉积氧化铝膜层的性能[J]. 材料研究学报, 2012, 26(1): 21-25.
, , , , . Preparation and Characterization of Alumina Coating on Stainless Steel by Cathodic Microarc Electrodeposition[J]. Chin J Mater Res, 2012, 26(1): 21-25.

全文: PDF(876 KB)  
摘要: 以0.4 mol/L Al(NO3)3乙醇溶液为电解液, 用阴极微弧电沉积方法在304不锈钢表面制备了80 μm厚的氧化铝膜层。分析了膜层的形貌、成分和相组成, 测试了膜层的抗高温氧化和电化学腐蚀性能。结果表明, 电沉积膜层由γ--Al2O3和α--Al2O3组成。膜层中含有少量的Fe、Cr、Ni元素, 表明膜/基界面附近的不锈钢基体在微弧放电作用下也参与氧化铝膜层的沉积和烧结过程。氧化铝膜层使不锈钢在800℃恒温氧化速率明显降低, 表明其抗高温氧化性能得到提高。同时, 其腐蚀电位正向移动, 腐蚀电流密度降低1个数量级, 表明其耐腐蚀性能得到提高。
关键词 无机非金属材料阴极微弧电沉积不锈钢氧化铝膜层性能    
Abstract:An alumina coating of 80 μm thick was fabricated on the surface of 304 stainless steel by cathodic microarc electrodeposition in 0.4 mol/L Al(NO3)3 ethanol solution. The morphology, composition and phase constituent of the alumina coating were analyzed by scanning electron microscope (SEM) and X-ray diffraction (XRD), and the high-temperature oxidation and electrochemical corrosion behaviors of the coating were evaluated. The results show that the coating is composed of γ–Al2O3 and α–Al2O3 phases, and the coating contains a little Fe, Cr, Ni elements, which confirm that the stainless steel substrate near the coating/steel also takes part in the deposition and sintering process of alumina coating under cathodic microarc discharge. The oxidation rate of the coated stainless steel at 800 ℃  isothermal oxidation test is obviously reduced. Meanwhile, its corrosion potential increases positively and its corrosion current density decreases about one order of magnitude, indicating that the corrosion resistance is improved.
Key wordsinorganic non-metallic materials    cathodic microarc electrodeposition    stainless steel    alumina coating, properties
收稿日期: 2011-10-27     
ZTFLH: 

TG146.2

 
基金资助:

国家自然科学基金51071031, 北京市自然科学基金2102018和中央高校基本科研业务费专项资金资助项目。

1 T.Irisawa, H.Matsumoto, Thermal shock resistance and adhesion strength of plasma-sprayed alumina coating on cast iron, Thin Solid Films, 509, 141(2006)

2 A.L.Yerokhin, X.Nie, A.Leyland, A.Matthews, S.J.Dowey, Plasma electrolysis for surface engineering, Surf. Coat. Technol., 122, 73(1999)

3 A.L.Yerokhin, A.Leyland, A.Matthews, Kinetic aspects of aluminium titanate layer formation on titanium alloys by plasma electrolytic oxidation, Appl Surf Sci, 200, 172(2002)

4 W.Xue, Z.Deng, Y.Lai, R.Chen, Analysis of phase distribution for ceramic coatings formed by microarc oxidation on aluminum alloy, J. Am. Ceram. Soc., 81(5), 1365(1998)

5 W.Xue, Q.Jin, Q.Zhu, M.Hua, Y.Ma, Anti-corrosion microarc oxidation coatings on SiCp/AZ31 magnesium matrix composite, J. Alloys Compd., 482, 208(2009)

6 LU Lihong, SHEN Dejiu, WANG Yulin, TIAN Xinhua, MAO Zhiqiang, Microarc oxidation of the hot-dipped aluminum on the Q235 steel substrate, Corr. Prot., 22(2), 58(2001)

(卢立红, 沈德久, 王玉林, 田新华, 毛志强, Q235钢热镀铝层的微弧氧化, 腐蚀与防护,  22(2), 58(2001))

7 Z.Wu, Y.Xia, G.Li, F.Xu, Structure and mechanical properties of ceramic coatings fabricated by plasma electrolytic oxidation on aluminized steel, Appl. Surf. Sci., 253(20), 8398(2007)

8 GU Weichao, SHEN Dejiu, WANG Yulin, LIAO Bo, Microarc oxidation of arc-spraying aluminum coatings, Mater. Prot., 35(12), 37(2002)

(顾伟超, 沈德久, 王玉林, 廖波, 电弧喷涂铝层的微弧氧化, 材料保护,  35(12), 37(2002))

9 W.Gu, D.Shen, Y.Wang, G.Chen, W.Feng, G.Zhang, S.Fan, C.Liu, S.Yang, Deposition of duplex Al2O3/aluminum coatings on steel using a combined technique of arc spraying and plasma electrolytic oxidation, Appl. Surf. Sci., 252, 2927(2006)

10 Y.Wang, Z.Jiang, Z.Yao, Preparation and properties of ceramic coating on Q235 carbon steel by plasma electrolytic oxidation, Current Appl. Phys., 9, 1067(2009)

11 YANG Xiaozhan, HE Yedong, WANG Deren, GAO Wei, Yttria-stabilized zirconia thin film by cathodic microarc electrodeposition, Chin. Sci. Bull., 47(7), 525(2002)

(杨晓战, 何业东, 王德仁, 高唯, 阴极微弧电沉积钇稳定氧化锆涂层, 科学通报,  47(7), 525(2002))

12 LI Xinmei, LI Yinshuo, HAN Yong, Preparation of alumina coatings on titanium by cathodic micro-arc electrodeposition, J. Inorg. Mater., 20(6), 1493(2005)

(李新梅, 李银锁, 憨勇, 钛表面阴极微弧电沉积制备氧化铝涂层, 无机材料学报,  20(6), 1493(2005))

13 LI Xinmei, LI Yinshuo, HAN Yong, Effects of electrolyte composition and electrical parameter on alumina coatings by cathodic microarc elctrodeposition on titanium, J. Chin. Ceram. Soc., 33(7), 799(2005)

(李新梅, 李银锁, 憨勇, 溶液配比及电参数对钛阴极微弧电沉积氧化铝涂层的影响, 硅酸盐学报,  33(7), 799(2005))

14 Q.Jin, W.Xue, X.Li, Q.Zhu, X.Wu, Al2O3 coating fabricated on titanium by cathodic microarc electrodeposition, J. Alloys. Compd., 476, 356(2009)

15 W.Xue, Q.Jin, Q.Zhu, High temperature oxidation behavior of titanium coated by cathodic microarc electrodeposition, Trans. Mater. Heat Treat., 31(9), 124,132(2010)

16 LI Xijin, XUE Wenbin, CHENG Guoan, High temperature oxidation propertie of Al2O3 coating on TiAl alloy fabricated by cathodic microarc deposition method, Chin. J. Aerospace Mater., 30(4), 26(2010)

(李夕金, 薛文斌, 程国安, 阴极微弧放电制备TiAl合金表面Al2O3膜的高温氧化性能, 航空材料学报,  30(4), 26(2010))
 
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