|
|
|
| Glycidyl Methacrylate Polymer Grafting on Regenerated Cellulose Membrane Surface by Atom Transfer Radical Polymerization |
GAO Ying1, WANG Junbo1, MI Yace1( ), SUN Junmin1,2() |
1.College of Chemical Engineering, Inner Mongolia University of Technology, Hohhot 010051, China
2.Datang International Power Generation Co, Ltd. High Aluminum Coal Resources Development and Utilization R D Center, Ordos 010300, China |
|
Cite this article:
GAO Ying, WANG Junbo, MI Yace, SUN Junmin. Glycidyl Methacrylate Polymer Grafting on Regenerated Cellulose Membrane Surface by Atom Transfer Radical Polymerization. Chinese Journal of Materials Research, 2025, 39(9): 694-700.
|
|
|
Abstract As an advanced technique capable of finely regulating the properties of materials, the controllable grafting technique has gradually become a research hotspot in the field of material science and technology due to its high flexibility and customization. In this study, the regenerated cellulose membrane was surface grafted with poly glycidyl methacrylate (PGMA) via controllable grafting technique by taking 2-bromoisobutyryl bromide (BIBBr) as initiator and CuBr as catalyst. The effect of several key parameters on the grafting effect were systematically investigated, including dosages of initiator BIBBr, monomer GMA and catalyst, CuBr as well as the reaction temperature. The aim is to introduce epoxy groups in a controllable manner and pave the way for downstream separation and purification. The results show that the amount of initiator BIBBr is directly related to the density of the surface grafted initiator, which can effectively control the grafting rate of GMA. By the optimized conditions, i.e., the dose of initiator BIBBr, which is 3 times of the hydroxyl equivalent, the dose of GMA 17.83 mmol, and of CuBr 0.18 mmol, while the reaction at 60 °C, the grafting reaction may result in a grafting rate up to 10.51% (mass fraction) with an epoxy value 12.63 μmol/g. This study provides an important reference for the functional design of cellulose membranes.
|
|
Received: 15 August 2024
|
|
|
| Fund: National Natural Science Foundation of China(22365023);Applied Technology Research and Development Project of Jungar Qi(2023YY-03) |
Corresponding Authors:
MI Yace, Tel: 18004853459, E-mail: miyacetx@163.com;
SUN Junmin, Tel: 18947196196, E-mail: fangwq_2005@163.com
|
| [1] |
Liu Y H, Li S B, Wang Z Y, et al. Ultrasound in cellulose-based hydrogel for biomedical use: from extraction to preparation [J]. Colloids Surf., 2022, 212B: 112368
|
| [2] |
Kang H L, Liu R G, Huang Y. Graft modification of cellulose: methods, properties and applications [J]. Polymer, 2015, 70: A1
|
| [3] |
Bayramoglu G, Arica M Y. Grafting of regenerated cellulose films with fibrous polymer and modified into phosphate and sulfate groups: application for removal of a model azo-dye [J]. Colloids Surf., 2021, 614A: 126173
|
| [4] |
Pan K, Zhang X W, Cao B. Surface‐initiated atom transfer radical polymerization of regenerated cellulose membranes with thermo‐responsive properties [J]. Polym. Int., 2010, 59(6): 733
|
| [5] |
Pan K, Zhang X W, Ren R M, et al. Double stimuli-responsive membranes grafted with block copolymer by ATRP method [J]. J. Membr. Sci., 2010, 356(1-2): 133
|
| [6] |
Ye J L, Chu J C, Yin J, et al. Surface modification of regenerated cellulose membrane based on thiolactone chemistry-a novel platform for mixed mode membrane adsorbers [J]. Appl. Surf. Sci., 2020, 511: 145539
|
| [7] |
Qiu X Y, Ren X Q, Hu S W. Fabrication of dual-responsive cellulose-based membrane via simplified surface-initiated ATRP [J]. Carbohydr. Polym., 2013, 92(2): 1887
|
| [8] |
Yang X Q, Li N, Constantinesco I, et al. Choline phosphate functionalized cellulose membrane: a potential hemostatic dressing based on a unique bioadhesion mechanism [J]. Acta Biomater., 2016, 40: 212
doi: S1742-7061(16)30307-5
pmid: 27345136
|
| [9] |
Chmielarz P, Fantin M, Park S, et al. Electrochemically mediated atom transfer radical polymerization (eATRP) [J]. Prog. Polym. Sci., 2017, 69: 47
|
| [10] |
Krys P, Matyjaszewski K. Kinetics of atom transfer radical polymerization [J]. Eur. Polym. J., 2017, 89: 482
|
| [11] |
Matyjaszewski K. Atom transfer radical polymerization: from mechanisms to applications [J]. Isr. J. Chem., 2012, 52(3‐4): 206
|
| [12] |
Macior A, Zaborniak I, Chmielarz P, et al. A new protocol for ash wood modification: synthesis of hydrophobic and antibacterial brushes from the wood surface [J]. Molecules, 2022, 27(3): 890
|
| [13] |
Zaborniak I, Chmielarz P, Matyjaszewski K. Modification of wood-based materials by atom transfer radical polymerization methods [J]. Eur. Polym. J., 2019, 120: 109253
|
| [14] |
Zaborniak I, Macior A, Chmielarz P, et al. Hydrophobic modification of fir wood surface via low ppm ATRP strategy [J]. Polymer, 2021, 228: 123942
|
| [15] |
Zhang Z, Sèbe G, Hou Y L, et al. Grafting polymers from cellulose nanocrystals via surface‐initiated atom transfer radical polymerization [J]. J. Appl. Polym. Sci., 2021, 138(48): 51458
|
| [16] |
Zhang J, Liu H, Liu H, et al. Using diethylamine as crosslinking agent for getting polyepichlorohydrin-based composite membrane with high tensile strength and good chemical stability [J]. Polym. Bull., 2017, 74(3): 625
|
| [17] |
Wang J, Sproul R T, Anderson L S, et al. Development of multimodal membrane adsorbers for antibody purification using atom transfer radical polymerization [J]. Polymer, 2014, 55(6): 1404
|
| [18] |
Qian X L, Fan H, Wang C Z, et al. Preparation of high-capacity, weak anion-exchange membranes by surface-initiated atom transfer radical polymerization of poly (glycidyl methacrylate) and subsequent derivatization with diethylamine [J]. Appl. Surf. Sci., 2013, 271: 240
|
| [19] |
Wang J, Jenkins E W, Robinson J R, et al. A new multimodal membrane adsorber for monoclonal antibody purifications [J]. J. Membr. Sci., 2015, 492: 137
|
| [20] |
Yu H S, Kim J S, Vasu V, et al. Cu-mediated butadiene ATRP [J]. ACS Catal., 2020, 10(12): 6645
|
| [21] |
Fantin M, Tognella E, Antonello A, et al. Effects of solvent and monomer on the kinetics of radical generation in atom transfer radical polymerization [J]. Chem Electro Chem, 2024, 11(6): e202300662
|
| [22] |
Dworakowska S, Lorandi F, Gorczyński A, et al. Toward green atom transfer radical polymerization: current status and future challenges [J]. Adv. Sci., 2022, 9(19): 2106076
|
| [23] |
Flejszar M, Chmielarz P, Smenda J, et al. Following principles of green chemistry: low ppm photo-ATRP of DMAEMA in water/ethanol mixture [J]. Polymer, 2021, 228: 123905
|
| [24] |
Chmielarz P, Sobkowiak A. Ultralow ppm seATRP synthesis of PEO-b-PBA copolymers [J]. J. Polym. Res., 2017, 24: 77
|
| No Suggested Reading articles found! |
|
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|
Cited |
|
|
|
|
| |
Shared |
|
|
|
|
| |
Discussed |
|
|
|
|
