Effect of Mn on Wetting Behavior of X80 Steel in Molten Zn-Mn Alloy

doi:10.11901/1005.3093.2020.426

Chinese Journal of Materials Research

2021, Vol. 35

Issue (10): 785-794 DOI: 10.11901/1005.3093.2020.426

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Effect of Mn on Wetting Behavior of X80 Steel in Molten Zn-Mn Alloy

PENG Haoping¹^,²^,³, XI Shiheng², CUI Derong², LIU Ya¹^,³, DENG Song², SU Xuping¹^,³, RUAN Ruiwen²(

)

^1.Jiangsu Key Laboratory of Material Surface Science and Technology, Changzhou University, Changzhou 213164, China
^2.Jiangsu Key Laboratory of Oil & Gas Storage and Transportation Technology, Changzhou University, Changzhou 213164, China
^3.Jiangsu Collaborative Innovation Center of Photovoltaic Science and Engineering, Changzhou University, Changzhou 213164, China

Cite this article:

PENG Haoping, XI Shiheng, CUI Derong, LIU Ya, DENG Song, SU Xuping, RUAN Ruiwen. Effect of Mn on Wetting Behavior of X80 Steel in Molten Zn-Mn Alloy. Chinese Journal of Materials Research, 2021, 35(10): 785-794.

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Abstract

The effect of the addition of Mn in the range of 0.1%~0.5% (mass fraction) in molten Zn-Mn alloys at 450℃on the surface wetting behavior of X80 steel was studied by means of contact angle measurement with an improved sessile drop method and microstructure observation with SEM-EDS in terms especially of the interaction at interface molten Zn-χMn(χ=0.1~0.5) alloys/X80 steel substrate. The results show that Mn can play a positive role in the wettability between the molten Zn alloy and the steel. At 450℃, with the increasing Mn content from 0.1 to 0.5, the wetting contact angle between the molten Zn-χMn alloy and the steel decreases from 85° to 62°. The molten Zn alloy/X80 steel belongs to the reactive wetting system, correspondingly, the interface reaction may result in interface products composed of FeZn₁₀(δ), FeZn₁₃(ζ) and Fe₃Zn₁₀(Γ)/Fe₅Zn₂₁(Γ1) phases. Therefore, the wetting behavior is affected by the interface reaction. There is a precursor film emerged at the front of the three-phase line, which can enhance the wettability of the molten Zn alloy to X80 steel.

Key words: surface and interface in the materials wetting behavior hot dip galvanizing contact angle

Received: 14 October 2020

ZTFLH:

TG178

Fund: National Natural Science Foundation of China(51671037);Natural Science Research Project of Higher Education of Jiangsu Province(19KJA530001);Postgraduate Research & Practice Innovation Program of Jiangsu Province(KYCX20-2574);Qing Lan Project of Education Department of Jiangsu Province

About author: RUAN Ruiwen, Tel: (0519)86330800, E-mail: ruanrwczu@163.com

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	Haoping PENG
	Shiheng XI
	Derong CUI
	Ya LIU
	Song DENG
	Xuping SU
	Ruiwen RUAN

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https://www.cjmr.org/EN/10.11901/1005.3093.2020.426 OR https://www.cjmr.org/EN/Y2021/V35/I10/785

Table 1 Chemical composition of X80 steel (mass fraction, %)

Fig.1 Variations of contact angle of Zn-Mn alloy/X80 steel with Mn content at 450℃ (a) curve of contact angle with time, (b) variation curve of initial contact angle and final contact angle

Fig.2 Wetting surface morphologies of Zn-xMn alloy melts and X80 steel, x= (a) 0.1%, (b) 0.2%, (c) 0.3%, (d) 0.4% and (e) 0.5% (mass fraction)

Table 2 Chemical compositions of precursor films (mass fraction, %)

Fig.3 Morphologies of precursor films of various Zn-xMn alloys, x= (a) 0.1%, (b) 0.2%, (c) 0.3%, (d) 0.4% and (e) 0.5%(mass fraction)

Fig.4 Cross-sectional morphologies of Zn-xMn alloy/X80 steel interfaces, x= (a) 0.1%, (b) 0.2%, (c) 0.3%, (d) 0.4% and (e) 0.5% (mass fraction)

Table 3 Chemical compositions of marked points in Fig.4 (mass fraction, %)

Fig.5 Microstructure of Zn-0.5%Mn (mass fraction) /X80 steel interface

Fig.6 Schematic diagrams of different stages of wetting and spreading

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