Preparation and Properties of PVDF Based Dielectric Nanocomposites Containing Multi-scale Functional Fillers

doi:10.11901/1005.3093.2020.187

Chinese Journal of Materials Research

2020, Vol. 34

Issue (11): 835-844 DOI: 10.11901/1005.3093.2020.187

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Preparation and Properties of PVDF Based Dielectric Nanocomposites Containing Multi-scale Functional Fillers

CHEN Lin, HUANG Jiao, YAN Lei, GUO Yi, LIN Hong, LIN Hailan, BIAN Jun(

)

College of Materials Science and Engineering, Xihua University, Chengdu 610039, China

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CHEN Lin, HUANG Jiao, YAN Lei, GUO Yi, LIN Hong, LIN Hailan, BIAN Jun. Preparation and Properties of PVDF Based Dielectric Nanocomposites Containing Multi-scale Functional Fillers. Chinese Journal of Materials Research, 2020, 34(11): 835-844.

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Abstract

Four hybrid BT/MWCNTs nanomaterials (BT-A/MWCNTs-B, where A= 5,10) were prepared by two kinds of acidified multi-wall carbon nanotubes (MWCNTs) with lengths of 10-20nm and 20-40nm respectively and two kinds of hydroxylated barium titanate (BT) with diameters of 50nm and 100nm respectively. The effect of multi-scale dielectric fillers BT-A/MWCNTs-B on the mechanical properties, heat resistance and dielectric properties of nanocomposites was investigated by means of X-ray diffractometer (XRD), infrared spectra (FTIR), differential scanning calorimetry analysis (DSC), scanning electron microscope (SEM), tensile properties and dielectric properties testing. Results show that compared with BT/PVDF and MWCNTs/PVDF nanocomposites, BT-A/MWCNTs-B/PVDF nanocomposites have higher crystallinity and thermal properties. When the content (mass fraction) of BT-10 and MWCNTs-2 was 16% and 5% respectively, the melting temperature of BT-10/MWCNTs-2/PVDF nanocomposites could reach 173.8℃, which was 14.2℃ higher than that of pure PVDF (159.6℃), and the crystallinity could reach 43.1%. The three-phase BT-A/MWCNTs-B/PVDF nanocomposites had better dielectric performance than that of the two-phase nanocomposites. At 100Hz, the dielectric constant of BT-10/MWCNTs-2/PVDF nanocomposites could reach 119, 14 times of that of pure PVDF, and the dielectric loss was only 0.051. The tensile strength and elastic modulus of BT-10/MWCNTs-2/PVDF nanocomposites were up to 57.7 MPa and 1226 MPa, respectively.

Key words: composite Polyvinylidene fluoride (PVDF) Hybrid nanometer packing Thermal performance Mechanical properties Dielectric properties

Received: 26 May 2020

ZTFLH:

TQ332

Fund: Cooperation Project of Chunhui Plan of the Ministry of Education of China(Z2018088);Open Research Project of Comprehensive Health Promotion Center of Xihua University(DJKG2019-002);2020 “Xihua Cup” Innovation and Entrepreneurship Training Program for College Students of Xihua University(2020133);Interface innovation research studio project for College Students of Xihua University(2019-07);Graduate Innovation Fund of Xi-hua University(SA2000002910)

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	Lin CHEN
	Jiao HUANG
	Lei YAN
	Yi GUO
	Hong LIN
	Hailan LIN
	Jun BIAN

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https://www.cjmr.org/EN/10.11901/1005.3093.2020.187 OR https://www.cjmr.org/EN/Y2020/V34/I11/835

Fig.1 Crystal structure of α-PVDF and β-PVDF

Fig.2 FTIR spectrum of MWCNTs, MWCNTs-COOH, BT, BT-OH and BT/MWCNTs

Fig.3 Schematic representation of chemical interactions in BT-A/MWCNTs-B/PVDF nanocomposites

Fig.4 XRD spectrums of dielectric fillers BT-A/MWCNTs-B (a) and nanocomposites BT-A/MWCNTs-B/PVDF (b)

Fig.5 SEM images of dielectric fillers and BT-A/MWCNTs-B/PVDF nanocomposites (a) dielectric fillers BT-5/MWCNTs-1; (b) dielectric fillers BT-10/MWCNTs-2; (c) nanocomposites BT-5/MWCNTs-1/PVDF; (d) nanocomposites BT-10/MWCNTs-2/PVDF.

Fig.6 Mechanical properties of PVDF-based dielectric nanocomposites

Table 1 Mechanical property data of PVDF based nanocomposites

Table 2 Dielectric properties of PVDF based nanocomposites

Fig.7 Dielectric properties curve of nanocomposites (a) dielectric constants and dielectric loss of 16%BT-10/PVDF, 5%MWCNTs-1/PVDF and BT-A/MWCNTs-B/PVDF nanocomposites at a frequency of 100Hz and (b) relationship diagram of dielectric constant and frequency of 16%BT-10/PVDF, 5%MWCNTs-1/PVDF and BT-A/MWCNTs-B/PVDF nanocomposites

Fig.8 Theoretical model of BT-A/MWCNTs-b/PVDF nanocomposites (a) BT-5/MWCNTs-1/PVDF，(b) BT-10/MWCNTs-2/PVDF

Fig.9 DSC curves of BT-A/MWCNTs-B/PVDF nanocomposites (a) crystallization curves; (b) melting curves

Table 3 DSC test results of BT-A/MWCNTs-B/PVDF nanocomposites

1	Zheng Y, Zhang J, Sun X, et al. Crystal structure regulation of ferroelectric poly(vinylidene fluoride) via controlled melt-recrystallization [J]. Ind. Eng. Chem. Res., 2017, 56(15): 4580
2	Zhou W, Gong Y, Tu L T, et al. Dielectric properties and thermal conductivity of core-shell structured Ni@NiO/poly(vinylidene fluoride) composites [J]. J. Alloys. Compd, 2017, 693: 34643
3	Foreman K, Poddar S, Ducharme S, et al. Ferroelectricity and the phase transition in large area evaporated vinylidene fluoride oligomer thin films [J]. J. Appl. Phys., 2017, 121(19): 34102
4	Garciaiglesias M, Waal B, Gorbunov A V, et al. A versatile method for the preparation of ferroelectric supramolecular materials via radical end-functionalization of vinylidene fluoride oligomers [J]. J. Am. Chem. Soc., 2016, 138(19): 6217
5	Lu, Hongchao, Li Li. Crystalline structure, dielectric, and mechanical properties of simultaneously biaxially stretched polyvinylidene fluoride film [J]. Polym. Adv. Technol., 2018, 29(12): 3056
6	Arjmand M, Sadeghi S, Khajehpour M, et al. Carbon nanotube/graphene nano ribbon/polyvinylidene fluoride hybrid nano-composites: rheological and dielectric properties [J]. J. Phys. Chem. C, 2017, 121(1): 169
7	Luo S, Yu S, Sun R, et al. Nano Ag-deposited BaTiO₃ hybrid particles as fillers for polymeric dielectric composites: toward high dielectric constant and suppressed loss [J]. ACS Appl. Mater. Interfaces, 2013, 6(1): 1
8	Yu K, Wang H, Zhou Y, et al. Enhanced dielectric properties of BaTiO₃/poly(vinylidene fluoride) nanocomposites for energy storage applications [J]. J. Appl. Phys., 2013, 113(3): 4105
9	Zhang L, Gao R, Hu P, et al. Preparation and dielectric properties of polymer composites incorporated with polydopamine@AgNPs core-satellite particles [J]. RSC Adv. 2016, 10(05): 2216
10	Wei W, Jun R, Luo H, et al. Calcium copper titanate/polyurethane composite films with high dielectric constant, low dielectric loss and super flexibility [J]. Ceram. Int., 2018, 44(05): 5086
11	Keerati M, Prasit T. Improved dielectric properties of poly(vinylidene fluoride) polymer nanocomposites filled with Ag nanoparticles and nickelate ceramic particles [J]. Appl. Surf. Sci., 2019, 481,1160
12	Wang Z, Wang T, Fang M, et al. Enhancement of dielectric and electrical properties in BFN/Ni/PVDF three-phase composites [J]. Compos. Sci. Technol., 2017, 146: 139
13	Jayakumar O D, Abdelhamid E H, Kotari V, et al. Fabrication of flexible and self-standing inorganic-organic three phase magneto-dielectric PVDF based multiferroic nanocomposite films through a small loading of graphene oxide (GO) and Fe3O4 nanoparticles [J]. Dalton Trans. 2015, 44(36): 15872
14	Fakhri P, Mahmood H, Jaleh B, et al. Improved electroactive phase content and dielectric properties of flexible PVDF nanocomposite films filled with Au- and Cu-doped graphene oxide hybrid nanofiller [J]. Synth. Met.. 2016, 220(8): 653
15	Sharma M, Quamara J K, Gaur A. Behaviour of multiphase PVDF in(1-x) PVDF/(x)BaTiO₃ nanocomposite films: structural, optical, dielectric and ferroelectric properties [J]. J. Mater. Sci.-Mater. Electron., 2018, 29(13): 10875
16	Yu K, Wang H, Zhou Y, et al. Enhanced dielectric properties of BaTiO3/poly(vinylidene fluoride) nanocomposites for energy storage applications [J]. J. Appl. Phys. 2013, 113(3): 1
17	Silva A B, Arjmand M, Sundararaj U, et al. Novel composites of copper nanowire/PVDF with superior dielectric properties [J]. Polymer, 2014, 55(01): 226
18	Shixin S, Shan X, Shangkun J, et al. A facile strategy to enhance the dielectric and mechanical properties of MWCNTs/PVDF composites with the aid of MMA-co-GMA copolymer [J]. Materials, 2018, 11(3): 347
19	Souliéziakovic C, Nicolaÿ R, Prevoteau A, et al. Dispersible carbon nanotubes. [J]. Chem.-Eur. J., 2014, 20(5): 1210
20	Selvi M, Prabunathan P, Song J K, et al. High dielectric multiwalled carbon nanotube-polybenzoxazine nanocomposites for printed circuit board applications [J]. Appl. Phys. Lett., 2013, 103(15): 539
21	Mizutani K, Kohno H. Multi-walled carbon nanotubes with rectangular or square cross-section [J]. Appl. Phys. Lett., 2016, 108(26): 56
22	Saka C. Overview on the surface functionalization mechanism and determination of surface functional groups of plasma treated carbon nanotubes [J]. Crit. Rev. Anal. Chem., 2017, 48(2): 2642
23	Bian J, Wang G, Zhou X, et al. Preparation and performance of nanocomposites HDPE toughened-reinforced synergetically with functionalized graphene and carbon nano-tubes [J]. Chinese Journal of Materials Research, 2017, 31(02): 136
	卞军, 王刚, 周醒等. 功能化石墨烯-碳纳米管协同强韧化HDPE纳米复合材料的制备和性能 [J]. 材料研究学报, 2017, 31(02): 136
24	Lin H L, Shen Y J, Wang Z J, et al. Preparation and properties of per functional graphene/elastomer co-operatively tough polypropylene nanocomposites [J]. Chinese Journal of Materials Research, 2016, 30(5): 393
	蔺海兰, 申亚军, 王正君等. 功能化石墨烯/弹性体协同强韧化聚丙烯纳米复合材料的制备和性能研究 [J]. 材料研究学报, 2016, 30(5): 393
25	Kim H, Johnson J, Chavez L A, et al. Enhanced dielectric properties of three phase dielectric MWCNTs/BaTiO₃/PVDF nanocomposites for energy storage using fused deposition modeling 3D printing [J]. Ceram. Int., 2018, 44(1): 1
26	Jin Y, Xia N, Gerhardt R A. Enhanced dielectric properties of polymer matrix composites with BaTiO₃ and MWCNT hybrid fillers using simple phase separation [J]. Nano Energy, 2016, 30: 407
27	Rath S K, Dubey S, Kumar G S, et al. Multi-walled CNT-induced phase behaviour of poly(vinylidene fluoride) and its electromechanical properties [J]. J. Mater. Sci., 2014, 49(1): 103
28	Mu Y, Li G. Effects of micron Al₂O₃ filler on flexural strength and high-temperature microwave absorbing properties of SiC_f/BN/SiC composites [J]. Chinese Journal of Materials Research, 2019, 33(11): 206
	穆阳, 李皓. Al₂O₃填料对SiC_f/BN/SiC复合材料弯曲强度和高温吸波性能的影响 [J]. 材料研究学报, 2019, 33(11): 206
29	Chen W, Nie Y Y, Sun X G, et al. Performance of lithiumion capacitors using pre-lithiated multi-walled carbon nanotube composite anode [J]. Chinese Journal of Materials Research, 2019, 33(5): 371
	陈玮, 聂艳艳, 孙晓刚等. 预嵌锂多壁碳纳米管的性能 [J]. 材料研究学报, 2019, 33(5): 371
30	Saleh T A. The influence of treatment temperature on the acidity of MWCNT oxidized by HNO₃, or a mixture of HNO₃/H₂SO₄ [J]. Appl. Surf. Sci., 2011, 257(17): 7746
31	Marzieh N, Reza T M, Maryam K, et al. Assessment of the optical and dielectric properties of MWCNTs/BaTiO₃ nanocomposite ceramics [J]. Ceram. Int., 2018, 44(11): 235
32	Chang S J, Liao W S, Ciou C J, et al. An efficient approach to derive hydroxyl groups on the surface of barium titanate nanoparticles to improve its chemical modification ability [J]. J. Colloid Interface Sci., 2009, 329(2): 300
33	Ji W B, Chu R Q, Xu Z J, et al. Effect of CeO₂-doping on properties of SrNa_0.5Bi_4.5Ti₅O₁₈-based high temperature lead-free piezoelectric ceramics [J]. Chinese Journal of Materials Research, 2015, 29(3): 201
	姬万滨, 初瑞清, 徐志军等. CeO₂掺杂对SrNa_0.5Bi_4.5Ti₅O₁₈高温无铅压电陶瓷性能的影响 [J]. 材料研究学报, 2015, 29(3): 201
34	Kappadan S, Gebreab T W, Thomas S, et al. Tetragonal BaTiO₃ nanoparticles: An efficient photocatalyst for the degradation of organic pollutants [J]. Mater. Sci. Semicond. Process, 2016, 51: 42
35	Ke K, Potschke P, Jehnichen D, et al. Achieving beta-phase poly(vinylidene fluoride) from melt cooling: Effect of surface functionalized carbon nanotubes [J]. Polymer, 2014, 55(2): 611
36	Maity N, Mandal A, Nandi A K. Interface engineering of ionic liquid integrated graphene in poly(vinylidene fluoride) matrix yielding magnificent improvement in mechanical, electrical and dielectric properties [J]. Polymer, 2015, 65: 154

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