Preparation and Supercapacitance of C-ZIF-8@AC Composites Electrode Material

doi:10.11901/1005.3093.2018.574

Chinese Journal of Materials Research

2019, Vol. 33

Issue (5): 352-360 DOI: 10.11901/1005.3093.2018.574

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Preparation and Supercapacitance of C-ZIF-8@AC Composites Electrode Material

Chuanxiang ZHANG^1,²,Zhongyi JIANG³,Yuming DAI^1,²,Xiancong HE^1,²,Yuan CONG^1,²,Shuaishuai ZHU^1,²

1. School of Materials Science and Engineering, Nanjing Institute of Technology, Nanjing 211167, China
2. Jiangsu Key Laboratory of Advanced Structural Materials and Application Technology, Nanjing 211167, China
3. College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China

Cite this article:

Chuanxiang ZHANG,Zhongyi JIANG,Yuming DAI,Xiancong HE,Yuan CONG,Shuaishuai ZHU. Preparation and Supercapacitance of C-ZIF-8@AC Composites Electrode Material. Chinese Journal of Materials Research, 2019, 33(5): 352-360.

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Abstract

A lead-carbon battery, which possesses simultaneously advantages of lead-acid battery and supercapacitor, can be obtained by adding a certain amount of carbon into the lead-acid battery. So, it is particularly critical to create a new type of carbon with ideal specific capacitance and stability in acid solutions. We tried to synthesize such a new carbon material namely C-ZIF-8@AC via a two step process i.e. low temperature liquid phase method and high temperature calcination. The materials were characterized by field emission scanning electron microscope (FESEM), high resolution transmission electron microscope (HRTEM), X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectrometer (FTIR) etc. The results show that the prepared C-ZIF-8@AC composed of carbon particles with polyhedral structure (ZIF-8 framework) grown uniformly on the surface of active carbon (AC) particles; After ZIF-8 has further been coupled with AC particles, the size of the formed C-ZIF-8 particles is reduced. Electrochemical results indicate that the elemental N in pyridine nitrogen and pyrropyrrole nitrogen of the C-ZIF-8 framework can enhance the specific capacitance of C-ZIF-8@AC, which is about 181 F/g, much higher than that of the simple AC. The C-ZIF-8@AC shows excellent cycling stability with 99% capacitance retention rate after 6000 cycles at the current density of 5 A/g, which is higher than that of the simple AC.

Key words: inorganic non-metallic materials C-zif-8@AC low temperature liquid phase method specific capacitance lead-carbon battery

Received: 21 September 2018

ZTFLH:

TQ152

Fund: National Natural Science Foundation of China(11575084, 51402150);Natural Science Foundation of Nanjing Institute of Technology(CKJA201502, JCYJ201606)

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	Chuanxiang ZHANG
	Zhongyi JIANG
	Yuming DAI
	Xiancong HE
	Yuan CONG
	Shuaishuai ZHU

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https://www.cjmr.org/EN/10.11901/1005.3093.2018.574 OR https://www.cjmr.org/EN/Y2019/V33/I5/352

Fig.1 FESEM images of AC (a); C-ZIF-8(b); C-ZIF-8@AC (c, d) under different magnification

Fig.2 HRTEM images of AC (a); C-ZIF-8 (b); C-ZIF-8@AC (c, d, e) and mappings of C (f); N (g); O(h); Zn (i)

Fig.3 FTIR of different samples (a); XPS of C-ZIF-8 (b) and C-ZIF-8@AC (c); fine XPS of N1s of C-ZIF-8@AC (d)

Fig.4 N₂ adsorption-desorption isotherms (a) and pore size distributions (b) of C-ZIF-8@AC and C-AC

Fig.5 CV curves of C-AC and C-ZIF-8@AC at the scan rate of 20 mV/s (a); CV curves of C-ZIF-8@AC at different scan rates (b); GCD curves of C-AC and C-ZIF-8@AC at the current density of 1 A/g (c); GCD curves of C-ZIF-8@AC at different current densities (d)

Fig.6 Specific capacitances at different current densities (a) and Nyquist plots of electrochemical impedance (b) of C-AC and C-ZIF-8@AC.The inset in the Fig.6b shows the enlarged plots in high frequency region

Fig.7

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