Diffusion Behavior of Cu in Carbon Steel and Its Influence on Corrosion Resistance of Carbon Steel

doi:10.11901/1005.3093.2018.338

Chinese Journal of Materials Research

2019, Vol. 33

Issue (3): 225-231 DOI: 10.11901/1005.3093.2018.338

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Diffusion Behavior of Cu in Carbon Steel and Its Influence on Corrosion Resistance of Carbon Steel

Tao MA,Huirong LI,Jianxin GAO,Yungang LI(

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College of Metallurgy and Energy, North China University of Science and Technology, Tangshan 063009, China

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Tao MA,Huirong LI,Jianxin GAO,Yungang LI. Diffusion Behavior of Cu in Carbon Steel and Its Influence on Corrosion Resistance of Carbon Steel. Chinese Journal of Materials Research, 2019, 33(3): 225-231.

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Abstract

The copper coating was deposited on the surface of carbon steel by electroplating method, and then annealed at high temperature. The diffusion coefficient of Cu in carbon steel were calculated by the Den-Broeder method, while the influence of Cu-metalizing on the corrosion resistance of carbon steel was investigated. Results show that the inward diffusion of Cu is mainly along grain boundaries of the carbon steel, while the diffusion of Cu will inhibit the growth of grains of the steel during heat treatment. The diffusion coefficient of Cu in carbon steel limits between 1.11×10^-16~3.03×10^-11 cm²/s, which increases with the increasing annealing temperature and decreases with the increasing Cu-concentration of copper. The diffusion activation energy of copper Cu in the ferrite + austenite region of carbon steel is between 90~108 kJ / mol at low temperatures, and in the ferrite region of carbon steel at high temperatures is between 126~167 kJ/mol. Furthermore, a Cu-Fe gradient material on the carbon steel gennerated via Cu-inward diffusion has better corrosion resistance rather than the bare carbon steel in NaCl solution.

Key words: metallic materials copper Cu-Fe gradient material diffusion coefficient diffusion active energy polarization curve

Received: 21 May 2018

ZTFLH:

TG146.1

Fund: National Natural Science Foundation of China(51474088)

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	Tao MA
	Huirong LI
	Jianxin GAO
	Yungang LI

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https://www.cjmr.org/EN/10.11901/1005.3093.2018.338 OR https://www.cjmr.org/EN/Y2019/V33/I3/225

Fig.1 Content distribution of Cu and Fe with the depth of samples after annealing diffusion treatment under different temperatures (a) 750℃, (b) 800℃, (c) 850℃, (d) 900℃, (e) 950℃, (f) 980℃, (g) 1000℃, (h) 1050℃

Fig.2 Microstructure of Cu-Fe diffusion couples after annealing diffusion treatment at 1050℃

Fig.3 SEM image and EDS line scanning of section of sample after annealing diffusion treatment at 1050℃

Fig.4 The diffusion coefficient of Cu in carbon steel at different weight concentration and temperatures

Fig.5 Fe-Cu alloy phase diagram

Fig.6 Relationship between diffusion coefficients of Cu and temperature during with different weight concentration of Cu and different temperature interval (a) 750~900℃, (b) 950~1050℃

Table1 Diffusion activation energy of Cu in different microstructures with different weight concentration (kJ/mol)

Fig.7 Fe-C alloy phase diagram under experimental conditions

Table 2 Fitting results of polarization curves for carbon steel and Cu plated carbon steel and Cu-Fe alloy in 3.5% NaCl solution

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