Preparation and Lithium Storage Performance of Two Dimensional Fold-like V2O5 Nanomaterial

doi:10.11901/1005.3093.2016.498

Chinese Journal of Materials Research

2017, Vol. 31

Issue (5): 374-380 DOI: 10.11901/1005.3093.2016.498

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Preparation and Lithium Storage Performance of Two Dimensional Fold-like V₂O₅ Nanomaterial

Yanwei LI^1,², Zhiping XIE¹, Canzheng LIU¹, Jinhuan YAO¹(

), Jiqiong JIANG¹, Jianwen YANG¹

1 Guangxi Key Laboratory of Electrochemical and Magneto-chemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, China
2 Key Laboratory of Rrenewable Energy, Chinese Academy of Sciences, Guangzhou 510640, China

Cite this article:

Yanwei LI, Zhiping XIE, Canzheng LIU, Jinhuan YAO, Jiqiong JIANG, Jianwen YANG. Preparation and Lithium Storage Performance of Two Dimensional Fold-like V₂O₅ Nanomaterial. Chinese Journal of Materials Research, 2017, 31(5): 374-380.

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Abstract

V₂O₅ gel was prepared by sol-gel method and V₂O₅ nanomaterial was fabricated by freeze-drying the V₂O₅ gel with proper pH value and followed by annealing treatment. XRD and FESEM results revealed that the prepared V₂O₅ nanomaterial consists of a single orthorhombic phase small V₂O₅ nanoparticles with alarge are a two-dimensional fold-like morphology. The lithium storage performance of the prepared V₂O₅ nanomaterial was characterized by cyclic voltammetry(CV), electrochemical impedance spectroscopy(EIS), potential relaxation technique(PRT), and charge-discharge tests. Due to the unique two-dimensional fold-like nanostructure, the prepared V₂O₅ nanomaterial exhibits much higher specific discharge capacity, better high rate performance, excellent cycling stability, and enhanced electrochemical reaction kinetics rather than the commercial V₂O₅. Therefore, the two-dimensional fold-like V₂O₅ nanomaterial is a very promising cathode material for lithium-ion batteries.

Key words: synthesizing and processing technics V₂O₅ sol-gel method cathode material lithium storage performance

Received: 23 August 2016

Fund: Supported by National Natural Science Foundation of China (Nos.51664012, 51464009 & 21263003), Guangxi Natural Science Foundation of China (Nos.2015GXNSFGA139006 & 2014GXNSFBA118238), and Key Laboratory of Renewable Energy, Chinese Academy of Sciences (No.y507k61001)

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	Yanwei LI
	Zhiping XIE
	Canzheng LIU
	Jinhuan YAO
	Jiqiong JIANG
	Jianwen YANG

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https://www.cjmr.org/EN/10.11901/1005.3093.2016.498 OR https://www.cjmr.org/EN/Y2017/V31/I5/374

Fig.1 XRD patterns of N-V₂O₅ sample (the vertical lines on the x-axis correspond to the standard XRD reflections of orthorhombic V₂O₅ and the inset shows the crystalline structure of layer V₂O₅)

Fig.2 FESEM images of N-V₂O₅ sample (a, b, c) and C-V₂O₅ sample (d)

Fig.3 CV curves (a) and EIS plots (b) of N-V₂O₅ and C-V₂O₅

Fig.4 Cycling performance (a) and rate performance (c) of N-V₂O₅ and C-V₂O₅ electrodes;charge/discharge curves at various cycles (b) and under various current densities (d) of N-V₂O₅ electrode

Fig.5 Charge/discharge curve (a), typical OCP-t curve (b) and typical curve of ln[exp(φ_∞-φ)F/RT-1] vs. t (c) of N-V₂O₅ electrode; (d) Chemical diffusion coefficient of Li ions in the N-V₂O₅ and C-V₂O₅ electrode

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