Influence of SiO2 Particles on Electrochemical Characteristics of Carbon Steel

doi:10.11901/1005.3093.2015.768

Chinese Journal of Materials Research

2017, Vol. 31

Issue (6): 422-428 DOI: 10.11901/1005.3093.2015.768

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Influence of SiO₂ Particles on Electrochemical Characteristics of Carbon Steel

Aijiao LI,Yanhua WANG(

),Lian ZHONG,Jia WANG,Lin FENG,Peipei YANG

Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, China

Cite this article:

Aijiao LI,Yanhua WANG,Lian ZHONG,Jia WANG,Lin FENG,Peipei YANG. Influence of SiO₂ Particles on Electrochemical Characteristics of Carbon Steel. Chinese Journal of Materials Research, 2017, 31(6): 422-428.

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Abstract

The influence of inert solid particles SiO₂ on electrochemical characteristics of carbon steel was studied by using the array electrode technique and the electrochemical impedance spectroscopy. It was found that the spreadability of droplets increased with the increase of the amount of SiO₂,as well as the corrosion activity area.In addition, the impedance spectra showed two capacitive loops with the deposition of SiO₂ particles, and the capacitive loop in the high frequencies was attributed to the blocking effect of the SiO₂ particles. The corrosion behavior of carbon steel was affected by these two aspects, the spreadability of droplets and the blocking effect of the SiO₂ particles. With the increase of the amount of SiO₂, the average current value decreased firstly and then increased. There was a critical value in the deposition amount of SiO₂ particles. When the amount was lower than the critical value, it could hinder corrosion. While, when the amount was higher than the critical value, it would accelerate corrosion owing to the expansion of droplets.

Key words: materials failure and protection spreadability array electrode deposition SiO2 particles

Received: 17 March 2016

Fund: Supported by National Natural Science Foundation of China (No.51131005) and Promotive Research Fund Forexcellent Young and Middle-aged Scientists of Shandong Province (No.BS2012HZ021)

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	Aijiao LI
	Yanhua WANG
	Lian ZHONG
	Jia WANG
	Lin FENG
	Peipei YANG

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https://www.cjmr.org/EN/10.11901/1005.3093.2015.768 OR https://www.cjmr.org/EN/Y2017/V31/I6/422

Fig.1 Galvanic current distribution of Q235 steel under NaCl droplet after (a) 10 min, (b) 1 h, (c) 3 h, (d) 5 h

Fig.2 Galvanic current distribution of Q235 steel under NaCl droplet as a function of deposition: (a) 0.0000 mg/cm², (b) 0.0010 mg/cm², (c) 0.0100 mg/cm², (d) 0.1000 mg/cm², (e) 1.0000 mg/cm²

Fig.3 Variations of the spreadability A₀ and the average current of carbon steel under NaCl droplet as a function of deposition

Fig.4 Impedance diagrams of Q235 steel under NaCl droplet as a function of deposition (a) Nyquist plot (b) Bode plot

Fig.5 Equivalent circuit models of impedance diagrams of Q235 steel under NaCl droplet as a function of deposition (a) blank (b) deposition

Fig.6 Variations of R_ct and R₁ as a function of deposition

Fig.7 Variations of the cathodic limiting current density of carbon steel under NaCl droplet at -800 mV as a function of deposition

Fig.8 The schematic diagram of corrosion mechanism of carbon steel under NaCl droplet as a function of deposition:(a) blank, (b) below the critical value, (c) above the critical value

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