Preparation of Micro-nano-sized Cu-Ag Core-shell Particles by a Quick-making Method and their Conductivity

doi:10.11901/1005.3093.2015.629

Chinese Journal of Materials Research

2016, Vol. 30

Issue (12): 903-908 DOI: 10.11901/1005.3093.2015.629

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Preparation of Micro-nano-sized Cu-Ag Core-shell Particles by a Quick-making Method and their Conductivity

Bin CAI,Zhejuan ZHANG(

),Zhuo SUN

School of Physics and Materials Science, Engineering Research Center for Nanophotonics and Advanced Instrument, Ministry of Education, East China Normal University, Shanghai 200062, China

Cite this article:

Bin CAI,Zhejuan ZHANG,Zhuo SUN. Preparation of Micro-nano-sized Cu-Ag Core-shell Particles by a Quick-making Method and their Conductivity. Chinese Journal of Materials Research, 2016, 30(12): 903-908.

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Abstract

Micro- and nano-sized Cu and Ag core-shell particles were fabricated by a simple and quick-making method with copper micro-particles, gelatin and silver sulfate (Ag₂SO₄) as raw materials, and citric acid trisodium (SC) as reducing- and chelating-agent. The influence of SC and Ag₂SO₄ on the morphologies and oxidation resistance of Cu-Ag particles were investigated. The results showed that the dosage of SC directly affected the uniformity and morphology of the Ag coated Cu particles. The more the Ag₂SO₄ was used, the lower the conductive resistance was for the prepared particles. With dosages of 1.5 g and 8.0 g for SC and Ag₂SO₄respectively, the Cu- particles could be covered by Ag nanoparticles completely to form core-shell structured Cu-Ag particles, thereafter, the electrical resistance of sheets made of which can reach as low as 1.1Ω.

Key words: metallic materials Ag coated Cu particles core-shell particles chelating agent conductivity

Received: 17 November 2015

Fund: *Supported by National Natural Science Foundation of China No.11204082, Shanghai Natural Fund Project No.16ZR1410700, School-enterprise Cooperation in Minhang District of Shanghai No. 2015MH218 and Postgraduate Scientific Research and Innovative Practice Funding Program of ECNU No. YJSKC2015-32.

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	Bin CAI
	Zhejuan ZHANG
	Zhuo SUN

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https://www.cjmr.org/EN/10.11901/1005.3093.2015.629 OR https://www.cjmr.org/EN/Y2016/V30/I12/903

Fig.1 Size distribution (a) and SEM image (b) of the raw Cu particles

Fig.2 SEM images of Cu-Ag particles prepared with different dosages of SC (a) 0 g; (b) 0.5 g; (c) 1.5 g; (d) 6.0 g

Fig.3 XRD patterns of the Cu-Ag powder prepared with 1.5 g SC

Fig.4 Cross-sectional SEM images (a) and Cross-sectional EDS analysis (b) of the Cu-Ag sample prepared with 1.5 g SC

Fig.5 SEM images of the Cu-Ag particles prepared with different dosages of Ag₂SO₄ (a) 3.0 g, (b) 4.0 g, (c) 5.0 g, (d) 8.0 g and (e) 11.7 g

Fig.6 EDS proportion of Ag in Cu-Ag production with different dosages of Ag₂SO₄

Table 1 Sheet resistance of Cu-Ag samples prepared with different dosages of SC and Ag₂SO₄

Fig.7 SEM images of Cu-Ag particles prepared with 8.0 g Ag₂SO₄ after being heated under 150℃ for 30 min

1	D. S. Jung, H. M. Lee, Y. C. Kang, S. B. Park, Air-stable silver-coated copper particles ofsub-micrometer size, J. Colloid Interf. Sci., 364(2), 574(2011)
2	E. B. Choi, J. H. Lee, Ethylene glycol-based Ag plating for the wet chemical fabrication of onemicrometer Cu/Ag core/shell particles, J. Alloys Compd., 643, S231(2015)
3	Cao Xiaoguo, Zhang Haiyan, Huang Huiping, Preparation and oxidation-resistant property research of micron Cu-Ag pimetallicpowder, Materials Review, 10, 151(2006)
3	(曹晓国, 张海燕, 黄惠平, 微米级铜银双金属粉的制备及其抗氧化性能研究, 材料导报, 10, 151(2006))
4	H. T. Hai, H.Takamura, J. Koike.Oxidation behavior of Cu-Ag core-shell particles for solar cell applications. J. Alloys Compd., 564, 71(2013)
5	Y. H.Peng, C. H. Yang, K. T. Chen, S. R. Popuri, C. H. Lee, B. S. Tang, Study on synthesis of ultrafine Cu-Ag core-shell powders with high electricalconductivity, Appl. Surf. Sci., 263, 38(2012)
6	V. Mancie, C. Rousse-Bertrand, J. Dille, J. Michel, P. Fricoteaux, Sono and electrochemical synthesis and characterization of copper core-silvershell nanoparticles, Ultrason. Sonochem., 17(4), 690(2010)
7	Hu Lei, Zhu Xiaoyun, Plating Layer Structure and Property of Silver-CoatedCopper Power with High Silver Content, Rare Metal Materials and Engineering, 11, 2017(2012)
7	(胡磊, 朱晓云, 高银含量银包铜粉镀层结构及性能研究, 稀有金属材料与工程, 11, 2017(2012))

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