High Temperature Oxidation Behavior of SIMP Steel and T91 Steel at 800℃

doi:10.11901/1005.3093.2015.230

Chinese Journal of Materials Research

2016, Vol. 30

Issue (2): 81-86 DOI: 10.11901/1005.3093.2015.230

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High Temperature Oxidation Behavior of SIMP Steel and T91 Steel at 800℃

SHI Quanqiang^1,², LIU Jian^1,², YAN Wei^2,³, WANG Wei^2,³, SHAN Yiyin^2,³, YANG Ke^2,^**(

)

1. University of Chinese Academy of Sciences, Beijing 100049, China
2. Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
3. Key Laboratory of Nuclear Materials and Safety Assessment, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China;

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SHI Quanqiang, LIU Jian, YAN Wei, WANG Wei, SHAN Yiyin, YANG Ke. High Temperature Oxidation Behavior of SIMP Steel and T91 Steel at 800℃. Chinese Journal of Materials Research, 2016, 30(2): 81-86.

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Abstract

Oxidation behavior of two ferrite/martensite(F/M) steels, namely a novel 9%-12% Cr modified F/M steel (SIMP steel) and a commercial T91 steel were comparatively studied in air at 800^oC. The oxide scales formed on the two steels were characterized by XRD, SEM and EPMA. The results show that the oxide scale formed on SIMP steel is single-layer composed of Cr₂O₃and Mn_1.5Cr_1.5O₄ spinel particles, and Si was enriched at the interface between the chromia scale and matrix; while the oxide scale formed on T91 steel has a double layered structure with an outer hematite Fe₂O₃ layer and an inner Fe-Cr spinel layer. The SIMP steel has better high temperature oxidation resistance than T91 steel, which may be due to the higher content of Cr and Si beneficial to the formation of the compact oxide scale on the SIMP steel.

Key words: metallic materials ADS high temperature oxidation SIMP steel T91 steel oxide scale

Received: 20 April 2015

ZTFLH:

TG172

Fund: *Supported by the Strategic Priority Research Program of Chinese Academy of Sciences Nos. XDA03010301 & XDA03010302.

About author: **To whom correspondence should be addressed, Tel: (024)23971628, E-mail: kyang@imr.ac.cn

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	Quanqiang SHI
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https://www.cjmr.org/EN/10.11901/1005.3093.2015.230 OR https://www.cjmr.org/EN/Y2016/V30/I2/81

Table 1 Chemical composition of the studied steels (%, mass fraction)

Fig.1 Microstructures of T91 (a) and SIMP (b) steels after heat treatment

Fig.2 Mass gain curves of SIMP and T91 steels oxidized in air at 800℃ for up to 500 h

Fig.3 XRD spectra of SIMP and T91steelsoxidized in air at 800℃ for 500 h

Fig.4 SEM images and EDS analysis of the surface oxide on T91 (a) and SIMP (b) steels oxidized in air at 800℃ up to 500 h

Fig.5 Cross section morphologies and EPMA element distribution of oxide layers on T91 (a) and SIMP (b) steels oxidized in air at 800℃ up to 500 h

Fig.6 Cross section morphologies of oxide layers on T91 (a) and SIMP (b) steels oxidizedin air at 800℃ up to 500 h

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