Preparation and Delaminating of Glycine-Mg3Al LDHs and its Intercalation Compounding with Montmorillonite

doi:10.11901/1005.3093.2013.372

Chinese Journal of Materials Research

2014, Vol. 28

Issue (2): 100-106 DOI: 10.11901/1005.3093.2013.372

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Preparation and Delaminating of Glycine-Mg₃Al LDHs and its Intercalation Compounding with Montmorillonite

Xiaoqian MA,Jinglong ZHOU,Nan LU,Xu WU,Xianmei XIE

College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024

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Xiaoqian MA,Jinglong ZHOU,Nan LU,Xu WU,Xianmei XIE. Preparation and Delaminating of Glycine-Mg₃Al LDHs and its Intercalation Compounding with Montmorillonite. Chinese Journal of Materials Research, 2014, 28(2): 100-106.

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Abstract

Glycine(Gly)was intercalated into Mg₃Al layered double hydroxides(Gly-Mg₃Al LDHs)by coprecipitation method. The delaminating of Gly-Mg₃Al LDHs in aqueous solution of pH=3~4 was realized by making use of the isoelectric point of Gly. Then Mg₃Al LDHs/montmorillonite layered composite was gained through inserting LDHs sheets into montmorillonite. The composite was characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR), electrophoresis apparatus and N₂-adsorption/desorption measurements. The results show that the formed Gly-Mg₃Al LDHs possesses well-defined crystallographic structure. When the raw material ratio is 0.5 (n_Gly:n_NO3^-=1:2), the obtained Gly-Mg₃Al LDHs exhibits the best performance of delaminating, while the zeta potential of the subsequence colloidal particles is between 35mV and 40mV. Additionally, the translucent colloidal solution may be kept stably for 72h.The interlayer space of the layered composite is 1.44 nm, which is the total thickness of LDHs sheet and montmorillonite sheet. The results prove that LDHs sheets and montmorillonite sheets are layer by layer staggered.

Key words: inorganic non-metallic materials glycine Mg₃Al LDHs delaminating montmorillonite intercalation compounding

Received: 31 May 2013

Fund: *Supported by National Natural Science Foundation of China No. 50872086 and the Natural Science Foundation of Shanxi Province No. 2012021006-3.

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	Xiaoqian MA
	Jinglong ZHOU
	Nan LU
	Xu WU
	Xianmei XIE

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https://www.cjmr.org/EN/10.11901/1005.3093.2013.372 OR https://www.cjmr.org/EN/Y2014/V28/I2/100

Fig.1 XRD Spectra of Gly-Mg₃Al LDHs with different n_Gly∶n_NO3^- ratios

Fig.2 XRD Spectra of Gly-Mg₃Al LDHs with different pH

Fig.3 schematic model of Gly-Mg₃Al LDHs

Fig.4 FT-IR spectrum of Gly-Mg₃Al LDHs with different n_Gly∶n_NO3^- ratios

Fig.5 FT-IR spectrum of Gly-Mg₃Al LDHs with different pH

Table 1 The effect of pH on the delamination

Table 2 The effect of n_Gly:n_NO3^- ratios on the delamination

Table 3 The effect of pH on the delamination

Fig.6 XRD Spectra of (a) delaminated Gly-Mg₃Al LDHs, (b) Gly-Mg₃Al LDHs, (c) montmorillonite and (d) Mg₃Al LDHs/montmorillonite layer composites

Fig.7 The preparation of Mg₃Al LDHs/montmorillonite layer composites

Fig.8 FT-IR spectrum of (a) Gly-Mg₃Al LDHs, (b) montmorillonite,(c) simple mixture of Gly-Mg₃Al LDHs and montmorillonite and (d) Mg₃Al LDHs/montmorillonite layer composites

Table 4 BET specific surface area and pore structure of montmorillonite, Gly-Mg₃Al LDHs and Mg₃Al LDHs/montmorillonite layer composites

Fig.9 N₂ absorption-desorption isotherm of Mg₃Al LDHs/montmorillonite layer composites

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