|
|
Isothermal Oxidation Behaviour of Ni–Cr–Ta–Al–Co–Mo Alloy at 900oC and 1000oC |
LU Xudong1,2, TIAN Sugui2, YU Xingfu2, WANG Changxin1 |
1.School of Materials Science and Engineering, Shenyang University of Technology, Shenyang 110178
2.Equipment Engineering College, Shenyang Ligong University, Shenyang 110159 |
|
Cite this article:
LU Xudong TIAN Sugui YU Xingfu WANG Changxin. Isothermal Oxidation Behaviour of Ni–Cr–Ta–Al–Co–Mo Alloy at 900oC and 1000oC. Chin J Mater Res, 2011, 25(4): 427-432.
|
Abstract Abstract: By means of measuring the kinetics curves of the oxidation and analysis method of TGA, XRD and SEM/EDAX. An investigation has been made into the oxidation behaviour of a nickel-based superalloy at 900℃ and 1000℃ in air. Results show that the kinetics curves of the alloy oxidizing obey the parabola regularity, and the rate of the mass gaining decrease gradually as the oxidizing time prolongs, and the oxidizing process is mainly controlled by the formation of Cr2O3 and Al2O3 phases. After oxidized at 900℃ and 1000℃, the oxide scales in the alloy consists of three layers, including the outer, middle and internal oxidizing layers, Cr2O3 and a few (Ni,Co)Cr2O4 phases are included in the outer oxide layer, the intermediate layer consists of CrTaO4 phase, and the internal oxide layer is identified as Al2O3 phase. In the period of the alloy oxidizing, the phase containing Ta-richer may restrain the element Al in the matrix diffusing outward, which restrains the growth up of the oxide scales to decrease the oxidizing rate of the alloy.
|
Received: 03 June 2010
|
|
Fund: Supported by National Natural Science Foundation of China No.50571070. |
1 Ren Xin, Wang Fuhui, Wang Xin, High–temperature oxidation and hot corrosion behaviours of the NiCr–CrAl coating on a nickel–based superalloy, Surface & Coatings Technology, 198, 425(2005)2 L.Huang, X.F.Sun, H.R.Guan, Z.Q.Hu, Oxidation behaviour of a single–crystal Ni–base superalloy in air at 900, 1000 and 1100oC, Tribology Letters, 23(1), 15(2006) 3 TIAN Sugui, GUO Hua, HU Zhuangqi, LI Tiefan, High temperature oxidation and oxides distribution characteristics of Ni–6.0Al–6.5Ta–8.5Mo–6.5Cr single crystal alloy, Acta Metallurgica Sinica, 37(4), 358(2001)(田素贵, 郭 华, 胡壮麒, 李铁藩, 单晶Ni--6.0Al--6.5Ta--8.5Mo--6.5Cr合金的高温氧化及其氧化物分布特征, 金属学报, 37(4), 358(2001))4 LI Qing, SONG Jinxia, XIAO Chengbo, WANG Dinggang, YU Qian, HAN Yafang, High temperature oxidation behavior of a Ni3Al base alloy containing high contents of W and Mo, Journal of Aeronautical Materials, 27(2), 6(2007)(李 青, 宋尽霞, 肖程波, 王定刚, 余 乾, 韩雅芳, 一种高W、Mo含量Ni3Al基合金的高温氧化行为, 航空材料学报, 27(2), 6(2007))5 DONG Jianxin, XIE Xishan, α–Cr precipitation behaviour and its effect on high Cr–containing superalloys, Acta Metallurgica Sinica, 41(11), 1160(2005)(董建新, 谢锡善, 不同Cr含量高温合金中α--Cr相析出行为及作用, 金属学报, 41(11), 1160(2005))6 ZHENG Liang, The effects of Tantalum and Ruthenium on the microstructures and properties of low Chromium and high Tungsten content cast Nickel–base superalloys, Xian University of Technology(2004)(郑 亮, Ta和Ru对低Cr高W铸造镍基高温合金组织及性能的影响, 硕士学位论文, 西安理工大学, (2004))7 LI Yun, SHANG Haibo, GUO Jianting, YUAN Chao, YANG Hongcai, Isothermal Oxidation Behavior of a Cast Ni–base Superalloy K35, Acta Metallurgica Sinica, 39(7), 751(2003)(李 云, 尚海波, 郭建亭, 袁 超, 杨洪才, 镍基铸造高温合金K35的高温氧化行为, 金属学报, 39(7), 751(2003))8 LIWeiyin, LIU Hongfei, ZHAO Shuangqun, Oxidation behaviour of a new Ni–based superalloy at 950oC, Transactions of Material and Treatment, 29(30), 28(2008)(李伟银, 刘红飞, 赵双群, 新型镍基高温合金950oC氧化行为的研究, 材料热处理学报, 29(30), 28(2008))9 M.H.L., X.F.Sun, J.G.Li, Z.Y.Zhang, T.Jin, H.R.Guan, Z.Q.Hu, Oxidation Behavior of a Single–Crastal Ni–base Superalloy in air.I: at 800 and 900 , Oxidation of Metals, 59(5/6), 600(2003)10 LIU Lirong, JIN Tao, SUN Xiaofeng, GUAN Hengrong, HU Zhuangqi, Effect of Al, Ti and Ta contents on the microstructure in Ni–base single crystal superalloy during aging, Rare Metal Materials and Engineering, 37(7), 1253(2008)(刘丽荣, 金 涛, 孙晓峰, 管恒荣, 胡壮麒, Al、Ti和Ta含量对镍基单晶高温时效组织的影响, 稀有金属材料与工程, 37(7), 1253(2008))11 Young Soo Park, Darryl P. Butt, Composition dependence of the kinetics and mechanisms of thermal oxidation of titanium–tantalum alloys, Oxidation of Metals, 51(5/6), 386(1999)12 L.Huang, X.F.Sun, H.R.Guan, Z.Q.Hu, Oxidation behaviour of the single crystal Ni–base superalloy DD32 in air at 900, 1000 and 1100oC, Oxidation of Metals, 65(5/6), 403(2006)13 G.R.Wallwork, A.Z.hed, Some limiting factors in the use of alloys at high temperatures, Oxidation of Metals, 3(2), 180(1971)14 TIAN Sugui, ZHANG Luting, YANG Hongcai,HU Zhuangqi, LI Tiefan, Kinetic features of high temperature oxidation for a single crystal Ni–base superalloy, Chinese Journal of Materials Research, 16(2), 186(2002)(田素贵, 张禄廷, 杨洪才, 胡壮麒, 李铁藩, 镍基单晶合金高温氧化的动力学特征, 材料研究学报, 16(2), 186(2002))15 LI Meiheng, SUN Xiaofeng, ZHANG Zhongyuan, HU Wangyu, HOU Guichen,GUAN Hengrong, HU Zhuangqi, Element diffusion and interface characteristics between NiCrAlY coating and Ni–base single crystal superalloy, Rare Metal Materials and Engineering, 33(1), 55(2004)(李美姮, 孙晓峰, 张重远, 胡望宇, 侯桂臣, 管恒荣, 胡壮麒, NiCrAlY涂层/Ni基单晶高温合金的元素扩散及界面特性, 稀有金属材料与工程, 33(1), 55(2004))16 S.Tin, T.M.Pollock, Phase instabilities and carbon additions in single crystal nickel–base superalloys , Materials Science and Engineering A, 348, 111(2003)17 Tian Sugui, Zhang Jinghua, Wu Xin, Yang Hongcai, Xu Yongbo, Hu Zhuangqi, Features and effect factors of creep of single crystal nickel–base superalloys, Metallurgical and Materials Transactions A, 32A, 2947(2001)18 LI Meishuan, High temperature oxidation of metals, first edition, (Beijing, Metallurgy Industry Press, 2001) p.164 (李美栓, 金属的高温腐蚀, 第1版, (北京, 冶金工业出版社, 2001) p.164)19 LIU Peisheng, SUN Xiaofeng, GUAN Hengrong, Internal oxidation of Co–base superalloy DZ40M at high temperature, Material Science & Technology, 6(1), 27(1998)(刘培生, 孙晓峰, 管恒荣, DZ40M钴基合金的高温内氧化现象, 材料科学与工艺, 6(1), 27(1998)) |
No Suggested Reading articles found! |
|
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|
Cited |
|
|
|
|
|
Shared |
|
|
|
|
|
Discussed |
|
|
|
|