Constructing Polyaniline/Alginate Film by Electrodeposition and Its Electrochemical Properties

doi:10.11901/1005.3093.2021.115

Chinese Journal of Materials Research

2022, Vol. 36

Issue (4): 314-320 DOI: 10.11901/1005.3093.2021.115

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Constructing Polyaniline/Alginate Film by Electrodeposition and Its Electrochemical Properties

YIN Jie(

), HU Yuntao, LIU Hui, YANG Yifei, WANG Yifeng

School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China

Cite this article:

YIN Jie, HU Yuntao, LIU Hui, YANG Yifei, WANG Yifeng. Constructing Polyaniline/Alginate Film by Electrodeposition and Its Electrochemical Properties. Chinese Journal of Materials Research, 2022, 36(4): 314-320.

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Abstract

A PANI/alginate modified glass electrode was prepared via a two-step electrodeposition approach. This approach combines the anodic electrodeposition of alginate with the electrochemical polymerization of aniline, which has many advantages such as convenient operation and simple post-treatment. The prepared PANI/alginate film presents dark green coloration similar to that of PANI. The PANI/alginate film is not only stable on the surface of the electrode, but also it can be detached completely from the electrode to be used as an independent film. The results from FTIR, XRD and SEM suggest that PANI and alginate do exist in the prepared film. The results of electrochemical performance analysis show that in comparison with the simple PANI modified electrode, the PANI/alginate modified electrode has higher electrochemical capacitance, better electrochemical stability, lower charge transfer resistance, better charge storage capacity and cycle stability. Thus, the PANI/alginate film modified electrode prepared by electrodeposition approach has promising application prospect as electrode material for capacitors.

Key words: polymer materials polyaniline/alginate film electrodeposition electrochemical properties

Received: 25 January 2021

ZTFLH:

O636

Fund: Independent Innovation Research Fund of Wuhan University of Technology(206601005);National Innovation and Entrepreneurship Training Program for College Students(202010497011)

About author: YIN Jie, Tel: 15827437627, E-mail: 1004350899@qq.com

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	Jie YIN
	Yuntao HU
	Hui LIU
	Yifei YANG
	Yifeng WANG

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https://www.cjmr.org/EN/10.11901/1005.3093.2021.115 OR https://www.cjmr.org/EN/Y2022/V36/I4/314

Fig.1 Schematic illustration of the fabrication of the PANI/alginate film (a); Images of the bare ITO slide (b); the alginate film (c), the PANI film (d) and the PANI/alginate film (e) on ITO slide; The PANI/alginate film peeled from ITO (f)

Fig.2 XRD patterns (a) and FTIR spectra (b) of the alginate film, the PANI film and the PANI/alginate film

Fig.3 SEM images of the alginate film (a, b) and the PANI/alginate film (c, d)

Fig.4 CVs of the bare electrode, the alginate modified electrode, the PANI modified electrode and the PANI/alginate modified electrode at a scan rate of 100 mV/s (a); Nyquist plots of the PANI modified electrode and the PANI/alginate modified electrode in a frequency range of 0.01 Hz~100 kHz (b)

Fig.5 CVs of the PANI/alginate modified electrode at different scan rates

Fig.6 Galvanostatic charge-discharge curves of the bare electrode, the alginate modified electrode, the PANI modified electrode and the PANI/alginate modified electrode at a current density of 1 A/g (a); and the PANI/alginate modified electrode at different current densities (b)

Fig.7 Cycling stabilities of the PANI modified electrode and the PANI/alginate modified electrode

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