Energy Analysis and Corresponding Model of Friction Strain-induced Solid State Amorphization of Lath Martensite

doi:10.11901/1005.3093.2019.393

Chinese Journal of Materials Research

2020, Vol. 34

Issue (4): 254-262 DOI: 10.11901/1005.3093.2019.393

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Energy Analysis and Corresponding Model of Friction Strain-induced Solid State Amorphization of Lath Martensite

YIN Cunhong¹^,², LI Shaobo¹^,², LIANG Yilong¹^,²^,³^,⁴^,⁵(

)

1.College of Mechanical Engineering, Guizhou University, Guiyang 550025, China
2.Guizhou Key Laboratory for Mechanical Behavior and Microstructure of Materials, Guiyang 550025, China
3.College of Materials Science and Metallurgical Engineering, Guizhou University, Guiyang 550025, China
4.National & Local Joint Engineering Laboratory for High-Performance Metal Structure Materials and Advanced Manufacturing Technology, Guizhou University, Guiyang 550025, China
5.Institute of Metal Materials and Mechanical Strength, Guizhou University, Guiyang 550025, China

Cite this article:

YIN Cunhong, LI Shaobo, LIANG Yilong. Energy Analysis and Corresponding Model of Friction Strain-induced Solid State Amorphization of Lath Martensite. Chinese Journal of Materials Research, 2020, 34(4): 254-262.

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Abstract

The coordinated plastic deformation, nano-lamination and amorphization in the friction-induced layer of lath martensite steel were characterized via transmission electron microscopy (TEM) observation on samples prepared with fixed-point ion beam cutting (FIB). It was found that high-density dislocation and defects concentrated in nano-lamellar structures. The amorphous structures formed at interfaces between nano-lamellar structures in friction-induced layer under high strain. These amorphous products may be beneficial to the further refinement of the wear debris and thereby the formation of a protective layer. According to the above experimental results, an amorphous nucleation model in dry sliding friction process was established based on tribology- and material-theory, and then the thermal conditions and energy barriers for amorphization were calculated. The results show that the amorphous nucleation energy model in dry sliding friction established according to the classical nucleation theory and the Gibbs free energy barrier calculation formula can be used to calculate the necessary critical dislocation density value for amorphization. According to the calculation results, the solid-state amorphization of the lath martensite can be induced by the dry sliding friction strain under the optimal friction condition.

Key words: metallic materials friction and wear solid state amorphization amorphous nucleation energy calculation lath martensite

Received: 25 August 2019

ZTFLH:

TB31/TH117.1

Fund: National Natural Science Foundation of China(No. 51671060);Guizhou Province Science and Technology Joint Fund(No. (2017)7244-5788)

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https://www.cjmr.org/EN/10.11901/1005.3093.2019.393 OR https://www.cjmr.org/EN/Y2020/V34/I4/254

Fig.1 A TEM sample of wear debris and nanolamellar prepared by FIB lift-out

Fig.2 Self-lubrication behavior during dry sliding friction

Fig.3 Wear mechanism in a self-lubrication process

Fig.4 A self-lubrication layer and high density dislocation concentration in nanolamellar

Fig.5 Solid-state amorphization in dry sliding friction

Fig.6 Gibbs free energy of a c-a transition (a) and temperature requirements of c-a transitions under different friction stress (b)

Fig.7 Gibbs free energy difference of a c-a transition

Physical parameter	Value
$G 110$ (GPa) $G = E 2 1 + ν$	81
$a$ /nm	0.2835
$b p$	$a 2 111$
$ρ$ / $k g ? m - 3$	$7.75 × 103$
$M$ / $k g ? m o l - 1$	$5.6 × 10 - 2$

Table 1 Physical parameters of 20CrNi2Mo steel

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