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| Preparation and Properties of Hybrid Proton Exchange Membranes of SPES-C/MIL-53(Al)-SO3H |
HAN Guanglu( ),CHEN Zhe,CAI Lifang,TIAN Junfeng,ZHANG Xuebo,MA Huanhuan |
| School of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450001, China |
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Cite this article:
HAN Guanglu,CHEN Zhe,CAI Lifang,TIAN Junfeng,ZHANG Xuebo,MA Huanhuan. Preparation and Properties of Hybrid Proton Exchange Membranes of SPES-C/MIL-53(Al)-SO3H. Chinese Journal of Materials Research, 2019, 33(9): 691-698.
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Abstract MIL-53(Al) was synthesized through hydrothermal synthesis, then sulfonic groups were introduced into MIL-53(Al) cages by sulfonation reaction to obtain MIL-53(Al)-SO3H with proton conduction property. The post-synthetic MIL-53(Al)-SO3H was incorporated into sulfonated polyarylethersulfone with cardo (SPES-C) polymer matrix to form hybrid PEMs. SEM results show that MIL-53(Al)-SO3H dispersed uniformly in SPES-C phase and no obvious interfacial defects in membranes could be observed. The TGA analysis confirmed that the membranes of PEMs have excellent thermal stability. The water uptake was enhanced with embedding MIL-53(Al)-SO3H and it presented positive correlation with composition. The incorporation of MIL-53(Al)-SO3H also inhibited the swelling ratio, indicating the excellent dimensional stability of the as-prepared hybrid PEMs. The hybrid PEMs also showed encouraging proton conductivity. The proton conductivity of the hybrid PEMs with incorporation amount of 5% (in mass fraction) MIL-53(Al)-SO3H reached to 0.15 S·cm-1, which was 32.5% higher than that of the pristine SPES-C membrane, and exceeded that of the ordinary commercial Nafion membrane (0.134 S·cm-1).
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Received: 06 March 2019
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| Fund: National Natural Science Foundation of China(21606211);Science and Technique Foundation (Foundation and Frontier Projects) of Henan Province(152300410127);Doctoral Research Fund of Zhengzhou University of Light Industry(2014BSJJ056) |
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