Effect of Heat Treatment on Microstructure of Interfacial Diffusion Layer of Cu/Al Composite Laminate Prepared by Cold Rolling

doi:10.11901/1005.3093.2013.877

Chinese Journal of Materials Research

2014, Vol. 28

Issue (7): 528-534 DOI: 10.11901/1005.3093.2013.877

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Effect of Heat Treatment on Microstructure of Interfacial Diffusion Layer of Cu/Al Composite Laminate Prepared by Cold Rolling

Xiaojiao ZUO,Xiaoguang YUAN(

),Hongjun HUANG,Huan LIU

School of Materials Science and Engineering, Shenyang University of Technology, Shenyang, 110780

Cite this article:

Xiaojiao ZUO,Xiaoguang YUAN,Hongjun HUANG,Huan LIU. Effect of Heat Treatment on Microstructure of Interfacial Diffusion Layer of Cu/Al Composite Laminate Prepared by Cold Rolling. Chinese Journal of Materials Research, 2014, 28(7): 528-534.

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Abstract

The effect of heat treatment on the microstructure of the interfacial diffusion layer of Cu/Al composite laminate prepared by cold rolling was investigated by means of SEM, TEM and micro-XRD The results show that an interfacial diffusion layer may form soon after heat treatment at high temperature; then as the heating time lengthened, the interfacial diffusion layer growths gradually from the original single-layer to become a three-layed one, while the heating time further lengthened, the morphology of the interfacial diffusion layer kept more or less unchanged besides a slight thickening; the interfacial diffusion layer consists of a layer of Al-Cu solid solution with intermetallic compound q(Al₂Cu) nearby the Al side, a layer of h₂(AlCu) in the middle and a layer of Cu-Al solid solution with intermetallic compound g₂(Al₄Cu₉) nearby the Cu side.

Key words: metallic materials Cu/Al composite laminate heat treatment diffusion layer intermetallic compound

Received: 20 November 2013

Fund: *Supported by National Natural Science Foundation of China No.51074108.

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	Xiaojiao ZUO
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	Huan LIU

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https://www.cjmr.org/EN/10.11901/1005.3093.2013.877 OR https://www.cjmr.org/EN/Y2014/V28/I7/528

Fig.1 Boundary layer morphology of Al-Cu composite laminate as rolled

Fig.2 Relationship of the Al-Cu composite laminate boundary morphology with holding time at 300℃

Fig.3 Image of Al-Cu composite laminate boundary after 300℃-10 min heat-treatment

Fig.4 Microstructure of boundary diffusion layer at Al side (a) and Cu side (b) after 300℃-10 h heat-treatment

Fig.5 Analysis of Al (a) and Cu (b) element after 300℃-10 h hea-treatment at boundary diffusion layer

Fig.6

300℃-10 h热处理后界面层铝侧和铜侧中的金属间化合物形态及能谱分析

Fig.7 The microstructure of Cu/Al composite laminate boundary diffusion layer after 300℃-10 h heat treatment

Fig.8 Diffraction location(a) and two dimension diffraction in situ with low angle (b) and high angle (c) of the Al-Cu composite laminate boundary after 300℃-10 h heat treatment

Fig.9 Analysis atlas of micro area-X diffraction at boundary layer after 300℃-10 h heat treatment

Fig.10 Electron diffraction analyze in boundary layer of Al side (a) and Cu side (b) by 300℃-10 h heat treatment

Fig.11 The boundary diffusion layer structure of Al-Cu composite laminate by cold rolling after heat treatment

1	HUANG Hongjun,YUAN Xiaoguang, Study on diffusion process and microstructure of Cu-Al clad metal sheet interface in heat-treatment, Journal of Northeastern University (Natural Science), 31(6), 31(2010)
1	(黄宏军, 袁晓光, 铜铝轧制复合板界面扩散过程与组织变化, 东北大学学报(自然科学版), 31(6), 31(2010))
2	CHEN Yanjun,ZHOU Shiping, YANG Futao, LIN Dezhong, MENG Liang, New development of processing techniques for laminates, Journal of Materials Science and Engineering, 20(1), 140(2010)
2	(陈燕俊, 周世平, 杨富陶, 林德仲, 孟亮, 层叠复合材料加工技术新进展, 材料科学与工程, 20(1), 140(2010))
3	ZU Guoyin,LI Xiaobing, DING Mingming, YU Jiuming, Investigating deformation behavior of asymmetrically rolled Cu/Al bimetal clad sheets, Journal of Northeastern University (Natural Science), 32(5), 675(2011)
3	(祖国胤, 李小兵, 丁明明, 于九明, 异步轧制铜/铝双金属复合板变形行为的研究, 东北大学学报(自然科学版), 32(5), 675(2011))
4	ZHENG Yuanmou,The explosion welding and welding of dissimilar metals, Welding Technique(Craft and New Technology), 30(5), 25(2001)
4	(郑远谋, 爆炸焊与异种金属的焊接, 焊接技术(工艺与新技术), 30(5), 25(2001))
5	E. Takeuchi, M. Zeze, H. Tanaka,Continuous casting of clad steel slab with level magnetic field brake , Steel Making Conference Proceedings, 225, 1996
6	DAI Guojun,Analysis of the process for plating Cu-Ti Co-metal wave-guide fimes on Li-ferrite surface, Research and Exploration in Laboratory, 4, 19(2004)
6	(戴国钧, 锂铁氧体表面沉积Cu-Ti复合金属波导膜系的工艺分析研究, 实验室研究与探索, 4, 19(2004))
7	SUN Deqin,WU Chunjing, XIE Jianxin, Research and development of forming technologies for metallic composite wires, Materials Review, 17(5), 65(2003)
7	(孙德勤, 吴春京, 谢建新, 金属复合线材成形工艺的研究开发概况, 材料导报, 17(5), 65(2003))
8	SUN Deqin,XIE Jianxin, WU Chunjing, The forming technology and development trend of clad plate, Metal Forming Technology, 21(2), 19(2003)
8	(孙德勤, 谢建新, 吴春京, 复合板的成形技术与发展趋势, 金属成形工艺, 21(2), 19(2003))
9	YANG Guiping,WANG Zhixiang, Study on complex interface bonding strength in Al/Cu bimetal tube drawing, Light Alloy Fabrication Technology, 26(5), 30(1998)
9	(杨贵平, 王智祥, 铝铜双金属管拉伸复合界面强度的研究, 轻合金加工技术, 26(5), 30(1998))
10	I. Takeshi, H. Kazuyuki, F. Masahiro, N. Toru,Improvement of the bonding strength of Al/Cu transition joint made by single-shot explosive welding technique using Cu intermediate plate, Journal of the Japan Welding Society, 12, 77(1994)
11	Y. C. Ha, J. H. Ha, H. G. Lee, D. K. Kim, B. I. Lee,Electrochemical and optical characterization of the corrosion resistivity of explosively bonded Al-Cu bimeta, Materials Science Forum, 475(2005)
12	Hiroshikzto,Shojiabe, ToshihikoTomizawa, Interfacial structures and mechanical properties of steel-Ni and steel-Ti diffusion bonds[J], Journal Of Materials Science,(32), 5225(1997)
13	M. Eizadjou, A. Kazemi Talachi, H. Danesh Manesh, H. Shakur Shahabi, K. Janghorban,Investigation of structure and mechanical properties of multi-layered Al/Cu composite produced by accumulative roll bonding (ARB) process, Composites Science and Technology, 68, 2003(2008)
14	HUANG Hongjun,LV Lin, MI Bingxue, ZUO Xiaojiao, LIU Huan, YUAN Xiaoguang, Effects of diffusion heat treatment on cold-rolled Cu/Al Composite Laminates, Journal of Northeastern University (Natural Science), 33(2), 91(2012)
14	(黄宏军, 吕琳, 蜜冰雪, 左晓姣, 刘欢, 袁晓光, 扩散热处理对冷轧铜铝复合板复合界面的影响, 东北大学学报(自然科学版), 33(2), 91(2012)
15	L. Yang, B. X. Mi, L. Lv,Formation sequence of interface intermetallic phases of cold rolling Cu/Al clad metal sheet in annealing Process, Switzerland: Trans. Tech. Publications, 600(2013)
16	CHEN Zhiyuan,Characterisation of clad roll bonding Al-Cu bimetal, Doctoral Dissertation, National Cheng Kung University, 2007
16	(陈志远, 铜铝轧延复合金属特性研究, 博士学位论文, 国立成功大学, 2007)

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