Characterization and Adsorption Performance of Polyurethane Foam Synthesized From Guluronic Acid Rich Sodium Alginate

doi:10.11901/1005.3093.2014.426

Chinese Journal of Materials Research

2014, Vol. 28

Issue (12): 942-948 DOI: 10.11901/1005.3093.2014.426

Current Issue | Archive | Adv Search

Characterization and Adsorption Performance of Polyurethane Foam Synthesized From Guluronic Acid Rich Sodium Alginate

Mingtian LI,Yan ZHAO,Zhiyu LIU,Yukun YAN,Jinsong ZHANG(

)

Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016

Cite this article:

Mingtian LI,Yan ZHAO,Zhiyu LIU,Yukun YAN,Jinsong ZHANG. Characterization and Adsorption Performance of Polyurethane Foam Synthesized From Guluronic Acid Rich Sodium Alginate. Chinese Journal of Materials Research, 2014, 28(12): 942-948.

Download:

HTML

PDF(5275KB)
Export: BibTeX | EndNote (RIS)

Abstract

Polyurethane foams based on guluronic acid (G)-rich sodium alginate (PF-SA) were synthesized by using cross-linking low molecular weight G-rich alginic acid(LG-HA)with hexamethylene diisocyanate (HDI). The prepared PF-SA was characterized and its adsorption performance of methylene blue (MB) in aqueous solution was investigated by XRD, FTIR, SEM, BET. The results show that the dosage of HDI and the concentration of LG-HA have a significant impact on the morphology and the microstructure of PF-SA; PF-SA with three-dimensional interconnected pore structure may be prepared when the molar ratio of HDI to the monomer unit of LG-HA was in the range of 1: 4 to1: 3, the concentration of LG-HA was in the range of 0.08-0.1 g/mL; this PF-SA is effective for the adsorption of MB: for a solution with concentration of 100 mg/L MB, the adsorption equilibrium can be reached in 30-160 min at room temperature. The removal efficiency of MB was as high as 99%．

Key words: organic polymer materials HDI sodium alginate cross linking reaction MB adsorption

Received: 18 August 2014

	Service

	E-mail this article
	Add to citation manager
	E-mail Alert
	RSS
	（）
	Articles by authors
	Mingtian LI
	Yan ZHAO
	Zhiyu LIU
	Yukun YAN
	Jinsong ZHANG

URL:

https://www.cjmr.org/EN/10.11901/1005.3093.2014.426 OR https://www.cjmr.org/EN/Y2014/V28/I12/942

Fig.1 Photographs of hydrogel with different molar ratios of HDI to monomer unit of LG-HA, (a) 3/1, (b) 2/1, (c) 1/1, (d) 1/2, (e) 1/3, (f) 1/4

Fig.2 SEM images of microstructure of PF-SA with different molar ratios of HDI to monomer unit of LG-HA, (a) 3/1, (b) 2/1, (c) 1/1, (d) 1/2, (e) 1/3, (f) 1/4

Fig.3 The preparation mechanism of PF-SA

Fig.4 FTIR spectra of (a) HDI, (b) LG-SA and (c) PF-SA

Fig.5 XRD spectra of LG-HA (a) and PF-SA (b)

Fig.6 Effects of the dosage of HDI on η (a) and q (b)

Fig.7 SEM images of microstructure of PF-SA prepared from LG-HA with different concerntrations, (a) 0.14 g/mL, (b) 0.1 g/mL, (c) 0.083 g/mL, (d) 0.067 g/mL

Fig.8 N₂ adsorption-desorption isotherms of PF-SA sample in Fig.7b

Fig.9 Effects of concerntration of LG-HA on η, (a) 0.14 g/mL, (b) 0.1 g/mL, (c) 0.083 g/mL, (d) 0.067 g/mL

1	TU Fengzhang,YAO Huimei, LIN Zhuguang, CHEN Lanlan, ZHANG Liang, Study on adsorption properties and mechanism of methylene blue on coal fly ash by spectrophotometry, Chinese Journal of Spectroscopy Laboratory, 27(3), 1116(2010)
1	(涂逢樟, 姚辉梅, 林竹光, 陈兰兰, 张亮, 分光光度法研究粉煤灰对亚甲基蓝的吸附及其机理研究, 光谱实验室, 27(3), 1116(2010))
2	ZHOU Yin,HU Changwei, LI Jianlong, Study on the biosorption mechanism of methylene blue in aqueous solution using pummelo peel, Research of Environmental Sciences, 21(5), 49(2008)
2	(周殷, 胡长伟, 李建龙, 柚子皮吸附水溶液中亚甲基蓝的机理研究, 环境科学研究, 21(5), 49(2008))
3	M. Kumar, R. Tamilarasan,Modeling studies: adsorption of aniline blue by using prosopis juliflora carbon/Ca/alginate polymer composite beads, Carbohydrate Polymers, 92(2), 2171(2013)
4	S.Yenisoy-Karakas, A.Aygün, M.Günes, E.Tahtasakal,Physical and chemical characteristics of polymer-based spherical activated carbon and its ability to adsorb organics, Carbon, 42(3), 477(2004)
5	S. H. Lin, R. S. Juang,Adsorption of phenol and its derivatives from water using synthetic resins and low-cost natural adsorbents: A review, Journal of Environmental Management, 90(3), 1336(2009)
6	ZHAO Yahong,PANG Fangliang, WANG Li, WANG Aiqin, Study on adsorption and desorption of methylene blue on Na-montmorillonite, Environmental Protection of Chemical Industry, 31(4), 357(2011)
6	(赵亚红, 庞方亮, 王丽, 王爱勤, 钠基蒙脱土对亚甲基蓝的吸附和解吸研究, 化工环保, 31(4), 357(2011))
7	C. Nakason, T. Wohmang, A. Kaesaman, S. Kiatkamjornwong,Preparation of cassava starch-graft-polyacrylamide superabsorbents and associated composites by reactive blending, Carbohydr. Polym., 81(2), 348(2010)
8	W. S. Wan Ngah, L. C. Teong, M. A. K. M. Hanafiah,Adsorption of dyes and heavy metal ions by chitosan composites: A review, Carbohydrate Polymers, 83(4), 1446(2011)
9	F. Rumiko, T. Yukari, Y. Toshio,Synthesis and properties of superabsorbent hydrogels based on guar gum and succinic anhydride, J. Appl. Polym. Sci., 114(1), 612(2009)
10	G. R. Mahdavinia, B. Massoumi, K. Jalili, G. Kiani,Effect of sodium montmorillonite nanoclay on the water absorbency and cationic dye removal of carrageenan-based nanocomposite superabsorbents, J. Polym.Res., 19, 9947(2012)
11	V. Singh, P. Kumari, S. Pandey, T. Narayan,Removal of chromium (VI) using poly(methylacrylate) functionalized guar gum, Bioresource Technology, 100(6), 1977(2009)
12	A. C. Chao, S. S. Shyu, Y. C. Lin, F. L. Mi,Enzymatic grafting of carboxyl groups on to chitosan–to confer on chitosan the property of a cationic dye adsorbent, Bioresource Technology, 91(2), 157(2004)
13	G. Crini,Recent developments in polysaccharide-based materials used as adsorbents in wastewater treatment, Progress in Polymer Science, 30(1), 38(2005)
14	L. Liu, Y. Z. Wan, Y. D. Xie, R. Zhai, B. Zhang, J. D. Liu,The removal of dye from aqueous solution using alginate-halloysite nanotube beads, Chemical Engineering Journal, 187, 210(2012)
15	A. Martinsen, G. Skjak-Braek, O. Smidsrod,Comparison of different methods for determination of molecular weight and molecular weight distribution of alginates, Carbohydr. Polym., 15(2), 171(1991)
16	W. M. Algothmi, N. M. Bandaru, Y. Yu, J. G. Shapter, A. V. Ellis,Alginate–graphene oxide hybrid gel beads: An efficient copper adsorbent material, Journal of Colloid and Interface Science, 397, 32(2013)
17	LIN Yongbo,XING Jia, SUN Weiguang, The research of sodium alginate on heavy metal pollution control, Environmental Science and Mangement, 32(9), 85-88(2007)
17	(林永波, 邢佳, 孙伟光, 海藻酸钠在重金属污染治理方面的研究, 环境科学与管理, 32(9), 85(2007))
18	LIU Bin,WANG Changyun, ZHANG Hongrong, WANG Bingui, WEI Yuxi, KANG Kai, LI Liang, YU Guangli, GENG Meiyu, GUAN Huashi, Preparation and identification of series of oligomannuronates, Chemical Journal of Chinese Universities, 27(3), 485(2006)
18	(刘斌, 王长云, 张洪荣, 王斌贵, 魏玉西, 康凯, 李亮, 于广利, 耿美玉, 管华诗, 系列甘露糖醛酸寡糖的制备与鉴定, 高等学校化学学报, 27(3), 485(2006))
19	ZHANG Zhenhai,LV Huixia, ZHOU Jianping, CHENG Yuchuan, FAN Ying, Determination of monomer composition and sequence of sodium alginates with 1HNMR, Journal of Instrumental Analysis, 28(4), 497(2009)
19	(张振海, 吕慧侠, 周建平, 程玉钏, 范颖, 应用1HNMR法比较7种海藻酸钠序列结构, 分析测试学报, 28(4), 497(2009))
20	A. F. Hassan, A. M. Abdel-Mohsen, Moustafa M.G. Fouda,Comparative study of calcium alginate, activated carbon, and theircomposite beads on methylene blue adsorption, Carbohydrate Polymers, 102, 192(2014)
21	LIU li,LI Yan, ZHAO Weizhen, YAO Ningning, NI Gang, Preparation of initiator for surface-initiated polymerization, Petrochemical Industry Application, 28(2), 12(2009)
21	(刘丽, 李燕, 赵炜珍, 姚宁宁, 倪刚, 一种SIP引发剂的制备, 石油化工应用, 28(2), 12(2009))
22	L. B. Li, Y. P. Fang, R. Vreeker, I. Appelqvist,Reexamining the egg-box model in calcium-alginate gels with X-ray diffraction, Biomacromolecules, 8(2), 464(2007)
23	HE Yusheng,LI Zhong, XI Hongxia, GUO Jianguang, XIA Qibin, Research progress of gas-solid adsorption isotherms, Ion Exchange and Adsorption, 20(4), 376(2004)
23	(何余生, 李忠, 奚红霞, 郭建光, 夏启斌, 气固吸附等温线的研究进展, 离子交换与吸附, 20(4), 376(2004))

[1]	YE Jiaofeng, WANG Fei, ZUO Yang, ZHANG Junxiang, LUO Xiaoxiao, FENG Libang. Epoxy Resin-modified Thermo-reversible Polyurethane with High Strength, Toughness, and Self-healing Performance[J]. 材料研究学报, 2023, 37(4): 257-263.
[2]	LI Hanlou, JIAO Xiaoguang, ZHU Huanhuan, ZHAO Xiaohuan, JIAO Qingze, FENG Caihong, ZHAO Yun. Synthesis of Branched Fluorine-containing Polyesters and their Properties[J]. 材料研究学报, 2023, 37(4): 315-320.
[3]	MA Yizhou, ZHAO Qiuying, YANG Lu, QIU Jinhao. Preparation and Dielectric Energy Storage Properties of Thermoplastic Polyimide/Polyvinylidene Fluoride Composite Film[J]. 材料研究学报, 2023, 37(2): 89-94.
[4]	SHEN Yanlong, LI Beigang. Preparation of Magnetic Amino Acid-Functionalized Aluminum Alginate Gel Polymer and its Super Adsorption on Azo Dyes[J]. 材料研究学报, 2022, 36(3): 220-230.
[5]	LONG Qing, WANG Chuanyang. Thermal Degradation Behavior and Kinetics Analysis of PMMA with Different Carbon Black Contents[J]. 材料研究学报, 2022, 36(11): 837-844.
[6]	JIANG Ping, WU Lihua, LV Taiyong, Pérez-Rigueiro José, WANG Anping. Repetitive Stretching Tensile Behavior and Properties of Spider Major Ampullate Gland Silk[J]. 材料研究学报, 2022, 36(10): 747-759.
[7]	YAN Jun, YANG Jin, WANG Tao, XU Guilong, LI Zhaohui. Preparation and Properties of Aqueous Phenolic Resin Modified by Organosilicone Oil[J]. 材料研究学报, 2021, 35(9): 651-656.
[8]	ZHANG Hao, LI Fan, CHANG Na, WANG Haitao, CHENG Bowen, WANG Panlei. Preparation of Carboxylic Acid Grafted Starch Adsorption Resin and Its Dye Removal Performance[J]. 材料研究学报, 2021, 35(6): 419-432.
[9]	SUN Liying, QIAN Jianhua, ZHAO Yongfang. Preparation and Performance of AgNWs -TPU/PVDF Flexible Film Capacitance Sensors[J]. 材料研究学报, 2021, 35(6): 441-448.
[10]	TANG Kaiyuan, HUANG Yang, HUANG Xiangzhou, GE Ying, LI Pinting, YUAN Fanshu, ZHANG Weiwei, SUN Dongping. Physicochemical Properties of Carbonized Bacterial Cellulose and Its Application in Methanol Electrocatalysis[J]. 材料研究学报, 2021, 35(4): 259-270.
[11]	SU Chenwen, ZHANG Tingyue, GUO Liwei, LI Le, YANG Ping, LIU Yanqiu. Preparation of Thiol-ene Hydrogels for Extracellular Matrix Simulation[J]. 材料研究学报, 2021, 35(12): 903-910.
[12]	ZHANG Xiangyang, ZHANG Qiyang, ZHENG Tao, TANG Tao, LIU Hao, LIU Guojin, ZHU Hailin, ZHU Haifeng. Fabrication of Composite Material Based on MOFs and its Adsorption Properties for Methylene Blue Dyes[J]. 材料研究学报, 2021, 35(11): 866-872.
[13]	WAN Liying, XIAO Yang, ZHANG Lunliang. Preparation and Properties of PU-DA System Based on Thermoreversible Diels-Alder Dynamic Covalent Bond[J]. 材料研究学报, 2021, 35(10): 752-760.
[14]	ZHANG Cuige, HU Liang, LU Zuxin, ZHOU Jiahui. Preparation and Emulsification Properties of Self-assembled Colloidal Particles Based on Alginic Acid[J]. 材料研究学报, 2021, 35(10): 761-768.
[15]	HUANG Jian, LIN Chunxiang, CHEN Ruiying, XIONG Wanyong, WEN Xiaole, LUO Xin. Ionic Liquid-assisted Synthesis of Nanocellulose Adsorbent and Its Adsorption Properties[J]. 材料研究学报, 2020, 34(9): 674-682.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Shared

Discussed