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Chinese Journal of Materials Research  2012, Vol. 26 Issue (6): 610-614    DOI:
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Preparation and Properties of Polypropylene Grafted Styrene Sulfonic Acid–polyaniline Antistatic Agents
ZU Liwu, ZHANG Xiaoyu, WANG Yazhen, XUE Shoucheng, XU Dongshuang, ZHANG Xiaozhou
College of Materials Science and Engineering, Qiqihar University, Qiqihar 161006
Cite this article: 

ZU Liwu ZHANG Xiaoyu WANG Yazhen XUE Shoucheng XU Dongshuang ZHANG Xiaozhou. Preparation and Properties of Polypropylene Grafted Styrene Sulfonic Acid–polyaniline Antistatic Agents. Chinese Journal of Materials Research, 2012, 26(6): 610-614.

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Abstract  

Polymer complex of polypropylene grafted styrene sulfonic acid–polyaniline(PP–g–SPS–PANI) was prepared by solution grafting to acrylic acid as a dopant and polypropylene (PP) as the matrix. PP–g–SPS–PANI were characterized by fourier transfer infrared spectrometry(FTIR), ZC–90 digital impedance meter and scanning electron microscopy(SEM). The amount of acrylic and initiator to influence on antistatic properties were studied. The results showed that the antistatic properties of PP–g–SPS–PANI increased with the amount of the acrylic and initiator, and then decreased. Acrylic doped so that PANI molecular chain formed charge delocalized conjugated structure and having conductive properties. The complex efficient and antistatic properties of antistatic agents are best when the mass ratio of acrylic with
polypropylene graft styrene sulfonamide acid(PP–g–SPS) macrylic/mPP−g−SPS=7:1, the molar ratio of initiator with aniline nAPS/nANI=2:1. The volume resistivity of PP–g–SPS–PANI/PP blends decreased to 9.5×1012Ω·cm. SEM results show that the interface of PP blends has a good compatibility.

Key words:  organic polymer materials      polypropylene antistatic agent      solution grafting      polyaniline     
Received:  29 May 2012     
ZTFLH:  TB324  
  TQ325  
Fund: 

Supported by Project of Heilongjiang Province Department of Education No.12521613 and Natural Science Foundation of Heilongjiang Province No.ZD201101.

URL: 

https://www.cjmr.org/EN/     OR     https://www.cjmr.org/EN/Y2012/V26/I6/610

1 K.B.Cheng, K.C.Leeb, T.H.Uengc, Electrical and impact properties of the hybrid knitted inlaid fabric reinforced  polypropylene composites, Composites Part A, 1216, 1219(2002)

2 Guoliang Tao, Aijun Gong, Jianjun Lu, Hung–Jue Sue, David E. Bergbreiter, Surface functionalized polypropylene: synthesis, characterization, and adhesion properties, Macromolecules, 34(22), 7672(2001)

3 Wentian Lin, Zhen Shao, Jinyong Dong, T.C.Mike Chung, Cross–linked polypropylene prepared by PP copolymers containing flexible styrene groups, Macromolecules, 42(11), 3750(2009)

4 Kazimiera A. Wilk, Ryszard Po zniak, Adam Sokolowski, Antistatic and wetting properties of chemodegradable cationic surfactants containing 1,3–dioxolane moiety, Journal of Surfactants and Detergents, 3(2), 207(2000)

5 Bohwon Kim, Vladan Koncar, Eric Devaux, Electrical and morphological properties of PP and PET conductive polymer fibers, Synthetic Metals, 167, 174(2004)

6 Jiku Wang, Xuyan Liu, Ho–Suk Choi, Jong–Hoon Kim,Conducting polymer films fabricated by oxidative graft copolymerization of aniline on poly(acrylic acid) grafted poly(ethylene terephthalate) surfaces, Phys. Chem. B, 112(47), 14829(2008)

7 Suzuki, Masahiro, Antistatic agent for synthetic polymer materials and method of application thereof, US, 6225386,2001

(铃  木, 正  宏, 高分子材料抗静电剂的合成方法及其应用, 美国, 6225386, 2001)

8 Yamasaki S, Koga T, Ohura H, Electrical conductivity effect of polyanili ne addition to poly(ethylene oxide) electrolyte film containing lithium Perchlor ate, J Mater Sci Lett, 15, 225(1996)

9 Z.M.Wang, H.Hong, T.C.Chung, Synthesis of maleic anhydride grafted polypropylene with high molecular weight using borane/O2 radical initiator and commercial PP polymers, Macromolecules, 38(22), 8966(2005)

10 Gangopadhyay R, De A, Ghosh G, Polyaniline–poly (vinylalcohol) conducting composite: material with easy process ability and novel application potential, Synthetic Metals, 123(1), 21(2001)

11 ZHANG Hongbo, SU Chunhui, LI Lin, Study of synthesis and property of the new antistatic agent, Journal of Materials Science and Engineering, 22(1), 121(2004)

(张洪波, 苏春辉, 李 林, 新型抗静电剂的合成及性能研究, 材料科学与工程学报,  22(1), 121(2004))

12 LIN Lin, WANG Cunguo, ZHANG Ping, YANG Lei, XIAO Hongjie, LI Binghai, LI Dapeng, ZHAO Qiang, Preparation of antistatic and flame retarding material by polypropylene composites filled with conductive polyacenic semiconductor material, Chemical Journal of Chinese Universities, 29(6), 1276(2008)

(林  琳, 王存国, 张  萍, 杨  蕾, 肖红杰, 李炳海, 李大鹏, 赵  强, 聚并苯纳米颗粒与聚丙烯复合制备新型抗静电阻燃材料, 高等学校化学学报,  29(6), 1276(2008))

13 GUO Jing, SHEN Xinyuan, LI Fuqing, BAI Lan, PEG–ZnO–PP composite antistatic agent and its modification for polypropylene fiber, China Synthetic Fiber Industry, 30(1), 31(2007)

(郭 静, 沈新元, 李福清, 白 兰, PEG--ZnO--PP复合抗静电剂及其对聚丙烯纤维的改性, 合成纤维工业,  30(1), 31(2007))

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