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Chinese Journal of Materials Research  2012, Vol. 26 Issue (5): 449-455    DOI:
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Surface Biomimetic Modification and Antibacterial Activity of AZ91 Magnesium Alloy
TIAN Jinhuan, JIAO Yanpeng, ZHOU Changren, DANG Xiangli,  DING Shan, LI Lihua, LI Hong
1.Department of Material Science and Engineering, College of Science and Engineering, Jinan University, Guangzhou 510630
2.Zhejiang Institute of Subtropical Crops, Wenzhou 325005
Cite this article: 

TIAN Jinhuan JIAO Yanpeng ZHOU Changren DANG Xiangli DING Shan LI Lihua LI Hong. Surface Biomimetic Modification and Antibacterial Activity of AZ91 Magnesium Alloy. Chinese Journal of Materials Research, 2012, 26(5): 449-455.

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Abstract  

The quaternary ammonium salts of chitosan (HACC) were synthesized with two different degrees of substitution (DS: 29%, 48%) of quaternary ammonium by reacting chitosan with glycidyl trimethylammonium chloride. Characterization of HACC was analyzed with IR spectra and HNMR spectroscopy. A biomimetic coating was codeposited on the surface of AZ91 magnesium alloy by adding HACC of two DS into simulated body fluid (SBF). The CaP/HACC coatings were analyzed by scanning electron microscopy (SEM) and X ray diffraction (XRD). The coatings have different crystal types. The results of antibacterial assays show that the CaP/HACC coatings have more antimicrobial activity to Staphylococcus aureus than CaP/CS coatings. The absorbances at the 6th hour show that the bacterial inhibition rate of four samples exceeds 90%. The absorbances at the 24th hour show that the samples obtained by adding the HACC of lower concentration into simulated body fluid have better antimicrobial effect and their bacterial inhibition rate reaches 98%.

Key words:  surface and interface in the materials      quaternary ammonium of salt      coating      antimicrobial activity     
Received:  18 June 2012     
ZTFLH:  O482  
Fund: 

Supported by National Natural Science Foundation of China No.81171459, Program of Excellent  "Pearl River" Young Scientists (2011),  and Fundamental Research Funds for the Central Universities Nos.21613125 and 21612317.

URL: 

https://www.cjmr.org/EN/     OR     https://www.cjmr.org/EN/Y2012/V26/I5/449

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