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Chin J Mater Res  2009, Vol. 23 Issue (3): 257-263    DOI:
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Synthesis and fluorescent properties of the ternary complexes of europium with aromatic carboxylic acid and butanedioic acid
GOU Lining; ZHOU Yue; TAN Hui; WANG Liying; LI Pingliang; GUO Dongcai
School of Chemistry and Chemical Engineering; Hunan University; Changsha 410082
Cite this article: 

GOU Lining ZHOU Yue TAN Hui WANG Liying LI Pingliang GUO Dongcai. Synthesis and fluorescent properties of the ternary complexes of europium with aromatic carboxylic acid and butanedioic acid. Chin J Mater Res, 2009, 23(3): 257-263.

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Abstract  

Six new ternary complexes of europium were synthesized with the first ligands of benzoic acid, p-methylbenzoic acid, m-chlorobenzoic acid, p-chlorobenzoic acid, p-hydroxylbenzoic acid, methoxybenzoic acid and the second ligand of butanedioic acid. Their molecular composition and structures were characterized by means of elemental analysis, EDTA titrimetric method, FT--IR and UV spectroscopies. The thermal stability properties of the title complexes were studied by thermal analysis instrument. The luminescent properties of the title complexes and their corresponding binary complexes were investigated by means of fluorescence instrument. The fluorescence spectra data show that the new ternary complexes have much higher luminescence intensity than their corresponding binary complexes.

Key words:  organic polymer materilas      europium      complex      synthesis      butanedioic acid      fluorescence     
Received:  27 September 2008     
Fund: 

Supported by Natural Science Foundation of Hunan Province No.05JJ30020 and the Development Foundation of the Scientific and Technological Bureau of Hunan Province No.04GK3035.

URL: 

https://www.cjmr.org/EN/     OR     https://www.cjmr.org/EN/Y2009/V23/I3/257

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