Fabrication and Performance of Metal Organic Framework Zn-BTC/rGO Nanocomposites

doi:10.11901/1005.3093.2023.446

Chinese Journal of Materials Research

2024, Vol. 38

Issue (8): 576-584 DOI: 10.11901/1005.3093.2023.446

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Fabrication and Performance of Metal Organic Framework Zn-BTC/rGO Nanocomposites

TAN Shangrong, YAO Zhuo(

), LIU Zechen, JIANG Yilei, GUO Shiqi, LI Lili

College of Materials and Metallurgy, University of Science and Technology Liaoning, Anshan 114051, China

Cite this article:

TAN Shangrong, YAO Zhuo, LIU Zechen, JIANG Yilei, GUO Shiqi, LI Lili. Fabrication and Performance of Metal Organic Framework Zn-BTC/rGO Nanocomposites. Chinese Journal of Materials Research, 2024, 38(8): 576-584.

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Abstract

As electrode material for supercapacitors, graphene-supported Zn-BTC metal-organic framework materials (Zn-BTC/rGO) with different morphologies were synthesized via a simple ultrasonic vibration method. The prepared Zn-BTC/rGO materials were characterized by means of TG, SEM, XRD, BET, Raman and electrochemical workstation in terms of the structure, morphology and electrochemical property. Their capacitance performance was examined by a three-electrode system. The results show that the synthesized one-dimensional rod-like Zn-BTC is uniformly anchored to the wrinkled layer of graphene nanosheets, and the material exhibits excellent capacitance performance, with a specific capacitance of 182.4 C·g^-1 (1 A·g^-1), which is better than the graphene-supported two-dimensional sheet-like Zn-BTC (139.3 C·g^-1), graphene (97.9 C·g^-1) and simple one-dimensional rod-like Zn-BTC (62.8 C·g^-1). A symmetrical supercapacitor was assembled with the graphene supported one-dimensional rod-shaped Zn-BTC, which presents excellent performance: the specific capacity of 57.7 F·g^-1 at a current density of 1 A·g^-1, the maximum energy density of 1.99 Wh·kg^-1 at a power density of 1390 W·kg^-1, and the specific capacity retention rate of 90.3% after 2000 charge-discharge cycles.

Key words: composite metal organic framework Zn-BTC graphene supercapacitor

Received: 08 September 2023

ZTFLH:

TB332

Fund: Scientific Study Project for Institutes of Higher Learning, Ministry of Education, Liaoning Province(LJKZ0290)

Corresponding Authors: YAO Zhuo, Tel: 13029368800, E-mail: yaozhuo1986@163.com

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	TAN Shangrong
	YAO Zhuo
	LIU Zechen
	JIANG Yilei
	GUO Shiqi
	LI Lili

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https://www.cjmr.org/EN/10.11901/1005.3093.2023.446 OR https://www.cjmr.org/EN/Y2024/V38/I8/576

Fig.1 Schematic illustration of the synthesis process of Zn-BTC/rGO nanocomposite

Fig.2 SEM images of rGO (a), Zn-BTC-1D (b), Zn-BTC/rGO-1D (c) and Zn-BTC/rGO-2D (d)

Fig.3 XRD patterns of rGO, Zn-BTC-1D, Zn-BTC/rGO-1D and Zn-BTC/rGO-2D samples

Fig.4 Raman patterns of rGO, Zn-BTC/rGO-1D, Zn-BTC/rGO-2D and Zn-BTC-1D samples

Fig.5 TG curves of Zn-BTC-1D and Zn-BTC/rGO-1D samples

Fig.6 GCD curves of different samples at current density of 1 A·g^-1 (a), GCD curves of Zn-BTC/rGO-1D electrode at different current densities from 1 to 40 A·g^-1 (b, c), specific capacity at various current densities for all electrodes at the current density ranging from 1 to 40 A·g^-1 (d) in 3 mol/L KOH electrolyte using three-electrode

Fig.7 Using three-electrode system in 3 mol/L KOH electrolyte CV curves (a) and specific capacity of Zn-BTC/rGO-1D electrode at various scan rates (2~100 mV·s^-1) (b), linear relationships between lg(i) and lg(v) for peak A and peak B in CV curves (c), separation of storage contribution from the capacitive behavior and diffusion-controlled processes at 20 mV·s^-1(d) and the contribution ratio of capacitive behavior and diffusion-controlled process at different scan rates (e)

Fig.8 Nyquist plot (a) and specific capacitance and capacitance retention at 1 A·g^-1 after 1000 cycles (b) of rGO, Zn-BTC/rGO-1D, Zn-BTC/rGO-2D and Zn-BTC-1D electrodes

Fig.9 CV curves at different scanning rates ranging from 2 mV·s^-1 to 100 mV·s^-1 (a); GCD curves at different current densities ranging from 1 A·g^-1 to 20 A·g^-1 (b); specific capacity at different current densities ranging from 1 A·g^-1 to 20 A·g^-1 (c); cycling performance after 2000 cycles (d); Nyquist plot (e) and (f) Ragon plot for symmetrical supercapacitor device assembled with Zn-BTC/rGO-1D

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