Microwave Absorption Performance of Encapsulated Magnetic Particles With Nitrogen-Doped Carbon Nanotubes Fe3O4@NCNTs

doi:10.11901/1005.3093.2023.366

Chinese Journal of Materials Research

2024, Vol. 38

Issue (6): 430-436 DOI: 10.11901/1005.3093.2023.366

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Microwave Absorption Performance of Encapsulated Magnetic Particles With Nitrogen-Doped Carbon Nanotubes Fe₃O₄@NCNTs

XU Dongwei¹, ZHANG Mingju¹, SHEN Zhihao¹, XIA Chenlu¹, XU Jingman¹, GUO Xiaoqin¹, XIONG Xuhai², CHEN Ping³(

)

^1.School of Material Science and Engineering, Zhengzhou University of Aeronautics, Zhengzhou 450046, China
^2.Liaoning Key Laboratory of Advanced Polymer Matrix Composites, Shenyang Aerospace University, Shenyang 110136, China
^3.State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, China

Cite this article:

XU Dongwei, ZHANG Mingju, SHEN Zhihao, XIA Chenlu, XU Jingman, GUO Xiaoqin, XIONG Xuhai, CHEN Ping. Microwave Absorption Performance of Encapsulated Magnetic Particles With Nitrogen-Doped Carbon Nanotubes Fe₃O₄@NCNTs. Chinese Journal of Materials Research, 2024, 38(6): 430-436.

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Abstract

One-dimensional carbon nanotubes (CNTs) have made them candidate as lightweight broadband microwave absorption material due to their intrinsic high electrical conductivity, light weight, and high specific surface area etc. In this paper, heterostructures of magnetic particels of iron oxide encapsulated with nitrogen-doped carbon nanotubes (Fe₃O₄@NCNTs) have been successfully constructed in-situ by one-step pyrolysis process. The phase composition and structure of the composites were characterized by powder X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM) and transmission electron microscopy (TEM), respectively. The electromagnetic parameters were measured by coaxial method and the reflection loss was simulated by Matlab. The results show that the calcination temperatures and the raw material ratio have important effect on the microwave absorption properties of nitrogen-doped magnetic functionalized carbon nanotube composites. The results demonstrated that when the calcination temperature was 750^oC and the raw material ratio (metal salt/carbon source) is 2:1, the Fe₃O₄@NCNTs-750 hybrids with only 10% of functional fillers reached a minimum reflection loss value of -57.7 dB and a maximum effective absorption bandwidth (EAB, below -10 dB) of 6.4 GHz at 2.0 mm.

Key words: composite carbon nanotube catalytic growth microwave absorption performance impedance matching

Received: 22 July 2023

ZTFLH:

TB332

Fund: Natural Science Foundation of Henan Province(232300420332);Key Scientific Research Pro-ject of Higher Education Institutions in Henan Province(23A430006);Youth Research Funds Plan of Zhengzhou University of Aeronautics(23ZHQN01005);National Natural Science Foundation of China(51873109);Liaoning Revitalization Talents Program(XLYC1802085)

Corresponding Authors: CHEN Ping, Tel: (0411)84986100, E-mail: Pchen@dlut.edu.cn

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	Articles by authors
	XU Dongwei
	ZHANG Mingju
	SHEN Zhihao
	XIA Chenlu
	XU Jingman
	GUO Xiaoqin
	XIONG Xuhai
	CHEN Ping

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https://www.cjmr.org/EN/10.11901/1005.3093.2023.366 OR https://www.cjmr.org/EN/Y2024/V38/I6/430

Fig.1 XRD, Raman patterns and XPS of Fe₃O₄@NCNTsunder different calcination temperatures

Fig.2 SEM and TEM images of Fe₃O₄@NCNTs-650 (a, b, c), Fe₃O₄@NCNTs-750 (d, e, f) and Fe₃O₄@NCNTs-850 (g, h, i)

Fig.3 Reflection loss diagrams of three dimensions and with different matching thicknesses for 650-10% (a, d), 750-10% (b, e) and 850-10% (c, f)

Fig.4 Relative complex permittivity of Fe₃O₄@NCNTs-X under different calcination temperatures (a) real part (ε′), (b) imaginary part (ε″), dielectric loss tangent (tanδε); relative complex permeability: (c) real part (μ′), (d) imaginary part (μ″) and (e) magnetic loss tangent (tanδμ)

Fig.5 Cole-Cole semicircles and Eddy current loss coefficient of composites under different calcination temperatures (a) Fe₃O₄@NCNTs-650, (b) Fe₃O₄@NCNTs-750, (c) Fe₃O₄@NCNTs-850 and (d) C₀

Fig.6 Attenuation constant (α) of Fe₃O₄@NCNTs-X calcinated under different temperatures

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