Preparation of Dopamine and Polyethyleneimine Co-deposition Modified Cation Exchange Membrane

doi:10.11901/1005.3093.2024.033

Chinese Journal of Materials Research

2024, Vol. 38

Issue (8): 585-592 DOI: 10.11901/1005.3093.2024.033

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Preparation of Dopamine and Polyethyleneimine Co-deposition Modified Cation Exchange Membrane

ZHOU Jian¹^,²(

), XIA Mengyue¹^,², ZHANG Hangfei¹^,², LIU Qiaojun¹^,²

^1.College of Environmental and Municipal Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China
^2.Ministry of Education Engineering Research Center of Water Resource Comprehensive Utilization in Cold and Arid Regions, Lanzhou 730070, China

Cite this article:

ZHOU Jian, XIA Mengyue, ZHANG Hangfei, LIU Qiaojun. Preparation of Dopamine and Polyethyleneimine Co-deposition Modified Cation Exchange Membrane. Chinese Journal of Materials Research, 2024, 38(8): 585-592.

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Abstract

The cation exchange membrane was prepared by co-deposition of Dopamine (DA) and Polyethyleneimine (PEI) based on mussel bionic binders, and its properties were characterized by infrared spectrometer, scanning electron microscope, and UV visible spectrophotometer. The effect of DA to PEI concentration ratio on the performance of the modified membrane was studied. The results showed that with the increase of PEI concentration, the selective permeability and membrane resistance increased first and then decreased, while the oxidation percentage of the modified membrane decreased first and then increased. When the concentration ratio of DA to PEI was 1:1, the modified membrane had lower oxidation percentage and membrane resistance. Accordingly, the water content and ion exchange capacity were 48.68% and 2.49 mmol/g, respectively, and the selective permeability was up to 97.8%, that is 8.08% superior to the original membrane.

Key words: organic polymer materials ion exchange membrane co-deposition high selective permeability

Received: 11 January 2024

ZTFLH:

TQ028

Fund: National Natural Science Foundation of China(52364055);Gansu Provincial Department of Education: Major Cultivation Project of University Scientific Research Innovation Platform(2024CXPT-14);Tianyou Youth Talent Lift Program of Lanzhou Jiaotong University

Corresponding Authors: ZHOU Jian, Tel: (0931)4956083, E-mail: zhoujian@mail.lzjtu.cn

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https://www.cjmr.org/EN/10.11901/1005.3093.2024.033 OR https://www.cjmr.org/EN/Y2024/V38/I8/585

Table 1 Performance parameters of commercial cation exchange membranes

Fig.1 Equivalent diagram of the test device

Fig.2 UV-Vis spectra of DA under different conditions

Fig.3 UV-Vis spectra of solutions with different concentration ratios of DA and PEI

Fig.4 Schematic diagram of DA-PEI co-deposition reaction

Fig.5 Influence of different concentration ratios of DA and PEI on water content and ion exchange capacity

Fig.6 Effects of different concentration ratios of DA and PEI on migration number and selective permeability

Fig.7 Effects of different concentration ratios of DA and PEI on oxidation resistance and membrane resistance

Fig.8 SEM images of original membrane and modified membrane with different concentration ratio (a) M0, (b) M1, (c) M2, (d) M3, (e) M4 and (f) M5

Table 2 Content of elements on the surface of the original membrane and the modified membrane (mass fraction, %)

Fig.9 EDS elemental surface scans of the original and modified membranes (a) M0, (b) M1, (c) M2, (d) M3, (e) M4 and (f) M5

Fig.10 Original membrane and the modified membranes with different concentration ratios of DA and PEI

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