Effect of Fe Microalloying on Plastic Deformation Behavior of Cu-Zr-Al Metallic Glasses

doi:10.11901/1005.3093.2020.444

Chinese Journal of Materials Research

2021, Vol. 35

Issue (11): 850-856 DOI: 10.11901/1005.3093.2020.444

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Effect of Fe Microalloying on Plastic Deformation Behavior of Cu-Zr-Al Metallic Glasses

XING Dong¹, CHEN Shuangshuang¹^,²(

), SONG Peidi¹, QI Kai¹, YIN Jun¹, LI Weihuo¹^,²

^1.School of Materials Science and Engineering, Anhui University of Technology, Ma'anshan 243002, China
^2.Key Laboratory of Green Fabrication and Surface Technology of Advanced Metal Materials, Anhui University of Technology, Ministry of Education, Ma'anshan 243002, China

Cite this article:

XING Dong, CHEN Shuangshuang, SONG Peidi, QI Kai, YIN Jun, LI Weihuo. Effect of Fe Microalloying on Plastic Deformation Behavior of Cu-Zr-Al Metallic Glasses. Chinese Journal of Materials Research, 2021, 35(11): 850-856.

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Abstract

Cu_(47.8－_x₎Zr_46.2Al₆Fe_x (x=0, 0.8, 1.2, 1.6) alloy were prepared by copper-mold injection casting method and the effect of Fe microalloying on the glass-forming ability and mechanical properties of Cu_(47.8－_x₎Zr_46.2Al₆Fe_x (x=0, 0.8, 1.2, 1.6) metallic glasses were investigated. The results show that the glass-forming ability of the alloy decreases with increasing of Fe content, while the plastic deformation ability at room temperature increases obviously. It is found that with the increase of minor Fe content more free volume will be introduced into the glassy matrix, and the inhomogeneity of composition and free volume distribution in the matrix will increase as a result of the positive mixing enthalpy of Fe and Cu. These factors jointly result in enhanced plasticity of metallic glass with high Fe content.

Key words: metallic materials bulk metallic glasses glass-forming ability heat of mixing room -temperature plasticity free volume

Received: 26 October 2020

ZTFLH:

TB331

Fund: Natural Science Foundation of Anhui Province(1908085ME147);International Cooperation and Exchanges in Anhui Provincial Key Project of Research(202004b11020010);Natural Science Foundation of Anhui Provincial Education Department(KJ2020A0262)

About author: CHEN Shuangshuang, Tel: (0555)2311570, E-mail: sschen1117@163.com

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	Dong XING
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	Weihuo LI

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https://www.cjmr.org/EN/10.11901/1005.3093.2020.444 OR https://www.cjmr.org/EN/Y2021/V35/I11/850

Fig.1 Relationship of heat of mixing (kJ/mol) among constituent elements in Cu-Zr-Al-Fe alloy system^[16]

Fig.2 XRD patterns of as-cast Cu_(47.8－_x₎Zr_46.2Al₆Fe_x (x=0, 0.8, 1.2, 1.6) alloy specimens with diameter of 2 mm

Fig.3 DSC curves of Fe₀、Fe_0.8 and Fe_1.2 BMGs with a diameter of 2 mm

Table 1 Summary of thermal parameters of the Fe₀、Fe_0.8 and Fe_1.2 BMGs

Fig.4 Engineering stress-strain curves for the Fe₀、Fe_0.8 and Fe_1.2 BMGs under compressive testing (a) and the enlarged serrated flow in region "I" in Fig.4a (b)

Table 2 Compressive mechanical properties of Fe₀、Fe_0.8 and Fe_1.2 BMGs, including yield stress σ_y, compressive strength σ_b, elastic strain ε_e, plastic strain ε_pand total strain ε_t

Fig.5 Percentage of stress drop in Fe_0.8and Fe_1.2 BMGs (a，b) and density of elastic energy dissipated in the shear band for the Fe_0.8and Fe_1.2BMGs varied with machine stiffness (c)

Fig.6 SEM images of the outer appearance (a, b) and fracture surface (c, d) of Fe_0.8and Fe_1.2BMGs

Fig.7 HRTEM image (a) and corresponding FFT pattern (b) of the deformed Fe_1.2BMG specimen

Fig.8 Thermal behavior of Fe_0.8and Fe_1.2 BMGs before glass transition temperature

Fig.9 Line chart of hardness changes of Fe₀、Fe_0.8 and Fe_1.2 BMGs

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