|
|
Effect of Rare Earth Addition on Microstructure, Mechanical Property and Nitriding Performance of a Medium Carbon Steel |
GUI Weimin( ), LIU Yi, ZHANG Xiaotian, HE Liangliang, WANG Ye, WANG Yuandong, HE Erkang, WANG Mengmeng |
Shaanxi Fast Gear Co. Ltd. , Xi'an 710077, China |
|
Cite this article:
GUI Weimin, LIU Yi, ZHANG Xiaotian, HE Liangliang, WANG Ye, WANG Yuandong, HE Erkang, WANG Mengmeng. Effect of Rare Earth Addition on Microstructure, Mechanical Property and Nitriding Performance of a Medium Carbon Steel. Chinese Journal of Materials Research, 2021, 35(1): 72-80.
|
Abstract Effect of rare earth microalloying on the microstructure and mechanical property of a medium carbon steel have been investigated, focusing on the influence of rare earth on the formed surface layer after nitriding heat treatment. The results indicate that by adding rare earth elements into the test steel: the original inclusions of long strips of MnS and the coarse Al2O3 convert into the small spherical inclusions of complex rare earth sulfur oxide; the ferrite volume content is reduced ,while more finer lamellar pearlites are formed; the impact energy increases by 126% and the plasticity increases by 10%. After nitriding heat treatment, it is found that the addition of rare earth elements can significantly improve the surface hardness and nitride case depth, as well as improving the vein-like structure of the nitriding layer.
|
Received: 29 May 2020
|
|
1 |
Liu K R, Yu H W, Han Q, et al. Preparation and characteristics of RE (Pr, Nd, Sm, Eu, Dy) doped TiO2 photocatalytic films [J]. Chin. J. Mater. Res., 2006, 20(5): 459
|
|
刘奎仁, 于会文, 韩庆等. 稀土掺杂TiO2光催化材料的制备和性能 [J]. 材料研究学报, 2006, 20(5): 459
|
2 |
Chen X Y. Application of rare earth in steel in China [J]. J. Rare Earth., 1992, 10(1): 61
|
3 |
Chen L X, Lei Y Q, Li S Q, et al. Research and development on high performance hydride electrode alloys [J]. Chin. J. Mater. Res., 2001, 15(1): 1
|
|
陈立新, 雷永泉, 李寿权等. 高性能贮氢电极合金的研究进展 [J]. 材料研究学报, 2001, 15(1): 1
|
4 |
Song X, Wang L, Zhao Z, et al. Effects of La on isothermal oxidation behavior of a Ni-Cr-W-Mo heat-resistant alloy at 1173K [J]. Chin. J. Mater. Res., 2009, 23(3): 275
|
|
宋秀, 王磊, 赵卓等. La对Ni-Cr-W-Mo耐热合金1173K恒温氧化行为的影响 [J]. 材料研究学报, 2009, 23(3): 275
|
5 |
Yang Q X, Ren X J, Liao B, et al. Discussion of RE inclusions as heterogeneous nuclei of primary austenite in hardfacing metals of medium-high carbon steels [J]. J. Rare Earth., 1999, 17(4): 293
|
6 |
Tang R, Liu Y N, Guo S W, et al. Properties of a non-stoichiometric LaNi5 type hydrogen storage alloy [J]. Chin. J. Mater. Res., 2002, 16(4): 395
|
|
唐睿, 柳永宁, 郭生武等. 非化学计量LaNi5型储氢合金的性能 [J]. 材料研究学报, 2002, 16(4): 395
|
7 |
Li C L, Wang Y S, Chen J J. Effects of rare earth on structure and mechanical properties of clean BNbRE steel [J]. J. Rare Earth., 2005, 23(4): 470
|
8 |
Feng X, Sui J H, Cai W, et al. Characterisation of rare earth assisted plasma carbonitrided TiNi alloys [J]. Surf. Eng., 2012, 28(8): 636
|
9 |
Ren H R. Effect of rare earth on the purifying degree and microstructure and mechanical properties of Q345H beam steel [D]. Taiyuan: Taiyuan University of Technology, 2012
|
|
任鸿儒. Ce元素对Q345H型钢的洁净度、组织和力学性能影响的研究 [D]. 太原: 太原理工大学, 2012
|
10 |
Yan R J, Dong F, Ma Z, et al. Effect of rare earth Ce on structure and mechanical properties of steel 22MnCrNiMo [J]. Journal of Inner Mongolia University of Science and Technology, 2017, 36(10): 333
|
|
闫瑞军, 董方, 马征等. 稀土Ce对22MnCrNiMo钢组织和力学性能的影响 [J]. 内蒙古科技大学学报, 2017, 36(4): 333
|
11 |
Peng J, Dong H, Bell T, et al. Effect of rare earth elements on plasma nitriding of 38CrMoAl steel [J]. Surf. Eng., 1996, 12(2): 147
|
12 |
Zhang J. Examination of plasma nitriding microstructure with addition of rare earths [J]. J. Rare Earth., 2004, 22(2): 272
|
13 |
Liu R L, Qiao Y J, Yan M F, et al. Effects of rare earth elements on the characteristics of low temperature plasma nitrocarburized martensitic stainless steel [J]. J. Mater. Sci. Technol., 2012, 28(11): 1046
|
14 |
Tian J, Zhang Q Z, Gao J. Accelerating nitriding by use of energizer [J]. Heat Treatment, 2011, 26(4): 80
|
|
田君, 张奇制, 高军. 催渗技术提高渗氮效率 [J]. 热处理, 2011, 26(4): 80
|
15 |
Chang Y W, Xu Z. Nitriding behaviors of 38CrMoAlA steel added with rare earth elements in different process [J]. Heat Treatment of Metals, 2001, 26(8): 9
|
|
常延武, 徐洲. 含稀土钢在不同工艺条件下的渗氮行为 [J]. 金属热处理, 2001, 26(8): 9
|
16 |
Han B J. Effect of rare earths content on nitriding performance of 38CrMoAl steel [J]. Surf. Technol., 2009, 38(6): 39
|
|
韩宝军. 稀土含量对38CrMoAl钢渗氮层性能的影响 [J]. 表面技术, 2009, 38(6): 39
|
17 |
Chen F S, Wang C G, Li Y X, et al. Effect of rare earth on microstructure and properties of 38CrMoAl steel plasma nitrided case [J]. Iron Steel, 2000, 35(8): 48
|
|
陈方生, 王成国, 刘玉先等. 稀土对38CrMoAl钢离子渗氮层结构和性能的影响 [J]. 钢铁, 2000, 35(8): 48
|
18 |
Yan M F, Liu R L. Influence of process time on microstructure and properties of 17-4PH steel plasma nitrocarburized with rare earths addition at low temperature [J]. Appl. Surf. Sci., 2010, 256(20): 6065
|
19 |
Tang L N, Yan M F. Effects of rare earths addition on the microstructure, wear and corrosion resistances of plasma nitrided 30CrMnSiA steel [J]. Surf. Coat. Technol., 2012, 206(8): 2363
|
20 |
Jiang H C, Yang S Q, Zhang W L, et al. Fabrication of hydrogen-resistant coatings for NdFeB rare earth permanent magnet [J]. J. Chin. Rare Earth Soc., 2002, 20(4): 382
|
|
蒋洪川, 杨仕清, 张万里等. NdFeB 稀土永磁材料阻氢涂层的制备 [J]. 中国稀土学报, 2002, 20(4): 382
|
21 |
Chen W, Wang L, Zhou L, et al. Recent researches on rapid nitriding of steel [J]. J. Wuhan Uni. Sci. Technol.(Nat. Sci. Ed.), 2006, 29(3): 225
|
|
陈玮, 王蕾, 周磊等. 钢的快速渗氮技术研究现状 [J]. 武汉科技大学学报(自然科学版), 2006, 29(3): 225
|
22 |
Mou H X. Studing appearance and kinetic of big-dimension rare earth inclusions in 5CrNiMo steels [D]. Jinan: Shandong University, 2006
|
|
牟红霞. 5CrNiMo钢中大尺寸稀土夹杂物的形貌和形成动力学研究 [D]. 济南: 山东大学, 2006
|
23 |
Wang L M, Lin Q, Yue L J, et al. Study of application of rare earth elements in advanced low alloy steels [J]. J. Alloy Compd., 2008, 451(1): 534
|
24 |
Sun B, Liu X H, Shen C, et al. Investigation on the inclusion distribution of ϕ450 mm round billet [C]. Proceedings of the 17th National Steelmaking Conference, 2013: 839
|
|
孙彪, 刘学华, 沈昶等. ϕ450 mm圆坯夹杂物分布研究 [C]. 第十七届全国炼钢学术会议文集, 2013: 839
|
25 |
Ma Z Y, Fang J, Yang Y T. Properties improvement of low alloy wear resistant steel casting for coal-mining machinery [J]. Foundry, 2011, 60(3): 302
|
|
马志英, 方静, 杨弋涛. 用于煤机的低合金耐磨铸钢性能改良研究 [J]. 铸造, 2011, 60(3): 302
|
26 |
Si T Z. Effect of RE on inclusions and mechanical properties of steel 42CrMoTiB [J]. Spe. Steel, 2013, 34(3): 56
|
|
斯庭智. 稀土对42CrMoTiB钢夹杂物和力学性能的影响 [J]. 特殊钢, 2013, 34(3): 56
|
27 |
Zhao X D, Jiang J, Hu G D, et al. Effects of Re microalloying on microstructure and properties of 5CrNiMo steel [J]. Shandong Metallurgy, 2004, 26(3): 40
|
|
赵晓栋, 姜江, 胡国栋等. 稀土微合金化对5CrNiMo钢组织和性能的影响 [J]. 山东冶金, 2004, 26(3): 40
|
28 |
Ma H T, Wu D, Zhang Y F. Rare earth adding technology and its behavior in steel for heavy-duty truck wheel [J]. J. Chin. Rare Earth Soc., 2008, 26(2): 200
|
|
马海涛, 吴迪, 张永富. 稀土添加工艺及其在重载汽车车轮钢中的作用 [J]. 中国稀土学报, 2008, 26(2): 200
|
29 |
Fan S B. Research on technique for extended service life of slab continuous casting rolls [D]. Qinhuangdao:Yanshan University, 2013
|
|
樊树宝. 板坯连铸辊长寿命技术的探究 [D]. 秦皇岛: 燕山大学, 2013
|
30 |
Zhang G Q, Dong H, Wang M Q. Study on high temperature properties of heavy-duty gear steels [J]. Iron and Steel, 2009, 44(5): 59
|
|
张国强, 董瀚, 王毛球. 重载齿轮钢的高温性能 [J]. 钢铁, 2009, 44(5): 59
|
31 |
Yang M. Effect of hierarchical microstructures of low carbon martensitic steel on fatigue damage behavior [D]. Kumming: Kumming University of Science and Technology, 2019
|
|
杨明. 低碳马氏体钢多层次组织对疲劳损伤行为的影响机制研究 [D]. 昆明: 昆明理工大学, 2019
|
32 |
Jia Z Y. Effect of shot-peening on the microstructure and mechanical properties of Al/steel dissimilar welding joints by laser [D]. Nanjing: Nanjing University of Science and Technology, 2019
|
|
贾子妍. 铝/钢异种金属的激光焊接及喷丸对接头组织和性能的影响研究 [D]. 南京: 南京理工大学, 2019
|
33 |
Tuttle R. Effect of rare earth additions on grain refinement of plain carbon steels [J]. Int. J. Metalcast., 2012, 6: 51
|
34 |
Hui C H. Research on grain refinement of 4137H steels and Sn-P bronze [D]. Dalian: Dalian University of Technology, 2007
|
|
回春华. 4137H低合金钢和锡磷青铜的晶粒细化研究 [D]. 大连: 大连理工大学, 2007
|
35 |
Liu H, Zheng D H, Xu Z Y. Effect of rare earth elements on isothermal transformation and microstructures in 20Mn steel [J]. J. Rare Earth., 1992, 10(3): 189
|
36 |
Liu C J, Jiang M F, Li C L, et al. Mechanism and effects of rare earth on the impacting toughness of heavy rail steel [C]. Proceedings of the 2005 Iron and Steel Annual Conference, 2005: 117
|
|
刘承军, 姜茂发, 李春龙等. 稀土对BNbRE重轨钢冲击韧性的影响作用 [C]. 2005年钢铁年会论文集, 2005: 117
|
37 |
Yang Q X, Zhao Y H, Li Y L, et al. Thermodynamics of modifying effect of rare earth oxide on Inclusions in hardfacing metal of medium-high carbon steel [J]. J. Rare Earth., 2002, 20(4): 291
|
38 |
Liu C J, Huang Y H, Jiang M F. Effects and mechanisms of RE on impact toughness and fracture toughness of clean heavy rail steel [J]. J. Iron Steel Res. Int., 2011, 18(3): 52
|
39 |
Wilson W G, Heaslip L J, Sommerville I D. Rare earth additions in continuously cast steel [J]. JOM, 1985, 37(9): 36
|
40 |
Waudby P E. Rare earth additions to steel [J]. Int. Mater. Rev., 1978, 23(1): 74
|
41 |
Xiong Y, Zhao W, Sun S H, et al. Evolution of pearlite microstructure during warm cross wedge rolling [J]. Chin. J. Mater. Res., 2007, 21(2): 183
|
|
熊毅, 赵文, 孙淑华等. 高碳钢中珠光体在温楔横轧过程中的组织演变 [J]. 材料研究学报, 2007, 21(2): 183
|
42 |
Huang J X, Wang J T, Zhang Z. Equal channel angular processing in a pearlitic structured steel [J]. Chin. J. Mater. Res., 2005, 19(2): 200
|
|
黄俊霞, 王经涛, 张郑. 珠光体组织的等径弯曲通道变形 [J]. 材料研究学报, 2005, 19(2): 200
|
43 |
Liu H L, Liu C J, Jiang M F. Effect of rare earths on impact toughness of a low-carbon steel [J]. Mater. Des., 2012, 33: 306
|
44 |
Wang Y X, Yan M F, Li B, et al. Surface properties of low alloy steel treated by plasma nitrocarburizing prior to laser quenching process [J]. Opt. Laser Technol., 2015, 67: 57
|
45 |
Yan L. Research on microstructure and properties of cast iron piston ring duplex treated with coating and multicomponent thermochemical treatment [D]. Chengdu: Southwest Jiaotong University, 2013
|
|
闫磊. 涂覆-低温多元共渗复合处理后铸铁活塞环组织性能研究 [D]. 成都: 西南交通大学, 2013
|
46 |
Devi M U, Mohanty O N. Plasma-nitriding of tool steels for combined percussive impact and rolling fatigue wear applications [J]. Surf. Coat. Technol., 1998, 107(1): 55
|
47 |
Yang L P, Zhang X R. Detection of loose(not dense) compound layer of nitriding-nitrocarburizing products [J]. Automobile Gear, 2013, 37
|
|
杨凌平, 张相如. 关于渗氮-氮碳共渗产品化合物层疏松(不致密)的检测 [J]. 汽车齿轮, 2013, 37
|
48 |
Yan M F, Liu Z R, Bell T. Effect of rare earths on diffusion coefficient and transfer coefficient of carbon during carburizing [J]. J. Rare Earth., 2001, 19(2): 122
|
49 |
Yan M F. Study on absorption and transport of carbon in steel during gas carburizing with rare-earth addition [J]. Mater. Chem. Phys., 2001, 70(2): 242
|
50 |
Liu R L, Yan M F, Wu D L. Microstructure and mechanical properties of 17-4PH steel plasma nitrocarburized with and without rare earths addition [J]. J. Mater. Process. Technol., 2010, 210(5): 784
|
No Suggested Reading articles found! |
|
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|
Cited |
|
|
|
|
|
Shared |
|
|
|
|
|
Discussed |
|
|
|
|