Adsorption Properties of Metal-organic Framework Material MIL-53(Al)-F127 for Bisphenol A

doi:10.11901/1005.3093.2019.466

Chinese Journal of Materials Research

2020, Vol. 34

Issue (5): 353-360 DOI: 10.11901/1005.3093.2019.466

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Adsorption Properties of Metal-organic Framework Material MIL-53(Al)-F127 for Bisphenol A

SUN Yue, LI Dawei, WEI Qufu(

)

Key Laboratory of Eco-textiles, Ministry of Education, Jiangnan University, Wuxi 214122, China

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SUN Yue, LI Dawei, WEI Qufu. Adsorption Properties of Metal-organic Framework Material MIL-53(Al)-F127 for Bisphenol A. Chinese Journal of Materials Research, 2020, 34(5): 353-360.

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Abstract

Mesostructured metal-organic framework material MIL-53(Al)-F127 was synthesized by one-step solvothermal method, and the morphology and structure of MIL-53(Al)-F127 were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffractometer (XRD), Fourier-transform infrared spectrometer (FTIR) and N₂adsorption-desorption (BET). The adsorption performance of MIL-53(Al)-F127 and the microporous structure MIL-53(Al) on bisphenol A in aqueous solution and the influence of the adsorbent concentration, pH, temperature were comparatively investigated. Results show that MIL-53(Al)-F127 exhibited good adsorption properties for bisphenol A in aqueous solution. The optimum pH level for the removal of BPA using MIL-53(Al)-F127 were 6. The optimum temperature for the sorption behavior of BPA on the sorbent was 30℃. The equilibrium sorption amounts of BPA on MIL-53-(Al)-F127 reached approximately 27.2 mg/g, the removal efficiency was 92% after approximately 20 min. The sorption kinetics of BPA were found to follow the quasi second order dynamic model.

Key words: composite metal-organic framework adsorption MIL-53(Al) MIL-53(Al)-F127 bisphenol A(BPA)

Received: 09 October 2019

ZTFLH:

TQ424.3

Fund: Natural Science Foundation of Jiangsu Province(BK20180628);Fundamental Research Funds for the Central Universities(JUSRP51907A);Priority Academic Program Development of Jiangsu Higher Education Institutions

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	Yue SUN
	Dawei LI
	Qufu WEI

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https://www.cjmr.org/EN/10.11901/1005.3093.2019.466 OR https://www.cjmr.org/EN/Y2020/V34/I5/353

Fig.1 SEM image of MIL-53(Al) (a) and MIL-53(Al)-F127 (b); TEM image of MIL-53(Al) (c) and MIL-53(Al)-F127 (d)

Fig.2 FTIR spectra of MIL-53(Al) (a) and MIL-53(Al)-F127 (b)

Fig.3 XRD pattern of MIL-53(Al) (a) and MIL-53(Al)-F127 (b)

Fig.4 Nitrogen adsorption-desorption isotherm of MIL-53(Al) and MIL-53(Al)-F127 (a) pore diameter distribution (b)

Fig.5 Sorption kinetics of MIL-53(Al) and MIL-53(Al)-F127. Effect of contact time on the BPA removal efficiency (a) and the equilibrium sorption amounts (b) pseudo-first-order kinetics model of the sorption of BPA on MIL-53(Al) and MIL-53(Al)-F127 (c, d) and pseudo-second-order kinetics model (e, f)

Fig.6 Effect of adsorbent concentation on the BPA removal efficiency

Fig.7 Effect of pH on the BPA removal efficiency

Fig.8 Effect of temperature on the BPA removal efficiency

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