Preparation and Properties of Epoxy Resin Composites Incorporated with Optical Fiber Preform Waste

doi:10.11901/1005.3093.2019.348

Chinese Journal of Materials Research

2020, Vol. 34

Issue (1): 57-63 DOI: 10.11901/1005.3093.2019.348

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Preparation and Properties of Epoxy Resin Composites Incorporated with Optical Fiber Preform Waste

SHI Congyun¹(

),WANG Jinfeng¹,CHEN Hongxiang¹,YANG Xumeng¹,DU Changjun¹,LI Guangyao¹,LIU Peng¹,CAI Haohao²

1. College of Chemistry and Chemical Engineering, Wuhan University of Science and Technology, Wuhan 430081, China
2. Wuda Jucheng Structure Co. , Ltd, Wuhan 430223, China

Cite this article:

SHI Congyun,WANG Jinfeng,CHEN Hongxiang,YANG Xumeng,DU Changjun,LI Guangyao,LIU Peng,CAI Haohao. Preparation and Properties of Epoxy Resin Composites Incorporated with Optical Fiber Preform Waste. Chinese Journal of Materials Research, 2020, 34(1): 57-63.

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Abstract

The optical fiber preform waste, an industrial by-product, was successively dried, crushed and grinded to produce fine particles, and then which are modified with coupling agents KH-570 and A-151 respectively to prepare KH-570/SiO₂and A-151/SiO₂. Further, the prepared two powders were blended respectively with epoxy resin (EP) to prepare EP based composites. The results of hydrophobicity test, FT-IR and SEM show that the two coupling agents present significant modification effect on the waste particles, however the modification effect of A-151 is better. The overall tensile properties of the composites can be ranked as the following order: A-151/SiO₂/EP>KH-570/SiO₂/EP> unmodified powder/EP, and the tensile properties are the best when the powder mass fraction was 20%. The maximum tensile strength of the above three particles modified EPs is 49.37 MPa, 45.57 MPa, and 44.36 MPa, which are 19.9%, 10.7% and 7.8% higher than that of the plain EP, respectively. Correspondingly the maximum elongations at break of the three composites are 0.92%, 0.82% and 0.46% higher than that of the plain EP, respectively. Besides the composite material prepared by filling the powder with good modification effect show better heat resistance performance.

Key words: composite optical fiber preform waste silane coupling agent epoxy resin tensile properties thermal stability

Received: 15 July 2019

ZTFLH:

TB332

Fund: Open Fund of State Key Laboratory of Optical Fiber and Cable Preparation Technology of Changfei Optical Fiber and Cable Co., Ltd(SKLD1501);Hubei Key Laboratory of Coal Conversion and New Carbon Materials(WKDM201306)

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	Articles by authors
	Congyun SHI
	Jinfeng WANG
	Hongxiang CHEN
	Xumeng YANG
	Changjun DU
	Guangyao LI
	Peng LIU
	Haohao CAI

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https://www.cjmr.org/EN/10.11901/1005.3093.2019.348 OR https://www.cjmr.org/EN/Y2020/V34/I1/57

Fig.1 Contact angle of powder pressed sheet with pure water

Fig.2 FT-IR spectrum of powder samples

Fig.3 SEM images of different powder samples (a) unmodified powder, (b) KH-570/SiO₂, (c) A-151/SiO₂

Fig.4 Schematic diagram of KH-570 and A-151 modified powder particles

Fig.5 Relationship between tensile strength and powder content of composites

Fig.6 Schematic diagram of silane coupling agent to improve the compatibility of waste particles with EP

Fig.7 Relationship between elongation at break and powder content of composites

Fig.8 TG curve of composite materials

Table 1 Temperature of composite materials under different weight loss rates

Fig.9 DTG curve of composite materials

[1]	Cheng P, Wang D Z. Epoxy Resin and Its Application [M]. Beijing: Chemical Industry Press, 2006.
[1]	(陈平，王德中. 环氧树脂及其应用 [M]. 北京：化学工业出版社， 2006)
[2]	Wu S W, Li Y Y, Chen G R, et al. Epoxy composites modified with POSS-containing block copolymer [J]. Polymer Materials Science and Engineering, 2018, 34(4): 14
[2]	(吴顺伟，李远源，陈国荣等. POSS嵌段共聚物改性环氧树脂 [J]. 高分子材料科学与工程， 2018, 34(4)： 14)
[3]	Yang G Q, Guo Y, Wang D Y, et al. Dielectric characteristics of epoxy composites modified with nano ZnO in non-uniform electrical field [J]. High Voltage Engineering, 2017, 43(9): 2825
[3]	(杨国清，郭玥，王德意等. 不均匀电场下纳米氧化锌改性环氧树脂的绝缘特性 [J]. 高压电技术， 2017, 43(9)： 2825)
[4]	Li J W, Wu Z X, Huang C J, et al. Mechanical properties of cyanate ester/epoxy resins reinforced with functionalized multi-wall carbon nanotubes [J]. Chinese Journal of Materials Research, 2014, 28(8): 561
[4]	(李静文，吴智雄，黄传军等. 多壁碳纳米管改性氰酸酯/环氧树脂基纳米复合材料的力学性能 [J]. 材料研究学报， 2014, 28(8)： 561)
[5]	Ji G Z, Zhu H Q, Jiang X W, et al. Mechanical strengths of epoxy resin composites reinforced by calcined pearl shell powders [J]. Journal of Applied Polymer Science,2009, 114: 3168
[6]	Chen Y F, Zhang X, Sun J L, et al. Properties of epoxy resin adhesive modified by nano-TiO2 [J]. Journal of Jiangsu University: Natural Science Edition, 2013, 34(3): 335
[6]	(陈宇飞，张旭，孙佳林等. 二氧化钛改性环氧树脂胶黏剂的性能 [J]. 江苏大学学报(自然科学版)， 2013, 34(3)： 335)
[7]	Xu C, Qu T G, Zhang X J, et al. Enhanced toughness and thermal conductivity for epoxy resin with a core-shell structured polyacrylic modifier and modified boron nitride. [J]. Royal Society of Chemistry, 2019, 9: 8654
[8]	Song D L, Liu S Q, Li F, et al. Effects of silane-modified nano ZrO2 on the corrosion resistance of epoxy coating on the surface of Mg-Li alloy. [J]. Chemical Journal of Chinese Universities, 2017, 38(1): 77
[8]	(宋大雷，刘思齐，李丰等. 硅烷改性纳米ZrO2对镁锂合金表面环氧树脂涂层耐蚀性能的影响 [J]. 高等学校化学学报， 2017, 38(1)： 77)
[9]	Wang Y Y, Wang S Y, Lu G J, et al. Influence of nano-AlN modification on the insulation properties of epoxy resin of dry-type transformers [J]. Transactions of China Electrotechnical Society, 2017, 32(7): 174
[9]	(王有元，王施又，陆国俊等. 纳米AlN改性对干式变压器环氧树脂绝缘性能的影响 [J]. 电工技术学报， 2017, 32(7)： 174)
[10]	Song Q C, Zhou Z, Yang C G, et al. Curing kinetics of epoxy resin modified with nano-particles and surface strength properties and friction coefficient [J]. Journal of Beijing University of Aeronautics and Astronautics, 2013, 39(4): 512
[10]	(宋起超，周真，杨春光. 纳米改性环氧树脂固化反应及表面与摩擦性能 [J]. 北京航空航天大学学报， 2013, 39(4)： 512)
[11]	Zhang R L, Liu Y S, Jin Y X. Preparation of EP/ZnO composites with needle nano ZnO and its mechanical properties [J]. Journal of Materials Engineering, 2011, 12: 78
[11]	(张荣良，柳亚输，金云学. 针状纳米ZnO制备EP/ZnO复合材料及其力学性能的研究 [J]. 材料工程， 2011, 12： 78)
[12]	Meng S S, Wang Y, Zhang B M. Preparation and mechanical properties of MWCNTs modified glass fiber [J]. Acta Materiae Compositae Sinica, 2015, 32(4): 989
[12]	(孟姗姗，王洋，张博明. 静电植绒法处理多壁碳纳米管改性玻纤织物/环氧树脂复合材料的制备及力学性能 [J]. 复合材料学报， 2015, 32(4)： 989)
[13]	Gao P Z, Lin M Q, Lin H J, et al. Study on the properties of nano-SiO2 modified epoxy composites [J]. Journal of Hunan University: Natural Science Edition, 2015, 42(6): 1
[13]	(高朋召，林明清，林海军等. 纳米二氧化硅改性环氧树脂复合材料的性能研究 [J]. 湖南大学学报(自然科学版)， 2015, 42(6)： 1)
[14]	Shi C Y, Ding J K, Wang J F, et al. Research on properties of EVA composites filled with modified optical fiber preform waste powder [J]. Inorganic Chemicals Industry, 2018, 50(10): 58
[14]	(石从云，丁家坤，王金峰等. 改性的光棒废料粉末填充EVA的复合材料性能研究 [J]. 无机盐工业， 2018, 50(10)： 58)
[15]	Su X. Effect of coupling agent with different non-hydronlytic groups on performance of modified SiO2/PDMS membrane [D]. Haerbin: Northeast Forestry University, 2017
[15]	(苏醒. 偶联剂非水解基团对改性SiO2/PDMS膜性能影响的研究 [D]. 哈尔滨：东北林业大学， 2017)
[16]	Shan S Y, Cheng P X, Yu X Y, et al. Properties of epoxy resin toughened by adding micro-SiO2 particles [J]. Chinese Journal of Colloid & Polymer, 2016, 34(1): 7
[16]	(单书燕，程品潇，于晓燕等. 超细二氧化硅微粉增韧改性环氧树脂的研究 [J]. 胶体与聚合物， 2016, 34(1)： 7)

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