Preparation and Properties of Base Metal Ni Electrode

doi:10.11901/1005.3093.2018.372

Chinese Journal of Materials Research

2019, Vol. 33

Issue (2): 131-137 DOI: 10.11901/1005.3093.2018.372

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Preparation and Properties of Base Metal Ni Electrode

Qian LUO¹,Chaobin JIANG¹,Wanxiong HUANG³,Ciyu LIU¹,Hang YAN¹,Yong CHEN¹(

),Bo YE^1,²(

)

1. School of Physics and Electronic Science, Hubei University, Laboratory of Ferro & Piezoelectric Materials and Devices of Hubei Province, Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Key Laboratory of Green Preparation and Application for Functional Materials, Ministry of Education, Hubei University, Wuhan 430062, China
2. School of Computer Science and Information Engineering, Hubei University, Wuhan 430062, China
3. Yi-Peng Optoelectronic Polytron Technologies Inc., Wuhan 430000, China

Cite this article:

Qian LUO,Chaobin JIANG,Wanxiong HUANG,Ciyu LIU,Hang YAN,Yong CHEN,Bo YE. Preparation and Properties of Base Metal Ni Electrode. Chinese Journal of Materials Research, 2019, 33(2): 131-137.

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Abstract

Nickel electrode paste was prepared with powders of Ni, B and glass as raw material and rosin containing terpineol as organic binder. Two formulae of 70%, 15% and 15% as well as 68%, 16% and 16% of Ni, B and glass (mass fraction) respectively were adopted, which were applied on PTC semiconductor porcelain and then fired in air at 790~870^oC with varying processing parameters to produce Ni electrodes. The prepared electrodes were characterized by means of SEM with EDX. The room temperature resistance and square resistance of the electrode were measured by multimeter and RTS-8 four-probe tester respectively. Results show that after fired at 810~850^oC for 20 min, the prepared Ni electrodes on PTC semiconductor porcelain and other ceramics present excellent compatibility with substrates and good electrical properties. With the increasing fire temperature, the resistance and square resistance of the electrode decrease first and then increase, however both of them are the lowest for the electrode fired at 820^oC.

Key words: metallic materials Ni electrode paste ohmic contact diffusion base metal

Received: 06 June 2018

ZTFLH:

TN304

Fund: Supported by the 3551 Optics Valley Talent Program of Wuhan(2016114);Opening Fund of Key Labora-tory of Green Preparation and Application for Functional Materials(201709)

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	Articles by authors
	Qian LUO
	Chaobin JIANG
	Wanxiong HUANG
	Ciyu LIU
	Hang YAN
	Yong CHEN
	Bo YE

URL:

https://www.cjmr.org/EN/10.11901/1005.3093.2018.372 OR https://www.cjmr.org/EN/Y2019/V33/I2/131

Table 1 Composition and function of Ni electrode paste

Table 2 Formula of Ni electrode slurry

Fig.1 Preparation process of Ni electrode slurry

Fig.2 Temperature curve of Ni electrode sample sintering process

Fig.3 Relationship between the square resistance of two groups of Ni electrodes and the sintering temperature

Fig.4 Relationship between body resistance and sintering temperature of two sets of Ni electrode samples

Fig.5 Cross section morphologies of Ni electrode samples at different sintering temperatures (a) 810℃, (b) 830℃, (c) 850℃, (d) 870℃

Fig.6 Variation of element concentration with scanning position at different sintering temperatures of electrode samples (a) 810℃， (b) 830℃， (c) 850℃， (d) 870℃

Fig.7 Change of element concentration at different scanning positions with sintering temperature (a) -25 μm， (b) 25 μm

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