Thermal Rearrangement of Acetate-functionalized Polyimides and Adsorption Properties for CO2

doi:10.11901/1005.3093.2018.280

Chinese Journal of Materials Research

2019, Vol. 33

Issue (3): 209-217 DOI: 10.11901/1005.3093.2018.280

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Thermal Rearrangement of Acetate-functionalized Polyimides and Adsorption Properties for CO₂

Yunhua LU¹(

),Guoyong XIAO¹,Lin LI²,Yan DONG¹,Haijun CHI¹,Zhizhi HU¹,Tonghua WANG²(

)

1. School of Chemical Engineering, University of Science and Technology Liaoning, Anshan 114051, China
2. State Key Lab of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China

Cite this article:

Yunhua LU,Guoyong XIAO,Lin LI,Yan DONG,Haijun CHI,Zhizhi HU,Tonghua WANG. Thermal Rearrangement of Acetate-functionalized Polyimides and Adsorption Properties for CO₂. Chinese Journal of Materials Research, 2019, 33(3): 209-217.

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Abstract

Two kinds of diamines containing ortho-hydroxyl groups and bulky moiety, 3,3'-diamino-4,4'-dihydroxytetraphenylmethane (DDTPM) and 9,9-bis (3-amino-4-hydroxyphenyl) fluorene (BAHPF) were polymerized respectively with aromatic dianhydride 2,2-bis (3,4-dicarboxyphenyl) hexafluoropropane dianhydride (6FDA) via a low-temperature solution polymerization, and next, two acetate-functionalized polyimides (PI) were prepared via chemical imidization, and thirdly, which were further thermally treated at 425^oC in N₂ atmosphere to obtain the thermally rearranged polymers. Then, the structure and property of the PIs and TR polymers were characterized by means of Fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance (NMR), thermogravimetric analysis (TGA), differential scanning calorimeter (DSC), X-ray photoelectric spectroscopy (XPS), X-ray diffraction(XRD) and gas adsorption isotherms etc. The results show that the thermal rearrangement (TR) occured partially for both of the PI(DDTPM-6FDA) and PI(BAHPF-6FDA), and the PI containing two phenyl groups show a range of thermal rearrangement temperature broader than the PI containing fluorene moieties. They show high glass transitionn temperatures (T_g) and larger interplanar crystal spacing. After the thermal treatment at 425^oC, the specific surface area of TR(DDTPM-6FDA) and TR(BAHPF-6FDA) are 198 and 582 m²/g, and their pore diameters are 0.42 and 0.44 nm, respectively. They are belong to microporous materials, and the adsorption capacity for CO₂ of TR(BAHPF-6FDA) is higher than that of TR(DDTPM-6FDA).

Key words: organic polymer materials polyimides thermally rearranged polymers acetate-func-tional CO₂ adsorption

Received: 18 April 2018

ZTFLH:

TB 324

Fund: Supported by National Natural Science Foundation of China(21878033);Supported by National Natural Science Foundation of China(21506020);Supported by National Natural Science Foundation of China(21406102);Supported by National Natural Science Foundation of China(21676044);Natural Science Foundation of Liaoning Province(20180550439);Program for Liaoning Excellent Talents in University(LJQ2015053)

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	Yunhua LU
	Guoyong XIAO
	Lin LI
	Yan DONG
	Haijun CHI
	Zhizhi HU
	Tonghua WANG

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https://www.cjmr.org/EN/10.11901/1005.3093.2018.280 OR https://www.cjmr.org/EN/Y2019/V33/I3/209

Fig.1 Synthesis of 3,3’-diamino-4,4’-dihydroxytetraphenylmethane

Fig. 2 Preparation of thermally arranged polymers

Fig.3 FTIR spectra of dihydroxyl compound, dinitro compound and diamine

Fig. 4 ¹H NMR spectra of dihydroxyl compound, dinitro compound and diamine

Fig.5 FTIR spectra of acetate-functional PI and corresponding TR polymers

Fig.6 Thermogravimetric analysis curves of acetate-functional polyimides

Fig.7 DSC curves of two acetate-functional polyimides

Fig.8 XPS curves of thermally rearranged polymers

Fig.9 XRD curves of acetate-functional polyimides and thermal rearrangement polymers

Fig.10 SEM images of thermally rearrangement polymers (a)TR(DDTPM-6FDA), (b)TR(BAHPF-6FDA)

Table 1 Solubility of acetate-functional polyimides and corresponding thermally rearranged polymers

Fig.11 N₂ adsorption-desorption isotherms of thermally rearranged polymers

Fig.12 CO₂ adsorption isotherms of thermally rearranged polymers

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