Influence of Co and Ni on Invar Effect of (Fe71.2B24Y4.8)96Nb4 Bulk Metallic Glass

doi:10.11901/1005.3093.2018.115

Chinese Journal of Materials Research

2018, Vol. 32

Issue (9): 691-696 DOI: 10.11901/1005.3093.2018.115

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Influence of Co and Ni on Invar Effect of (Fe_71.2B₂₄Y_4.8)₉₆Nb₄ Bulk Metallic Glass

Jinmiao WANG¹, Qiang HU²(

), Yihong YAN¹, Caosheng HU³, Shenghui XIE¹, Xierong ZENG^1,⁴(

)

1 College of Materials Science and Engineering, Shenzhen University, Shenzhen 518060, China
2 Institute of Applied Physics, Jiangxi Academy of Sciences, Nanchang, 330029, China
3 Jiangxi Dayou Technology Co. Ltd., Yichun 336000, China
4 Dongguan Janus Precision Components Co. Ltd., Dongguan 441900, China

Cite this article:

Jinmiao WANG, Qiang HU, Yihong YAN, Caosheng HU, Shenghui XIE, Xierong ZENG. Influence of Co and Ni on Invar Effect of (Fe_71.2B₂₄Y_4.8)₉₆Nb₄ Bulk Metallic Glass. Chinese Journal of Materials Research, 2018, 32(9): 691-696.

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Abstract

Thermal expansion behavior of bulk metallic glasses [(Fe_100-_xCo_x)_71.2B₂₄Y_4.8]₉₆Nb₄ (x=0~60) and [(Fe_100-_xNi_x)_71.2B₂₄Y_4.8]₉₆Nb₄ (x=0~20) was investigated. Results show that the Invar effect of the (Fe_71.2B₂₄Y_4.8)₉₆Nb₄ decreases after the addition of Co or Ni, and the decreasing extent is almost the same if the amount of x is the same for Co and Ni respectively. These phenomena indicate that the decreasing amount of the Fe-Fe atomic pairs is the main influence of Co and Ni on the Fe atomic local structure. In addition, the thermal expansion coefficient after the magnetic transition changes oppositely with the Curie temperature, which is mostly related to the free volume annihilation in the structural relaxation.

Key words: metallic materials Fe-based bulk metallic glasses invar effect thermal expansion Curie temperature

Received: 18 January 2018

ZTFLH:	TG139
	TG142

Fund: Science and Technology Project of Shenzhen (Nos. JCYJ20150324141711663 ＆ JCYJ20160422- 104921235) and Program of Introducing Innovative Research Team in Dongguan (No. 2014607109)

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	Jinmiao WANG
	Qiang HU
	Yihong YAN
	Caosheng HU
	Shenghui XIE
	Xierong ZENG

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https://www.cjmr.org/EN/10.11901/1005.3093.2018.115 OR https://www.cjmr.org/EN/Y2018/V32/I9/691

Fig.1 XRD patterns of [(Fe_100-_xCo_x)_71.2B₂₄Y_4.8]₉₆Nb₄ (a) and [(Fe_100-_xNi_x)_71.2B₂₄Y_4.8]₉₆Nb₄ (b) BMGs

Table 1 Atomic radius r_a, melting point T_m, Curie temperature T_c, atomic magnetic moment M and valence electron configuration VE of Fe, Co and Ni, and the mixing enthalpy of liquid T_m-B binary alloys

Fig.2 Thermal expansion of [(Fe_100-_xCo_x)_71.2B₂₄Y_4.8]₉₆Nb₄ (a) and [(Fe_100-_xNi_x)_71.2B₂₄Y_4.8]₉₆Nb₄ (b) BMGs

Fig.3 Thermal expansion coefficients of [(Fe_100-_xCo_x)_71.2B₂₄-Y_4.8]₉₆Nb₄ (a) and [(Fe_100-_xNi _x)_71.2B₂₄Y_4.8]₉₆Nb₄ (b) BMGs

Fig.4 Definition of the characteristic thermal expansion coefficients

Fig.5 Effect of Co and Ni on the characteristic thermal expansion coefficients (a, b) and (c) Curie temperature

Fig.6 Correlation between the thermal expansion coefficients and the Curie temperature after magnetic transition (a) [(Fe_100-_xCo_x)_71.2B₂₄Y_4.8]₉₆Nb₄, (b) [(Fe_100-_x-Ni_x)_71.2B₂₄Y_4.8]₉₆Nb₄

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