AgCl Nano-cubics Used as Photoinitiator for Polymerizing Monodispersed Polystyrene Microspheres

doi:10.11901/1005.3093.2016.098

Chinese Journal of Materials Research

2016, Vol. 30

Issue (11): 868-874 DOI: 10.11901/1005.3093.2016.098

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AgCl Nano-cubics Used as Photoinitiator for Polymerizing Monodispersed Polystyrene Microspheres

Ying YANG,Yan ZHAO,Yukun YAN,Jinsong ZHANG

Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China

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Ying YANG,Yan ZHAO,Yukun YAN,Jinsong ZHANG. AgCl Nano-cubics Used as Photoinitiator for Polymerizing Monodispersed Polystyrene Microspheres. Chinese Journal of Materials Research, 2016, 30(11): 868-874.

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Abstract

Mono-dispersed polystyrene microspheres were prepare by UV irradiation assisted polymerization of styrene monomer with AgCl nano-cubic particles as photoinitiator and polyvinylpyrrolidone (PVP) as dispersion stabilizer. The morphology, molecular structure and glass transition temperature of the polymers were characterized by SEM, FT-IR and DSC respectively. From the polymerization dynamics, it follows that the photopolymerization process was a first order reaction. The photopolymerization reaction could be identified as a kind of free radical polymerization, while CH₃CH₂O was the active group in the photopolymerization. Besides, AgCl nano-cubic particles were stable under UV irradiation.

Key words: organic polymer materials AgCl photoinitiate polystyrene microspheres polymerize

Received: 16 February 2016

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	Ying YANG
	Yan ZHAO
	Yukun YAN
	Jinsong ZHANG

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https://www.cjmr.org/EN/10.11901/1005.3093.2016.098 OR https://www.cjmr.org/EN/Y2016/V30/I11/868

Fig.1 SEM image of the AgCl particles (a) and size distribution of the AgCl particles (b)

Fig.2 Digital photo of AgCl colloid under UV irradiation for different time

Fig.3 SEM image of AgCl nanocubes after UV irradiation for 10 min

Fig.4 XRD patterns of AgCl nanoparticles under UV-irradiated for 0 min (a) and 120 min (b)

Fig.5 SEM image of photoinitiated polystyrene microspheres (a) and size distribution of PS microspheres (b)

Fig.6 FTIR spectra of polystyrene

Fig.7 DSC thermogram of PS (a) photoinitiated polystyrene microspheres; (b) common thermally induced polystyrene microspheres (the heating rate is 5℃/min) V_st=0.5 mL, V_AgCl=4 mL, VC2H5OH=10 mL, m_PVP=0.0375 g, reaction time=1 h

Table 1 Molecular weight determined by GPC for different reaction time

Fig.8 Kinetic curve of polymerization with different reaction time. V_St=0.5 mL, V_AgCl=4 mL, VC2H5OH=10 mL, m_PVP=0.0375 g

Table2 UV-light induced polymerization of styrene using AgCl as initiator

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