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Chinese Journal of Materials Research  2016, Vol. 30 Issue (6): 438-442    DOI: 10.11901/1005.3093.2015.656
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Influence of Carbon on Performance of Ni68.6Cr8.7Nb(3-x)P16.5B3.2Cx Amorphous Alloy
SHI Xiaogang1,2, LI Wen1,**(), YU Dechuan2,3, FU Huameng2
1. College of Materials Science and Engineering, Shenyang Ligong University, Shenyang 110159, China
2. Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
3. College of Science, Northeastern University, Shenyang 110819, China
Cite this article: 

SHI Xiaogang, LI Wen, YU Dechuan, FU Huameng. Influence of Carbon on Performance of Ni68.6Cr8.7Nb(3-x)P16.5B3.2Cx Amorphous Alloy. Chinese Journal of Materials Research, 2016, 30(6): 438-442.

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Abstract  

The influence of C content on the glass forming ability, thermal stability and corrosion resistance of Ni68.6Cr8.7Nb3P(16.5-x)B3.2Cx (x=0, 0.1, 0.3, 0.5, 0.7, 1, %) alloy was studied. The results show that an amorphous rod of 2 mm in diameter could be made for the alloy with 0.5 % C; a certain among of C addition can improve the thermal stability of the Ni-based amorphous alloy; with the increase of C amount, the corrosion resistance of amorphous ribbon in 1 mol/L H2SO4 solution is enhanced gradually.

Key words:  metallic materials      Ni-based amorphous alloy      glass forming ability      thermal stability      corrosion resistance     
Received:  16 November 2015     
ZTFLH:  TG139  
Fund: *Supported by National Natural Science Foundation of China No.51434008
About author:  **To whom correspondence should be addressed, Tel: (024)24680841, E-mail: wenli@imr.ac.cn

URL: 

https://www.cjmr.org/EN/10.11901/1005.3093.2015.656     OR     https://www.cjmr.org/EN/Y2016/V30/I6/438

Fig.1  XRD patterns of Ni68.6Cr8.7Nb3P(16.5-x)B3.2Cx(x=0, 0.1, 0.3, 0.5, 0.7, 1, %) amorphous rods with a diameter of 1.5 mm
Fig.2  XRD patterns of Ni68.6Cr8.7Nb3P(16.5-x)B3.2Cx(x=0, 0.1, 0.3, 0.5, 0.7, 1, %)amorphous rods with a diameter of 2 mm
Fig.3  DSC curves of Ni68.6Cr8.7Nb3P(16.5-x)B3.2Cx(x=0, 0.1, 0.3, 0.5, 0.7, 1, %) bulk alloys
Composition Tg /K Tx/K T/K
NiC0 718.1 742.2 24.1
NiC0.1 674.1 706.7 32.6
NiC0.3
NiC0.5 674.9 719.2 44.3
NiC0.7 690.7 712.7 22
NiC1
Table 1  Thermal parameters of Ni68.6Cr8.7Nb3P(16.5-x)B3.2Cx (x=0, 0.1, 0.3, 0.5, 0.7, 1, %) bulk alloys
Composition Tg/K Tx/K T//K
Ni68Nb32 892 932 40
Ni62Nb33Zr5 877 917 40
Ni60Nb30Ta10 934 961 27
Ni56Zr16Al9.5Y18.5 716 755 39
Ni59Zr16Ti13Si3Sn2Nb7 845 885 40
Table 2  Classical ingredients[9, 10] reported in the literatures
Fig.4  Corrosion behaviors of Ni68.6Cr8.7Nb3P (16.5-x) B3.2Cx(x=0, 0.1, 0.5, %)amorphous ribbon, (a) polarization curves of amorphous ribbon, (b) corrosion potential trend of amorphous ribbons
Fig.5  Corroded morphologies of Ni68.6Cr8.7Nb3P(16.5-x)B3.2Cx(x=0 (a), 0.1 (b), 0.5 (c), %) amorphous ribbons in 1 mol/L H2SO4 solution corrosion
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