Martensitic Transformation and Crystal Structure of Ni-Fe-Ga Ferromagnetic Shape Memory Alloys

doi:10.11901/1005.3093.2014.432

Chinese Journal of Materials Research

2014, Vol. 28

Issue (12): 881-886 DOI: 10.11901/1005.3093.2014.432

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Martensitic Transformation and Crystal Structure of Ni-Fe-Ga Ferromagnetic Shape Memory Alloys

Jing BAI^1,^2,^**(

),Xinli WANG¹,Jianglong GU¹,Yanbo LI¹,Xiang ZHAO¹,Liang ZUO¹

1. Key Laboratory for Anisotropy and Texture of Materials, Northeastern University, Shenyang 110819
2. Hebei Provincial Laboratory for Dielectric and Electrolyte Materials, Northeastern University at Qinhuangdao Branch, Qinhuangdao 066004

Cite this article:

Jing BAI,Xinli WANG,Jianglong GU,Yanbo LI,Xiang ZHAO,Liang ZUO. Martensitic Transformation and Crystal Structure of Ni-Fe-Ga Ferromagnetic Shape Memory Alloys. Chinese Journal of Materials Research, 2014, 28(12): 881-886.

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Abstract

A moderate amount of g-phase precipitates in Ni-Fe-Ga ferromagnetic shape memory alloy can drastically improve its toughness. The martensitic transformation temperature, the microstructure and the crystal structure of the complicated alloys Ni₅₀₊_xFe_25-_xGa₂₅(x=3, 4.5, 6) were investigated by DSC, XRD, SEM and TEM techniques. The results showed that the martensitic transformation temperature T_m went up along with the increasing Ni content; the Ni₅₆Fe₁₉Ga₂₅alloy exhibited a microstructure composed of fine and clear martensite lathes of several martensitic variants in different orientation. The 6M+14M mixed martensite and g-phases were detected in the Ni₅₆Fe₁₉Ga₂₅alloy by XRD and TEM. Among the investigated alloys, the Ni₅₆Fe₁₉Ga₂₅alloy had not only the most appropriate martensitic transformation temperature for practical application, but also the suitable crystal structure for facilitating the magnetostrictive strain.

Key words: metallic materials functional material Ni-Fe-Ga ferromagnetic shape memory alloys crystal structure microstructure martensitic transformation

Received: 19 August 2014

Fund: *Supported by National Natural Science Foundation of China No. 51301036, Natural Science Foundation of Hebei Province No.E2013501089, Research Fund for the Doctoral Program of Higher Education of China No.20120042110021 and the Fundamental Research Funds for the Central Universities No.N130523001.

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	Jing BAI
	Xinli WANG
	Jianglong GU
	Yanbo LI
	Xiang ZHAO
	Liang ZUO

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https://www.cjmr.org/EN/10.11901/1005.3093.2014.432 OR https://www.cjmr.org/EN/Y2014/V28/I12/881

Table 1 Characteristic martensitic transformation temperature and latent heat of Ni₅₀₊_xFe_25-_xGa₂₅(x=3, 4.5, 6) alloys (atomic fraction, %)

Table 2 Phase composition of Ni₅₀₊_xFe_25-_xGa₂₅(x=3, 4.5, 6) alloys

Fig.1 Micrographs of Ni₅₀₊_xFe_25-_xGa₂₅(x=3, 4.5, 6) alloys, (a) Ni₅₃Fe₂₂Ga₂₅ alloy, (b) Ni_54.5Fe_20.5Ga₂₅alloy, (c) Ni₅₆Fe₁₉Ga₂₅allloy

Fig.2 SEM images of Ni₅₆Fe₁₉Ga₂₅ alloy

Fig.3 XRD spectrum of Ni₅₆Fe₁₉Ga₂₅ alloy

Fig.4 TEM bright field image (a) and selected area electron diffraction pattern (b) of 6M martensite in Ni₅₆Fe₁₉Ga₂₅alloy

Fig.5 TEM bright field image (a) and selected area electron diffraction pattern (b) of 14M martensite in Ni₅₆Fe₁₉Ga₂₅alloy

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