用二次发泡法制备<strong>SiC/Al</strong>复合泡沫铝孔结构的稳定性

doi:10.11901/1005.3093.2023.543

材料研究学报

2024, Vol. 38

Issue (8): 605-613 DOI: 10.11901/1005.3093.2023.543

研究论文

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用二次发泡法制备SiC/Al复合泡沫铝孔结构的稳定性

黄闻战(

), 陈尧, 陈鹏, 张玉洁, 陈星宇

太原科技大学材料科学与工程学院太原 030024

Stability of Pore Structure of ZL102 Al-alloy Foam Prepared by Secondary Foaming Method

HUANG Wenzhan(

), CHEN Yao, CHEN Peng, ZHANG Yujie, CHEN Xingyu

School of Materials Science and Engineering, Taiyuan University of Science and Technology, Taiyuan 030024, China

引用本文:

黄闻战, 陈尧, 陈鹏, 张玉洁, 陈星宇. 用二次发泡法制备SiC/Al复合泡沫铝孔结构的稳定性[J]. 材料研究学报, 2024, 38(8): 605-613.
Wenzhan HUANG, Yao CHEN, Peng CHEN, Yujie ZHANG, Xingyu CHEN. Stability of Pore Structure of ZL102 Al-alloy Foam Prepared by Secondary Foaming Method[J]. Chinese Journal of Materials Research, 2024, 38(8): 605-613.

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摘要:

用二次发泡法制备不同SiC含量的SiC/Al复合泡沫铝前驱体，再将其在660℃~700℃发泡制备出SiC/Al复合泡沫铝，用EDS、SEM和超景深显微镜等手段对其表征，研究了SiC含量对前驱体致密度的影响、对在不同温度制备的ZL102复合泡沫铝合金的孔隙率、孔数、平均孔径和孔壁厚度的变化，以及黏度对其孔结构稳定性的影响及其机制。结果表明，提高SiC含量可提高前驱体的致密度。680℃是较为适宜的二次发泡温度。随着发泡温度的提高低黏度泡沫铝的平均孔径和孔壁厚度减小，而高黏度泡沫铝的平均孔径增大、孔壁厚度减小。高黏度泡沫铝的孔结构稳定，其孔隙率更高。

关键词 ：复合材料, 金属基, 泡沫铝, 二次发泡, 熔体黏度, SiC含量

Abstract：

SiC / ZL102 Al-alloy composite foam was prepared via secondary foaming process in the temperature range of 660^oC~700^oC, by taking the prepared SiC/ZL102 Al-alloy composites with addition of appropriate foaming agent and various SiC amount as precursors. The influence of viscosity of melt composites on the stability of ZL102 Al-alloy foam was studied by revealing the relation between the SiC content with the density of precursor, the variation of porosity, pore number, average pore size and pore wall thickness of the prepared ZL102 Al-alloy foams at different temperatures. The acquired foams were characterized by means of EDS, SEM and super deep field microscope. The results show that with the increasing SiC content the density of the precursors is increased, whilst, the density, precursor with 6wt.%SiC is the highest. The suitable secondary foaming temperature is 680^oC. With the increasing foaming temperature, the average pore size and pore wall thickness of low viscosity Al-alloy foam decrease, while the average pore size of high viscosity Al-alloy foam increases and the pore wall thickness decreases. The high viscosity Al-alloy foam has stable pore structure and higher porosity.

Key words： composites metal matrix aluminum foam secondary foaming melt viscosity SiC content

收稿日期: 2023-11-08

ZTFLH:

TB331

基金资助:太原科技大学博士科研启动资金(20192066);来晋优秀博士基金(20202021);山西省高等学校科技创新(2020L0342)

通讯作者: 黄闻战，副教授，2019063@tyust.edu.cn，研究方向为轻质金属材料/多孔材料

Corresponding author: HUANG Wenzhan, Tel: 13889234335, E-mail: 2019063@tyust.edu.cn

作者简介: 黄闻战，男，1989年生，博士

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https://www.cjmr.org/CN/10.11901/1005.3093.2023.543 或 https://www.cjmr.org/CN/Y2024/V38/I8/605

图1 制备前驱体的工艺流程

图2 用二次发泡法制备复合泡沫铝的工艺流程

图3 SiC含量对前驱体致密度的影响

图4 在680℃制备的泡沫铝前驱体的组织

图5 在660℃~700℃制备的1%~8%SiC泡沫铝的二值化图像

图6 在660℃~720℃制备的1%~8%SiC泡沫铝的孔隙率

图7 在680℃制备的1%~8%SiC泡沫铝的金相组织

图8 在680℃制备的6%SiC复合泡沫铝的SEM和EDS图片

图9 在660℃~720℃制备的1%~8%SiC复合泡沫铝孔数的变化

图10 在660℃~720℃制备的1%~8%SiC复合泡沫铝的平均孔径

图11 在660℃~720℃制备的1%~8%SiC复合泡沫铝孔壁厚度的变化

1	Tan W, Yuan L, Can X Z, et al. Fabrication, properties, and applications of open-cell aluminum foams: A review [J]. J. Mater. Sci. Technol., 2021, 62: 11 doi: 10.1016/j.jmst.2020.05.039
2	Wang H, Zhu D, Hou S, et al. Cellular structure and energy absorption of Al Cu alloy foams fabricated via a two-step foaming method [J]. Mater. Des., 2020, 196: 109090
3	Zhang Y. Fluidity of aluminum foam melt and its effect on pore structure [D]. Nanjing: Southeast University., 2021
3	张益. 泡沫铝熔体的流动性能及其对孔结构的影响 [D]. 南京: 东南大学, 2021
4	Marvi-Mashhadi M, Lopes C S, Llorca J. Surrogate models of the influence of the microstructure on the mechanical properties of closed- and open-cell foams [J]. J. Mater. Sci., 2018, 53: 12937
5	Islam M, Kader M, Hazell P, et al. Investigation of microstructural and mechanical properties of cell walls of closed-cell aluminium alloy foams [J]. Mater. Sci. Eng. A., 2016, 666: 245
6	Guang Z Y, Yan X L, Xu Z, et al. Preparation of complex shaped aluminum foam by a novel casting-foaming method [J]. Mater. Lett., 2021, 293: 129673
7	Hong X C, Liu Y Z, Huang B. Microstructure, properties and strengthening mechanism of TiC/ SiC synergistic reinforced aluminum matrix composites by selective laser melting [J]. Chin. J. Nonferrous Met., 2021, 31(9): 2436
7	洪旭潮, 刘允中, 黄斌. 激光选区熔化成形TiC/SiC协同增强铝基复合材料的组织性能与强化机制 [J]. 中国有色金属学报, 2021, 31(9): 2436
8	Hui P L, Feng X W, Ge C D, et al. Preparation and characterization of different surface modified SiCp reinforced Al-matrix composites [J]. J. Cent. South Univ., 2020, 27: 2567
9	Saravana K M, Begum S R, Pruncu C, et al. Role of homogeneous distribution of SiC reinforcement on the characteristics of stir casted Al-SiC composites [J]. J. Alloys Compd., 2021, 869: 159250
10	Xiu Z, Yang W, Dong R, et al. Microstructure and mechanical properties of 45vol.%SiCp/7075Al composite [J]. J. Mater. Sci. Technol., 2015, 31(9): 930
11	Shikang F, Insung H, Andrew L, et al. Investigating metal solidification with x-ray imaging [J]. Met., 2022, 12(3): 395
12	Lin H. Basic research on the preparation of steel-aluminum composite foam aluminum sandwich panels [D]. Shenyang: Northeastern University., 2018
12	林皓. 钢铝复合泡沫铝夹芯板制备的基础研究 [D]. 沈阳: 东北大学, 2018
13	Liang X. Preparation and properties of silicon carbide mesh porous ceramics for porous media combustion [D]. Wuhan: Wuhan University of Science and Technology, 2017
13	梁雄. 多孔介质燃烧用碳化硅网状多孔陶瓷的制备及性能研究 [D]. 武汉: 武汉科技大学, 2017
14	Imran M, Khan A A. Characterization of Al-7075 metal matrix composites: a review [J]. J. Mater. Res. Technol., 2019, 8(3): 3347 doi: 10.1016/j.jmrt.2017.10.012
15	Miao Q, Zuo X Q, Zhou Y, et al. The pore structure, mechanical properties, sound absorption properties and mechanism of 304 stainless steel fiber/ZL104 aluminum alloy composite foam were studied [J]. Chin. J. Mater. Res., 2023, 37(3): 175
15	苗琪, 左孝青, 周芸等. 304不锈钢纤维/ZL104铝合金复合泡沫的孔结构、力学、吸声性能及其机理 [J]. 材料研究学报, 2023, 37(3): 175
16	Dong C G, Wang R C, Peng C Q, et al. Research progress of SiCp/Al composites [J]. Chin. J. Nonferrous Met., 2021, 31(11): 3161
16	董翠鸽, 王日初, 彭超群等. SiCp/Al复合材料研究进展 [J]. 中国有色金属学报, 2021, 31(11): 3161
17	Zhu Z Q, Wang Q P, Min F F, et al. Research progress on interface control of SiCp/Al composites [J]. Mat. Guide., 2021, 35(13): 13139
17	朱志强, 王庆平, 闵凡飞等. SiCp/Al复合材料界面调控研究进展 [J]. 材料导报, 2021, 35(13): 13139
18	Ma H Y, Zhang J S, An Y K. Research status of the stable forming mechanism of tackifier in aluminum foam [J]. Func. Mater., 2022, 53(6): 6040
18	马浩源, 张均闪, 安钰坤. 增粘剂在泡沫铝孔泡稳定成形机制研究现状 [J]. 功能材料, 2022, 53(6): 6040 doi: 10.3969/j.issn.1001-9731.2022.06.007
19	Xing L Y, Li Y F, Chen X B. The position and role of advanced composite materials in the development of aviation equipment [J]. J. Compos. Mater., 2022, 39(9): 4179
19	邢丽英, 李亚锋, 陈祥宝. 先进复合材料在航空装备发展中的地位与作用 [J]. 复合材料学报, 2022, 39(9): 4179
20	Navya K, Prasanta J, Satish S, et al. Processing and characterization of Al-Si alloy/SiC foam interpenetrating phase composite [J]. Mat. Today: Proc., 2021, 44(P2): 2930
21	Xie D H, Pan R, Zhu S Z, et al. Effect of particle size on microstructure and mechanical properties of B4C/Al-Zn-Mg-Cu composites [J]. Chin. J. Mater. Res., 2023, 37(10): 731
21	谢东航, 潘冉, 朱士泽等. 增强颗粒尺寸对B4C/Al-Zn-Mg-Cu复合材料微观组织及力学性能的影响 [J]. 材料研究学报, 2023, 37(10): 731 doi: 10.11901/1005.3093.2022.574
22	Xu Y, Deng Y, Casari D, et al. In-situ X-radiographic study of nucleation and growth behaviour of primary silicon particles during solidification of a hypereutectic Al-Si alloy [J]. J. Alloys Compd., 2020, 832: 154948
23	Yu H, Dong Q, Chen Y, et al. Influence of silicon on growth mechanism of micro-arc oxidation coating on cast Al-Si alloy [J]. R. Soc. Open Sci., 2018, 5(7): 172428
24	Luksch J, Bleistein T, Koenig K, et al. Microstructural damage behaviour of Al foams [J]. Acta Mater., 2021(6): 116739
25	Wang F, Bian Y, Wang L, et al. Foaming behavior of microsized aluminum foam using hot rolling precursor [J]. Metals, 2023, 13(5): 928
26	Wang J K, Zhang Y Z, Li S S, et al. Preparation of 3C-SiC by carbothermal reduction of diatomite catalyzed by Fe and its mechanism [J]. Chin. J. Mater. Res., 2018, 32(10): 767
26	王军凯, 张远卓, 李赛赛等. Fe催化硅藻土碳热还原反应制备3C-SiC及其机理 [J]. 材料研究学报, 2018, 32(10): 767 doi: 10.11901/1005.3093.2017.533
27	Zhou C L. Preparation and properties of Ti₃SiC₂ ceramics and their reinforced Al matrix composites [D]. Guangzhou: South China University of Technology, 2017
27	周超兰. Ti₃SiC₂陶瓷及其增强Al基复合材料的制备与性能研究 [D]. 广州: 华南理工大学, 2017
28	Zhou X Y, Qin J, Liu X Q, et al. The relationship between cell wall thickness, porosity and average pore size of aluminum foam [J]. Mater. Rep., 2010, 24(4): 75
28	周向阳, 覃静, 刘希泉等. 泡沫铝孔壁厚度、孔隙率和平均孔径之间的关系 [J]. 材料导报, 2010, 24(4): 75

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