氟化六方氮化硼的制备及其作为水基添加剂的摩擦学性能

doi:10.11901/1005.3093.2023.383

材料研究学报

2024, Vol. 38

Issue (6): 410-422 DOI: 10.11901/1005.3093.2023.383

研究论文

本期目录 | 过刊浏览

氟化六方氮化硼的制备及其作为水基添加剂的摩擦学性能

王伟¹(

), 常文娟¹, 吕凡凡¹, 解泽磊¹, 于呈呈²

^1.西安建筑科技大学冶金工程学院西安 710055
^2.季华实验室佛山 528200

Preparation and Tribological Properties of Fluorinated Boron Nitride Nanosheets Water-based Additive

WANG Wei¹(

), CHANG Wenjuan¹, LV Fanfan¹, XIE Zelei¹, YU Chengcheng²

^1.Xi'an University of Architecture and Technology College of Metallurgical Engineering, Xi'an 710055, China
^2.Jihua Laboratory, Foshan 528200, China

引用本文:

王伟, 常文娟, 吕凡凡, 解泽磊, 于呈呈. 氟化六方氮化硼的制备及其作为水基添加剂的摩擦学性能[J]. 材料研究学报, 2024, 38(6): 410-422.
Wei WANG, Wenjuan CHANG, Fanfan LV, Zelei XIE, Chengcheng YU. Preparation and Tribological Properties of Fluorinated Boron Nitride Nanosheets Water-based Additive[J]. Chinese Journal of Materials Research, 2024, 38(6): 410-422.

全文: PDF(26848 KB) HTML

摘要:

对NH₄F氟源进行恒温磁力搅拌和球磨辅助氟化，制备出氟化氮化硼纳米片(F-BNNSs)，在接触Ti6-Al-4V(TC4)/GCr15的条件下研究了六方氮化硼纳米片(h-BNNSs)和氟化氮化硼纳米片(F-BNNSs)作为水基润滑添加剂的摩擦学行为。结果表明，随着h-BN与NH₄F的质量比从1∶2提高到1∶4这种水基润滑添加剂的平均摩擦系数先由0.3135降低到0.1435然后提高到0.2177。h-BN与NH₄F的质量比为1∶3时的F-BNNSs₁₂其摩擦系数和磨损率比h-BNNSs分别降低了55%和75%。基于磨损痕迹的分析结果表明，F-BNNSs₁₂良好的减磨耐磨性能可归因于：1、纳米片层间相互作用的减弱使相对滑动变得容易；2、F-BNNSs₁₂的不相称纳米棒-纳米片结构形成滚动摩擦使其润滑性能良好；3、F-BNNSs₁₂沉积在摩擦副表面生成不连续的润滑膜，避免了与摩擦副的直接接触。

关键词 ：无机非金属材料, 六方氮化硼, 氟化氮化硼纳米片, 水基润滑添加剂, 摩擦学性能

Abstract：

Hexagonal boron nitride (h-BN) is a typical layered structure material with enormous potential in the field of friction and lubrication. Fluorinated boron nitride nanosheets (F-BNNSs) were prepared by constant temperature magnetic stirring and ball mill-assisted fluorination using NH₄F as fluorine sourced, while h-BN as raw material. Tribological behavior of hexagonal boron nitride nanosheets (h-BNNSs) and F-BNNSs as water-based lubricant additives were evaluated under Ti6-Al-4V(TC4)/GCr15 contact conditions. The results showed that when as water based liblicant additives, the F-BNNSs prepared with the mass ratio of h-BN to NH₄F increased from 1:2 to 1:4, the resulted average coefficients of friction (COFs) varied from 0.3135 to 0.1435 to 0.2177. When the mass ratio of h-BN and NH₄F was 1:3, the COFs and wear rate of F-BNNSs₁₂ prepared were 55% and 75% lower than that of h-BNNSs, respectively. Based on the analysis of wear scars, it were found that the excellent friction reduction and anti-wear performance of F-BNNSs₁₂ can be attributed to three aspects: The weakening polar interactions between the nanosheet layers may facilitate the relative slidding; F-BNNSs₁₂ incommensurate nanorod-nanosheet structure may cause rolling friction and good lubrication performance; F-BNNSs₁₂ deposited on the surface of the friction pair favour forminga discontinuous lubricating film, to alleviate the direct contact for the friction pair.

Key words： inorganic non-metallic materials hexagonal boron nitride fluorinated boron nitride nanosheets water-based lubrication additives tribological properties

收稿日期: 2023-08-11

ZTFLH:

TB332

基金资助:国家自然科学基金(51975450);陕西省科技新星基金(2021KJXX-32);西安市创新能力强基计划-先进制造技术攻关项目(21XJZZ0031);陕西省教育厅服务地方专项(22JC047);陕西省重点研发计划(2023-YBGY-383)

通讯作者: 王伟，教授，gackmol@163.com，研究方向为材料加工中的摩擦与润滑

Corresponding author: WANG Wei, Tel: 13609264618, E-mail: gackmol@163.com

作者简介: 王伟，男，1985年生，博士

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https://www.cjmr.org/CN/10.11901/1005.3093.2023.383 或 https://www.cjmr.org/CN/Y2024/V38/I6/410

图1 F-BNNSs制备过程的示意图

表1 摩擦实验参数

图2 F-BNNSs的XRD谱以及局部放大和F-BNNSs的红外光谱

图3 F-BNNS的XPS图和F-BNNSs12的窄谱

图4 h-BNNSs和F-BNNSs的SEM照片

图5 F-BNNSs12的TEM、SAED图像和粒径统计

图6 NH4F氟化h-BN原理图

图7 F-BNNSs水基润滑添加剂的 Zeta 电位值和接触角

图8 h-BNNSs和F-BNNSs的摩擦学性能

图9 h-BNNSs和F-BNNSs的磨损表面SEM图像

图10 不同载荷下磨损表面的SEM照片

图11 TC4盘磨痕表面的磨损轨道、三维轮廓图和二维高度轮廓曲线

图12 1 mg/mL F-BNNSs12水基润滑磨损表面的Raman谱和XPS谱

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