碳含量对<strong>CrN:a-C</strong>多相复合涂层摩擦学性能的影响

doi:10.11901/1005.3093.2023.192

材料研究学报

2024, Vol. 38

Issue (4): 297-307 DOI: 10.11901/1005.3093.2023.192

研究论文

本期目录 | 过刊浏览

碳含量对CrN:a-C多相复合涂层摩擦学性能的影响

马飞¹^,³, 王闯², 郭武明²(

), 史祥东¹^,³, 孙建颖¹^,³, 庞刚¹^,³

^1.内燃机与动力系统全国重点实验室潍坊 261061
^2.中国科学院宁波材料技术与工程研究所中国科学院海洋新材料与应用技术重点实验室浙江省海洋材料与防护技术重点实验室宁波 315201
^3.潍柴动力股份有限公司潍坊 261061

Effect of Carbon Content on Tribological Properties of CrN:a-C Multiphase Composite Coatings

MA Fei¹^,³, WANG Chuang², GUO Wuming²(

), SHI Xiangdong¹^,³, SUN Jianying¹^,³, PANG Gang¹^,³

^1.State Key Laboratory of Engine Reliability, Weifang 261061, China
^2.Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
^3.Weichai Power Co. Ltd., Weifang 261061, China

引用本文:

马飞, 王闯, 郭武明, 史祥东, 孙建颖, 庞刚. 碳含量对CrN:a-C多相复合涂层摩擦学性能的影响[J]. 材料研究学报, 2024, 38(4): 297-307.
Fei MA, Chuang WANG, Wuming GUO, Xiangdong SHI, Jianying SUN, Gang PANG. Effect of Carbon Content on Tribological Properties of CrN:a-C Multiphase Composite Coatings[J]. Chinese Journal of Materials Research, 2024, 38(4): 297-307.

全文: PDF(26481 KB) HTML

摘要:

分别以Cr靶、N₂与C₂H₂作为Cr源、氮源与碳源，采用多弧离子镀技术制备CrN:a-C多相复合涂层，通过调节C₂H₂的流量改变涂层中碳的含量，使用X射线衍射仪(XRD)、拉曼光谱(Raman)、场发射扫描电镜热场(FE-SEM)、多功能摩擦磨损试验机等手段研究了碳含量对其组成结构、机械性能以及摩擦学性能的影响。结果表明：随着涂层内碳含量的提高涂层非晶碳的结构特征逐渐明显和涂层致密性降低，使机械性能降低但是其结合力和硬度仍然比较高。在干摩擦和5W-30润滑油环境中涂层均呈现出较好的低摩擦与低磨损特性。碳含量和摩擦产物的影响，使摩擦系数和磨损率在两种环境中均先提高后降低。在C₂H₂流量为120 sccm的条件下在干摩擦和润滑油环境中涂层的摩擦系数分别为0.33和0.12，磨损率分别为1.3 × 10^-5 mm³/(N·m)和7.4 × 10^-6 mm³/(N·m)，可为摩擦副部件提供有效的减磨抗磨防护作用。

关键词 ：材料表面与界面, CrN：a-C多相复合涂层, 氮化铬, 非晶碳, 摩擦学性能

Abstract：

Multiphase composite coatings CrN:a-C were deposited by multi-arc ion plating technology with Cr target, gases N₂ and C₂H₂ as source of Cr, N and C, respectively. The carbon content of the coating can be regulated by adjusting the C₂H₂ flow rate. The effect of carbon content on the composition, structure, mechanical properties, and tribological properties of CrN:a-C multiphase composite coatings was assessed by means of X-ray diffractometer (XRD), Raman spectroscope, field emission scanning electron microscope (FE-SEM), and multifunctional friction -wear tester. The results indicated that with the increase of carbon content, the structural characteristics of amorphous carbon of the coating were gradually obvious, while the compactness of the coating was decreased, which leads to the gradual decrease of the mechanical properties, but it still shows a higher hardness and adhesive strength to the substrate. CrN:a-C multiphase composite coatings exhibited better characteristics of low coefficient of friction and low wear rate during dry friction and friction in the presence of lubricating oil 5W-30, which are affected by carbon content and friction products. The coefficient of friction (CoF) and wear rate increase first and then decrease in conditions of dry friction and friction with lubricating oil respectively. Among others, the coating prepared by the C₂H₂ flow rate of 120 sccm presented CoF of 0.33 and 0.12, and wear rate of 1.3 × 10^-5 mm³/(N·m) and 7.4 × 10^-6 mm³/(N·m) in conditions of dry friction and friction with lubricating oil respectively, which was expected to provide effective anti-friction and anti-wear protection for friction pair.

Key words： surface and interface of material CrN:a-C multiphase composite coating chromium nitride amorphous carbon tribological properties

收稿日期: 2023-03-21

ZTFLH:

TG142.7

基金资助:内燃机可靠性国家重点实验室开放基金(SKLER-201902)

通讯作者: 郭武明，guowuming@nimte.ac.cn，研究方向为材料表面防护工程

Corresponding author: GUO Wuming, Tel: 15394317731, E-mail: guowuming@nimte.ac.cn

作者简介: 马飞，男，1984年生，高级工程师

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图1 CrN:a-C多相复合涂层的XRD谱

图2 涂层表面的拉曼曲线

图3 铸铁横截面的形貌

图4 316不锈钢表面CrN:a-C多相复合涂层的形貌

图5 316表面CrN:a-C多相复合涂层划痕的测试曲线和SEM形貌

图6 316表面CrN:a-C多相复合涂层的硬度曲线和压痕的光学显微照片

图7 大气环境下的摩擦曲线和摩擦平均系数与磨损率

图8 大气环境下磨痕的3D轮廓形貌以及磨痕截面曲线

图9 大气环境下磨痕的SEM形貌

图10 涂层磨痕处的拉曼曲线

图11 在油环境下的摩擦曲线、摩擦平均系数与磨损率

图12 油环境下磨痕3D轮廓形貌(1)以及磨痕截面曲线(2)

图13 在油环境中磨痕的SEM形貌

图14 摩擦磨损机理

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