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材料研究学报  2013, Vol. 27 Issue (3): 267-272    
  研究论文 本期目录 | 过刊浏览 |
施加超声波电沉积制备Co-Ni合金层*
盛敏奇1,2,钟庆东2,吕臣凯1,万康1
1 苏州大学沙钢钢铁学院 苏州 215021
2 上海大学上海市现代冶金与材料制备重点实验室 上海 200072
Preparation of Co-Ni Alloy Coatings by Ultrasound Electrodeposition
SHENG Minqi1,2** ZHONG Qingdong2 LV Chenkai1 WAN Kang1
1. Shagang School of Iron and Steel, Soochow University, Suzhou 215021
2. Shanghai Key Laboratory of Modern Metallurgy and Material Processing, Shanghai University,
Shanghai 200072
引用本文:

盛敏奇,钟庆东, 吕臣凯, 万康. 施加超声波电沉积制备Co-Ni合金层*[J]. 材料研究学报, 2013, 27(3): 267-272.
SHENG Minqi, ZHONG Qingdong, LV Chenkai, WAN Kang. Preparation of Co-Ni Alloy Coatings by Ultrasound Electrodeposition[J]. Chinese Journal of Materials Research, 2013, 27(3): 267-272.

全文: PDF(3469 KB)  
摘要: 研究了超声波(100 W, 100 kHz)对电沉积Co-Ni合金层的结构、形貌和性能的影响。结果表明: 施加超声波可有效降低电沉积过程中浓差扩散的影响, 促进阴极表面与镀液界面间的电子转移。超声波可降低Co-Ni合金层的Co含量并细化晶粒, 使Co-Ni合金层更为平整。超声波影响Co-Ni合金层结构和形貌, 可提高Co-Ni合金层的硬度以及在3.5%NaCl溶液中的耐腐蚀性。
关键词 材料失效与保护Co-Ni合金层电沉积静态超声波电化学    
Abstract:The effects of ultrasound agitation (100 W, 100 kHz) on the structure, morphology and properties of electrodeposited Co-Ni alloy coatings were investigated in this paper. The result shows that: when ultrasonic agitation was used during the alloy coating electrodeposition, the concentration diffusion was effectively reduced, and the electron transfer between the cathode/solution interface was also promoted. Ultrasound agitation leads to the increase of Co content in alloy coating. The Co-Ni alloy coating deposited under ultrasound agitation is more fine-grained and uniform. The ultrasound agitation can lead to the enhancement of hardness and corrosion resistance properties of Co-Ni alloy coatings.
Key wordsmaterials failure and protection    Co-Ni alloy coatings    electrodeposition    silent    ultrasound    electrochemistry
收稿日期: 2013-04-01     
ZTFLH:  TB304  
基金资助:* 国家自然科学基金 (51204115, 50615024)和新世纪优秀人才支持计划(NCET-07-0536)资助项目。
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