材料研究学报  2013, Vol. 27 Issue (2): 183-188

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低碳钢表面Fe-Ni合金层的制备及耐腐蚀性能

盛敏奇1, 2 许继芳1, 2 万康1 吕臣凯1

1. 苏州大学 沙钢钢铁学院 苏州 215021 2. 上海大学 上海市现代冶金与材料制备重点实验室 上海 200072

Preparation and Corrosion Resistance Performance of Fe-Ni Alloy Coating on Surface of Mild Steel

SHENG Minqi1, 2 XU Jifang1, 2* WAN Kang1 LV Chenkai1

1. Shagang School of Iron and Steel, Soochow University, Suzhou, Jiangsu 215021 2. Shanghai Key Laboratory of Modern Metallurgy and Material Processing, Shanghai University, Shanghai 200072

盛敏奇 许继芳 万康, 吕臣凯. 低碳钢表面Fe-Ni合金层的制备及耐腐蚀性能[J]. 材料研究学报, 2013, 27(2): 183-188.
. Preparation and Corrosion Resistance Performance of Fe-Ni Alloy Coating on Surface of Mild Steel[J]. Chinese Journal of Materials Research, 2013, 27(2): 183-188.

摘要 参考文献 相关文章 Metrics 全文: PDF(3594 KB)   摘要: 以纳米NiO粉体为Ni源, 通过热扩渗在低碳钢表面制备Fe-Ni合金层, 研究了处理温度对Fe-Ni合金层表面状态、结构和耐腐蚀性能的影响。结果表明: 处理温度高于800 ℃可在低碳钢表面形成厚度20—25 μm、表面Ni含量(原子分数)高于25%、与低碳钢基底形成了冶金结合的Fe-Ni合金层, 处理温度不低于900 ℃时Fe-Ni合金层为单一α-Fe固溶体相。随着处理温度的提高, Fe-Ni合金层在质量分数为3.5%NaCl溶液中的耐腐蚀性能提高。在3.5%的NaCl溶液中Fe-Ni合金层的Ecorr均较低碳钢的Ecorr发生了正移, Fe-Ni合金层的icorr均较低碳钢的icorr有不同程度的降低, Fe-Ni合金层的电化学阻抗均大于低碳钢的电化学阻抗。 关键词 ： 材料失效与保护,  低碳钢,  Fe-Ni合金层,  热扩渗,  电化学,  腐蚀     Abstract： Fe-Ni alloy coatings were prepared on the surface of mild steel by means of thermal diffusion, using nano-NiO powder as the source of Ni element. The effects of treatment temperature on surface state, structure and corrosion resistance of the Fe-Ni alloy coatings were investigated. The result shows that: when the treatment temperature was higher than 800 ℃, 20-25 μm Fe-Ni alloy coatings formed and Ni content (atomic fraction) were higher than 25% on the surface, the coating and the substrate was integrated to metallurgy structure. When the treatment temperature was higher than 900 ℃, Fe-Ni alloy structure became single α-Fe solid solution phase. The corrosion resistance of Fe-Ni alloy coatings increased with the treatment temperature from 700 to 1000 ℃. In contrast with mild steel in 3.5%NaCl solution, the Fe-Ni alloy coatings have more positive corrosion potential, much lower corrosion current density. The electrochemical impedance of Fe-Ni alloy coatings was also bigger than that of mild steel in 3.5%NaCl solution. Key words： materials failure and protection    mild steel    Fe-Ni alloy coating    thermal diffusion    electrochemical    corrosion      ZTFLH:  TB304   服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 44.8K 链接本文: https://www.cjmr.org/CN/      或      https://www.cjmr.org/CN/Y2013/V27/I2/183 1 Li Zhuang, Wu Di, Lv Wei, Effects of rolling and cooling conditions on microstructure and mechanical properties of low carbon cold heading steel, Journal of Iron and Steel Research, International, 19(11), 64(2012) 2 LIU Jing, LU Shouli, Relationship between microstructure and properties in low carbon steel, Journal of University of Science and Technology Beijing, 24(2), 208(2002) (刘 靖, 鹿守理, 低碳钢组织与力学性能关系, 北京科技大学学报, 24(2), 208(2002)) 3 Yang Kun, Gou Huiyang, Zhang Bo, Huang Rui, Li Hui, Lu Manman, Zhang Xiangyi, Microstructures and fracture features of cold-rolled low carbon steel sheet after annealing and mechanical stress concurrently loaded, Materials Science and Engineering: A, 502(1-2), 126(2009) 4 Songjeng Huang, V. 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