TA2纯钛微弧氧化陶瓷膜层的颜色和性能

材料研究学报

2010, Vol. 24

Issue (4): 395-400

研究论文

本期目录 | 过刊浏览

TA2纯钛微弧氧化陶瓷膜层的颜色和性能

唐辉¹, 王欣宇², 于德珍², 王云龙¹, 于维先², 王福平¹

1.哈尔滨工业大学化工学院哈尔滨 150001
2.哈尔滨工业大学材料学院哈尔滨 150001

On the Color and Properties of the Coatings on Titanium by Micro–Arc Oxidation

TANG Hui¹, WANG Xinyu², YU Dezheng², WANG Yunlong¹, YU Weixian², WANG Fuping¹

1.School of Chemical Engineering & Technology, Harbin Institute of Technology, Harbin 150001
2. school of Material Science and Engineering, Harbin Institute of Technology, Harbin 150001

引用本文:

唐辉王欣宇于德珍王云龙于维先王福平 . TA2纯钛微弧氧化陶瓷膜层的颜色和性能[J]. 材料研究学报, 2010, 24(4): 395-400.
, , , , , . On the Color and Properties of the Coatings on Titanium by Micro–Arc Oxidation[J]. Chin J Mater Res, 2010, 24(4): 395-400.

全文: PDF(922 KB)

摘要:

在添加乙酸铜、乙酸镁的磷酸--氟锆酸钾电解液中对纯钛TA2基体进行微弧氧化处理, 制备出颜色均匀的浅棕色陶瓷膜层。通过X射线衍射分析(XRD)、扫描电子显微分析(SEM)及附带的能谱(EDS), 研究了陶瓷膜的表面和截面形貌、元素分布、相组成; 用分光光度计测量了膜层的颜色, 根据热震试验和三点弯曲法评价了膜层与基体的结合强度。结果表明: 随着微弧氧化时间的延长, 膜层中铜镁元素的含量增加, 膜层的颜色随之发生变化, 膜层与基体的结合强度降低。热震实验结果表明, 膜层与基体有较高的结合强度。

关键词 ：材料表面与界面 , 微弧氧化 , 钛 , 浅棕色 , 结合强度

Abstract：

A light brown ceramic coating was obtained on TA2 pure titanium substrate by micro–arc oxidation in the H3PO4–K2ZrF6 electrolyte system containing Cu(CH3COO)2 and Mg(CH3COO)2. The XRD, SEM, EDS methods were employed to investigate the phase constitutes, element compositions and morphologies of the coatings. The color of coatings were tested by spectrophotometer, the adhesion strength of the coatings to substrate were investigated by thermal impact and three–point bending method. The results show that with increasing oxidation time, the content of copper and magnesium element were added and the color of the coatings changed too, and bonding strength was reduced. After thermal shock
the coating and the substrate remains a high bonging strength.

Key words： surface and interface in the materials micro–arc oxidation titanium light brown color bonding strength

收稿日期: 2010-05-05

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