铝空气电池<strong>Al-Zn-In-Mg-Ga-Mn</strong>合金阳极的电化学性能

doi:10.11901/1005.3093.2023.256

材料研究学报

2024, Vol. 38

Issue (4): 257-268 DOI: 10.11901/1005.3093.2023.256

研究论文

本期目录 | 过刊浏览

铝空气电池Al-Zn-In-Mg-Ga-Mn合金阳极的电化学性能

吴厚燃¹^,², 段体岗²(

), 马力², 邵刚勤¹(

), 张恒宇², 张海兵²

^1.武汉理工大学材料复合新技术国家重点实验室武汉 430070
^2.洛阳船舶材料研究所海洋腐蚀与防护全国重点实验室青岛 266237

Electrochemical Performance of Al-Zn-In-Mg-Ga-Mn Alloys as Anodes for Al-Air Batteries

WU Houran¹^,², DUAN Tigang²(

), MA Li², SHAO Gangqin¹(

), ZHANG Hengyu², ZHANG Haibing²

^1.State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China
^2.National State Key Laboratory for Marine Corrision and Protection, Luoyang Ship Material Research Institute, Qingdao 266237, China

引用本文:

吴厚燃, 段体岗, 马力, 邵刚勤, 张恒宇, 张海兵. 铝空气电池Al-Zn-In-Mg-Ga-Mn合金阳极的电化学性能[J]. 材料研究学报, 2024, 38(4): 257-268.
Houran WU, Tigang DUAN, Li MA, Gangqin SHAO, Hengyu ZHANG, Haibing ZHANG. Electrochemical Performance of Al-Zn-In-Mg-Ga-Mn Alloys as Anodes for Al-Air Batteries[J]. Chinese Journal of Materials Research, 2024, 38(4): 257-268.

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摘要:

研究了铝空气电池的Al-Zn-In-Mg-Ga-Mn合金阳极在2 mol/L NaCl和4 mol/L KOH电解液中的自腐蚀行为和电化学性能。结果表明，在2 mol/L的NaCl和4 mol/L的KOH溶液中，Al-Zn-In-Mg-Ga-Mn合金阳极比纯Al阳极的腐蚀电位(E_corr)分别负移了0.041和0.018 V，自腐蚀速率分别降低了0.2146和15.1 mg·cm^-2·h^-1，使金属阳极的电化学活性得以提高，自腐蚀行为受到了抑制。在2 mol/L的NaCl电解液中，合金阳极的放电容量峰值达到2608.96 Ah·kg^-1，比纯Al阳极提高了55.59%；能量密度最高为1742.61 Wh·kg^-1，比纯Al阳极提高了274.58%，阳极效率为87.55%。在4 mol/L的KOH电解液中，合金阳极的放电容量最高为1605.15 Ah·kg^-1，比纯Al阳极提高了131.27%；能量密度最高为1404.83 Wh·kg^-1，比纯Al阳极提高了231.52%，阳极效率为53.86%。

关键词 ：金属材料, Al-Zn-In-Mg-Ga-Mn合金, 铝空气电池, 电化学性能, 腐蚀行为

Abstract：

The free corrosion behavior and electrochemical properties of Al-Zn-In-Mg-Ga-Mn alloys, as anodes working with 2 mol/L NaCl and 4 mol/L KOH electrolytes were studied. Results revealed that in the two electrolytes, the corrosion potential (E_corr) of alloy anodes shifted negatively by 0.041 V and 0.018 V, and the free corrosion rates decreased by 0.2146 and 15.1 mg·cm^-2·h^-1, respectively in the contrast to those of pure Al anode. The electrochemical activity of pure Al anode was improved, while its free corrosion behavior was inhibited. In the 2 mol/L NaCl electrolyte, the discharge capacity peak of the alloy anode reached 2608.96 Ah·kg^-1, which was 55.59% higher than that of the pure Al anode. The highest energy density attained 1742.61 Wh·kg^-1, being 274.58% superior to that of the pure Al anode. The anode efficiency was 87.55%. In the 4 mol/L KOH electrolyte, the highest discharge capacity of the Al-Zn-In-Mg-Ga-Mn alloy anode was 1605.15 Ah·kg^-1, which was 131.27% higher than that of the pure Al anode. The highest energy density was 1404.83 Wh·kg^-1, which was 231.52% higher than that of the pure Al anode. The anode efficiency was 53.86%.

Key words： metallic materials Al-Zn-In-Mg-Ga-Mn alloy aluminum-air battery electrochemical performance corrosion behavior

收稿日期: 2023-05-08

ZTFLH:

TQ152

基金资助:国家重点研发计划(2022YFB3808800)

通讯作者: 段体岗，高级工程师，duantigang@sunrui.net，研究方向为海洋腐蚀与防护、化学能源;
邵刚勤，研究员，gqshao@whut.edu.cn，研究方向为新能源材料、无机新材料结构构建与解析

作者简介: 吴厚燃，男，1999年生，硕士生

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https://www.cjmr.org/CN/10.11901/1005.3093.2023.256 或 https://www.cjmr.org/CN/Y2024/V38/I4/257

图1 电池放电特性测试系统示意图

图2 纯Al和Al-Zn-In-Mg-Ga-Mn合金的XRD谱、晶粒尺寸分布和晶粒特征图

图3 纯Al及Al-Zn-In-Mg-Ga-Mn合金阳极的自腐蚀速率和平均腐蚀深度柱状图

表1 纯Al和Al-Zn-In-Mg-Ga-Mn合金阳极的自腐蚀参数

图4 纯Al及Al-Zn-In-Mg-Ga-Mn合金阳极的自腐蚀产物形貌及表面形貌

图5 纯Al及Al-Zn-In-Mg-Ga-Mn合金阳极的开路电位

图6 纯Al及Al-Zn-In-Mg-Ga-Mn合金阳极的动电位极化曲线

表2 纯Al和Al-Zn-In-Mg-Ga-Mn合金阳极的腐蚀参数

图7 纯Al及Al-Zn-In-Mg-Ga-Mn合金阳极的Nyquist和Bode图

表3 拟合的EIS参数

图8 纯Al及Al-Zn-In-Mg-Ga-Mn合金阳极的电压-时间曲线

图9 纯Al及Al-Zn-In-Mg-Ga-Mn合金阳极放电特性和阳极效率

表4 近年来关于Al-Zn-In及Al-Zn-In基合金阳极的相关铝空气电池性能的研究

图10 纯Al和Al-Zn-In-Mg-Ga-Mn合金阳极放电3 h后的腐蚀形貌和成分分布图

图11 纯Al和Al-Zn-In-Mg-Ga-Mn合金阳极放电3 h后的表面形貌

图12 铝空气电池放电示意图

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