<strong>S/NiFeP/KB</strong>复合材料锂硫电池正极的性能

doi:10.11901/1005.3093.2023.614

材料研究学报

2024, Vol. 38

Issue (11): 828-836 DOI: 10.11901/1005.3093.2023.614

研究论文

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S/NiFeP/KB复合材料锂硫电池正极的性能

武静, 张子怡, 韩旭, 侯星延, 李雪艳, 李莎莎, 刘雯, 李鹏(

)

太原科技大学化学工程与技术学院太原 030024

Preparation and Performance of S/NiFeP/KB Composites Electrocatalyst for Lithium Sulfur Batteries

WU Jing, ZHANG Ziyi, HAN Xu, HOU Xingyan, LI Xueyan, LI Shasha, LIU Wen, LI Peng(

)

Taiyuan University of Science and Technology, College of Engineering and Technology, Taiyuan 030024, China

引用本文:

武静, 张子怡, 韩旭, 侯星延, 李雪艳, 李莎莎, 刘雯, 李鹏. S/NiFeP/KB复合材料锂硫电池正极的性能[J]. 材料研究学报, 2024, 38(11): 828-836.
Jing WU, Ziyi ZHANG, Xu HAN, Xingyan HOU, Xueyan LI, Shasha LI, Wen LIU, Peng LI. Preparation and Performance of S/NiFeP/KB Composites Electrocatalyst for Lithium Sulfur Batteries[J]. Chinese Journal of Materials Research, 2024, 38(11): 828-836.

全文: PDF(8910 KB) HTML

摘要:

将2D纳米片NiFeP生长在Ketjen Black ECP-600JD炭黑(KB)上制备出花球颗粒状NiFeP/KB电催化剂，再将其与纳米硫颗粒按适当比例均匀混合制备出锂硫电池的正极。这种S/NiFeP/KB正极在0.1C下首次放电比容量为1454.5 mAh/g，循环200次后仍有821.1 mAh/g，在2C下300次循环后比容量为639.9 mAh/g，容量保持率达74.7%；使用NiFeP/KB电催化剂能提高电池中多硫化锂的氧化、还原反应速率，从而改善锂、硫反应动力学。

关键词 ：复合材料, 锂硫电池, 双金属磷化物, NiFeP, 纳米硫颗粒, 电催化剂

Abstract：

Transition metal phosphide has not only metal-like conductive properties but good adsorption and catalytic conversion of polysulfide lithium. In this paper, the NiFeP/KB electrocatalyst grown by 2D nanosheet NiFeP on Ketjen Black ECP-600JD carbon black (KB) was prepared. The S/NiFeP/KB cathode material was obtained by mixing the nano sulfur particles with NiFeP/KB in a proportional and uniform way. Due to the synergistic effect of metal doping and hierarchical structure, the electrode prepared using S/NiFeP/KB material had a specific capacity of 1454.5 mAh/g at 0.1C for the first discharge, which remained 821.1 mAh/g after 200 cycles, 639.9 mAh/g after 300 cycles at 2C, and the capacity retention rate reached 74.7%. Further combined with CV and EIS tests, the NiFeP/KB electrocatalyst can effectively improve the oxidation and reduction reaction rate of lithium polysulfide in the battery, thus promoting the reaction kinetics of lithium and sulfur.

Key words： composite lithium-sulfur battery bimetallic phosphide NiFeP Nano-sulfur particles electrocatalyst

收稿日期: 2023-12-27

ZTFLH:

TM911

基金资助:国家自然科学基金(22278251);大学生创新创业训练计划(202210109013)

通讯作者: 李鹏，lipeng_ty@tyust.edu.cn，研究方向为锂硫电池

Corresponding author: LI Peng, Tel: 13466816621, E-mail: lipeng_ty@tyust.edu.cn

作者简介: 武静，女，1998年生，硕士生

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https://www.cjmr.org/CN/10.11901/1005.3093.2023.614 或 https://www.cjmr.org/CN/Y2024/V38/I11/828

图1 NiFeP/KB复合材料合成示意图、NiFe-LDH和NiFeP的SEM照片、NiFe-LDH及NiFeP/KB的高倍SEM照片

图2 纳米硫颗粒的高倍SEM照片和S/NiFeP/KB复合材料的SEM照片

图3 NiFe-LDH/KB和NiFeP/KB的XRD谱

图4 NiFeP/KB的XPS全谱、Ni 2p和Fe 2p的精细能谱以及P 2p的轨道谱

图5 NiFeP/KB和NiFeP/KB/S的氮气吸附-脱附等温曲线和孔径分布图以及 S/NiFeP/KB和S/KB的TGA曲线

图6 S/NiFeP/KB和S/KB电极在0.1C下的循环性能、S/NiFeP/KB和S/KB电极的倍率性能、S/NiFeP/KB电极的首圈充放电曲线以及S/NiFeP/KB电极在2C下的循环性能

图7 S/NiFeP/KB和S/KB电极在0.1 mV/s下的CV曲线、S/NiFeP/KB电极在0.1 mV/s下循环4圈的CV曲线以及S/NiFeP/KB和S/KB电极的电化学阻抗谱

图8 S/NiFeP/KB电极和S/KB电极在不同扫速下的CV曲线以及S/NiFeP/KB和S/KB电极峰值电流的线性拟合

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