<strong>Mo-Fe</strong>基非晶合金丝材对偶氮染料的降解性能

doi:10.11901/1005.3093.2024.176

材料研究学报

2024, Vol. 38

Issue (11): 837-848 DOI: 10.11901/1005.3093.2024.176

研究论文

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Mo-Fe基非晶合金丝材对偶氮染料的降解性能

贺旺, 陈亚楠, 唐梅芳, 高文郡, 苏辰, 郭胜锋(

)

西南大学材料与能源学院重庆 400715

Research on the Degradation Performance of Azo Dyes for MoFe-based Amorphous Alloy Wires

HE Wang, CHEN Yanan, TANG Meifang, GAO Wenjun, SU Chen, GUO Shengfeng(

)

School of Materials and Energy, Southwest University, Chongqing 400715, China

引用本文:

贺旺, 陈亚楠, 唐梅芳, 高文郡, 苏辰, 郭胜锋. Mo-Fe基非晶合金丝材对偶氮染料的降解性能[J]. 材料研究学报, 2024, 38(11): 837-848.
Wang HE, Yanan CHEN, Meifang TANG, Wenjun GAO, Chen SU, Shengfeng GUO. Research on the Degradation Performance of Azo Dyes for MoFe-based Amorphous Alloy Wires[J]. Chinese Journal of Materials Research, 2024, 38(11): 837-848.

全文: PDF(14664 KB) HTML

摘要:

用熔融纺丝法制备Mo-Fe基(Mo₅₁Co₁₇Fe₁₇B₁₅和Mo₅₁Fe₃₄B₁₅)非晶合金丝材，研究了这两种非晶丝材对结晶紫溶液的降解性能及其机理。结果表明，Mo₅₁Co₁₇Fe₁₇B₁₅和Mo₅₁Fe₃₄B₁₅非晶合金丝材能彻底降解pH值为2~9的结晶紫溶液。Mo₅₁Fe₃₄B₁₅的降解效率比Mo₅₁Co₁₇Fe₁₇B₁₅的高，为了达到相同的降解效率前者所需时间为后者的二分之一。与Mo₅₁Co₁₇Fe₁₇B₁₅丝材相比，Mo₅₁Fe₃₄B₁₅非晶合金丝材的自腐蚀电位较高、腐蚀电流密度较低。这两种丝材优异的耐腐蚀性能和表面较高的Fe²⁺含量，有利于为催化降解提供大量的电子转移基础，适宜的耐腐蚀性能和较高的电子转移性能是其具有优异降解性能的关键原因。

关键词 ：金属材料, 钼基非晶合金, 非晶丝材, 染料废水, 催化降解

Abstract：

Mo-based amorphous alloys show excellent degradation performance and thermal stability in the field of dye wastewater degradation, and have efficient catalytic reactivity over a wide pH range. This paper successfully prepared novel MoFe-based (Mo₅₁Co₁₇Fe₁₇B₁₅and Mo₅₁Fe₃₄B₁₅) amorphous alloy wires using the melt-spinning method. This further enhanced the catalytic activity of Mo-based amorphous alloys in extremely acidic media, and investigated the degradation performance of the two amorphous wire materials towards crystal violet solution and its reaction mechanism. The results show that Mo₅₁Co₁₇Fe₁₇B₁₅and Mo₅₁Fe₃₄B₁₅ amorphous alloy wires can completely degrade crystal violet solution with pH 2~9. The degradation efficiency of Mo₅₁Fe₃₄B₁₅ is higher than that of Mo₅₁Co₁₇Fe₁₇B₁₅, and the time required for the former to reach the same degradation degree is only 1/2 of the latter. In addition, the Mo₅₁Fe₃₄B₁₅ amorphous alloy wires have a higher self-corrosion potential and lower corrosion current density, superior corrosion resistance and a higher surface Fe²⁺ content, which is conducive to providing a large number of electron transfer basis for the catalytic degradation process. The suitable corrosion behavior and faster electron transfer ability are the key reasons for its superior degradation performance.

Key words： metallic materials Mo-based amorphous alloy amorphous alloy wires dye wastewater catalytic degradation

收稿日期: 2024-04-17

ZTFLH:

TQ426.83

基金资助:国家自然科学基金(52071276);中央高校基本科研业务费专项基金(SWU-XDJH202313)

通讯作者: 郭胜锋，教授，sfguo@swu.edu.cn，研究方向为非晶合金、高熵合金以及生物医用金属

Corresponding author: GUO Shengfeng, Tel: 13500330725, E-mail: sfguo@swu.edu.cn

作者简介: 贺旺，女，1995年生，硕士

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https://www.cjmr.org/CN/10.11901/1005.3093.2024.176 或 https://www.cjmr.org/CN/Y2024/V38/I11/837

图1 Mo51Co17Fe17B15和Mo51Fe34B15非晶合金丝材的XRD谱和DSC曲线

图2 Mo51Co17Fe17B15和Mo51Fe34B15非晶合金丝材降解结晶紫溶液的紫外-可见吸收光谱

图3 Mo51Co17Fe17B15和Mo51Fe34B15非晶合金丝材降解不同pH值的结晶紫溶液的归一化浓度变化(室温，20 × 10-6结晶紫溶液，0.1 mol/L H2O2)以及不同非晶合金催化剂用于降解偶氮染料废水适用的pH值和反应速率常数kobs[24~30]

图4 Mo51Co17Fe17B15和Mo51Fe34B15非晶合金丝材在不同温度下降解结晶紫溶液的归一化浓度变化；反应速率常数kobs以及反应活化能Ea (pH = 2，20 × 10-6结晶紫溶液，0.1 mol/L H2O2)

图5 Mo51Co17Fe17B15和 Mo51Fe34B15非晶合金丝材不同H2O2添加量降解结晶紫溶液的归一化浓度变化和反应速率常数kobs (303 K，pH = 2，20 × 10-6结晶紫溶液)

图6 Mo51Co17Fe17B15和 Mo51Fe34B15非晶合金丝材降解不同初始浓度结晶紫溶液的归一化浓度变化以及反应速率常数kobs和降解效率(η = (1-Ct/C0) × 100%) (313 K，pH = 2，0.1 mol/L H2O2)

图7 Mo51Co17Fe17B15和Mo51Fe34B15非晶合金丝材的循环稳定性

图8 Mo51Co17Fe17B15和Mo51Fe34B15非晶合金在结晶紫溶液中的极化曲线和奈奎斯特图

图9 Mo51Co17Fe17B15和Mo51Fe34B15非晶合金丝材降解偶氮染料废水前后的表面形貌

图10 Mo51Co17Fe17B15和Mo51Fe34B15非晶合金丝材降解染料废水后的表面EDS能谱

图11 Mo51Co17Fe17B15和Mo51Fe34B15降解偶氮染料废水后非晶合金丝材表面的XPS谱

图12 Mo51Co17Fe17B15和Mo51Fe34B15非晶合金丝材降解结晶紫染料废水的机理示意图

1	Selvaraj V, Swarna Karthika T, Mansiya C, et al. An over review on recently developed techniques, mechanisms and intermediate involved in the advanced azo dye degradation for industrial applications [J]. J. Mol. Struct., 2021, 1224: 129195
2	Zhang C J, Chen H, Xue G, et al. A critical review of the aniline transformation fate in azo dye wastewater treatment [J]. J. Clean. Prod., 2021, 321: 128971
3	Wang Y, Zhang H, Chang N, et al. Preparation of acid-alkali modified coal fly ash adsorbent and its removal performance on dyes [J]. Chin. J. Mater. Res., 2023, 38(5): 379
3	王琰, 张昊, 常娜等. 酸-碱改性粉煤灰吸附剂的制备及其对染料的去除性能 [J]. 材料研究学报, 2023, 38(5): 379
4	Yu M X, Kuai L, Wang L, et al. Synthesis of N-doped hierarchical porous carbon and its adsorption capacity for acid orange 74 [J]. Chin. J. Mater. Res., 2021, 35(9): 667 doi: 10.11901/1005.3093.2020.427
4	余谟鑫, 蒯乐, 王亮等. 吲哚基掺氮分级多孔炭的制备及其对酸性橙74的吸附性能 [J]. 材料研究学报, 2021, 35(9): 667 doi: 10.11901/1005.3093.2020.427
5	Zhang H, Li F, Chang N, et al. Preparation of carboxylic acid grafted starch adsorption resin and its dye removal performance [J]. Chin. J. Mater. Res., 2021, 35(6): 419 doi: 10.11901/1005.3093.2020.279
5	张昊, 李帆, 常娜等. 羧酸型接枝淀粉吸附树脂的制备和对染料的去除性能 [J]. 材料研究学报, 2021, 35(6): 419
6	Zhang X Y, Zhang Q Y, Tang T, et al. Fabrication of composite material based on MOFs and its adsorption properties for methylene blue dyes [J]. Chin. J. Mater. Res., 2021, 35(11): 866 doi: 10.11901/1005.3093.2021.002
6	张向阳, 章奇羊, 汤涛等. 基于MOFs的复合材料制备及其对亚甲基蓝染料的吸附性能 [J]. 材料研究学报, 2021, 35(11): 866 doi: 10.11901/1005.3093.2021.002
7	Zhang L C, Jia Z, Lyu F, et al. A review of catalytic performance of metallic glasses in wastewater treatment: Recent progress and prospects [J]. Prog. Mater. Sci., 2019, 105: 100576
8	Pei L F, Zhang X Y, Yuan Z Z. Application of Fe-based amorphous alloy in industrial wastewater treatment: a review [J]. J. Renew. Mater., 2022, 10(4): 969
9	Wang J Q, Liu Y H, Chen M W, et al. Rapid degradation of azo dye by Fe-based metallic glass powder [J]. Adv. Funct. Mater., 2012, 22(12): 2567
10	Xie S H, Xie Y L, Kruzic J J, et al. The pivotal role of boron in improving the azo dye degradation of glassy Fe-based catalysts [J]. ChemCatChem, 2020, 12(3): 750
11	Wang R W, Liu J, Gan Z H, et al. Crystallization kinetics of amorphous alloys Fe_73.5Si_13.5- _x Ge _x B₉Cu₁Nb₃ (x = 3, 6) [J]. Chin. J. Mater. Res., 2014, 28(3): 204
11	汪汝武, 刘静, 甘章华等. Fe_73.5Si_13.5- _x Ge _x B₉Cu₁Nb₃ (x = 3, 6)非晶合金的结晶动力学 [J]. 材料研究学报, 2014, 28(3): 204 doi: 10.11901/1005.3093.2013.603
12	Wang J M, Hu Q, Yang Y H, et al. Influence of Co and Ni on invar effect of (Fe_71.2B₂₄Y_4.8)₉₆Nb₄ bulk metallic glass [J]. Chin. J. Mater. Res., 2018, 32(9): 691
12	王金苗, 胡强, 严意宏等. Co和Ni对(Fe_71.2B₂₄Y_4.8)₉₆Nb₄块体非晶合金因瓦效应的影响 [J]. 材料研究学报, 2018, 32(9): 691 doi: 10.11901/1005.3093.2018.115
13	Chen F, Zhou Y, Chen Y N, et al. Fabrication of nano-porous Co by dealloying for supercapacitor and azo-dye degradation [J]. Chin. J. Mater. Res., 2020, 34(12): 905 doi: 10.11901/1005.3093.2020.443
13	陈峰, 周洋, 陈彦南等. 脱合金制备纳米多孔Co及其超级电容器和对偶氮染料的降解性能 [J]. 材料研究学报, 2020, 34(12):905
14	Shen Y L, Li B G. Preparation of magnetic amino acid-functionalized aluminum alginate gel polymer and its super adsorption on azo dyes [J]. Chin. J. Mater. Res., 2022, 36(3): 220 doi: 10.11901/1005.3093.2021.163
14	申延龙, 李北罡. 磁性氨基酸功能化海藻酸铝凝胶聚合物的制备及对偶氮染料的超强吸附 [J]. 材料研究学报, 2022, 36(3):220 doi: 10.11901/1005.3093.2021.163
15	Shi J L, Sheng M Q, Wu Q, et al. Preparation of electrode materials of amorphous Co-W-B/Carbon cloth composite and their electro-catalytic performance for electrolysis of water [J]. Chin. J. Mater. Res., 2020, 34(4): 263 doi: 10.11901/1005.3093.2019.397
15	施嘉伦, 盛敏奇, 吴琼等. 非晶Co-W-B/碳布复合电极材料的制备及其电解水催化性能 [J]. 材料研究学报, 2020, 34(4): 263 doi: 10.11901/1005.3093.2019.397
16	Zhang Z L, Wang S Q, Xu B L, et al. Electrocatalytic oxygen evolution performance of high entropy FeCoNiMoCr alloy thin film electrode [J]. Chin. J. Mater. Res., 2021, 35(3): 193 doi: 10.11901/1005.3093.2020.233
16	张泽灵, 王世琦, 徐邦利等. FeCoNiMoCr高熵合金薄膜电极的电催化析氧性能 [J]. 材料研究学报, 2021, 35(3): 193 doi: 10.11901/1005.3093.2020.233
17	Wang J Q, Liu Y H, Chen M W, et al. Excellent capability in degrading azo dyes by MgZn-based metallic glass powders [J]. Sci. Rep., 2012, 2(1): 418
18	Jia Z, Kang J, Zhang W C, et al. Surface aging behaviour of Fe-based amorphous alloys as catalysts during heterogeneous photo Fenton-like process for water treatment [J]. Appl. Catal. B Environ., 2017, 204: 537
19	Tang M F, Lai L M, Ding D Y, et al. Rapid degradation of direct blue dye by Co-based amorphous alloy wire [J]. J. Non-Cryst. Solids, 2022, 576: 121282
20	Tang M F, Lai L M, Su C, et al. MoCoB metallic glass microwire catalysts for highly efficient and pH-universal degradation of wastewater [J]. npj Mater. Degrad., 2023, 7(1): 73
21	Lin B, Bian X F, Wang P, et al. Application of Fe-based metallic glasses in wastewater treatment [J]. Mater. Sci. Eng. B, 2012, 177(1): 92
22	Zhang C Q, Zhang H F, Lv M Q, et al. Decolorization of azo dye solution by Fe-Mo-Si-B amorphous alloy [J]. J. Non-Cryst. Solids, 2010, 356(33-34): 1703
23	Wang X F, Pan Y, Zhu Z R, et al. Efficient degradation of rhodamine B using Fe-based metallic glass catalyst by Fenton-like process [J]. Chemosphere, 2014, 117: 638 pmid: 25461929
24	Chen S Q, Yang G N, Luo S T, et al. Unexpected high performance of Fe-based nanocrystallized ribbons for azo dye decomposi-tion [J]. J. Mater. Chem. A, 2017, 5(27): 14230
25	Deng Z, Zhang C, Liu L. Chemically dealloyed MgCuGd metallic glass with enhanced catalytic activity in degradation of phenol [J]. Intermetallics, 2014, 52: 9
26	Hou L, Wang Q Q, Fan X D, et al. Effect of Co addition on catalytic activity of FePCCu amorphous alloy for methylene blue degradation [J]. New J. Chem., 2019, 43(16): 6126
27	Li Z K, Qin X D, Zhu Z W, et al. Cu-based metallic glass with robust activity and sustainability for wastewater treatment [J]. J. Mater. Chem. A, 2020, 8(21): 10855
28	Turnbull D. Under what conditions can a glass be formed? [J]. Contemp. Phys., 1969, 10(5): 473
29	Wang P, Bian X F, Li Y X. Catalytic oxidation of phenol in wastewater — A new application of the amorphous Fe₇₈Si₉B₁₃ alloy [J]. Chin. Sci. Bull., 2012, 57(1): 33
30	Zhao B W, Zhu Z W, Qin X D, et al. Highly efficient and stable CuZr-based metallic glassy catalysts for azo dye degradation [J]. J. Mater. Sci. Technol., 2020, 46: 88 doi: 10.1016/j.jmst.2019.12.012
31	Zhang C Q, Zhang H F, Lv M Q, et al. Decolorization of azo dye solution by Fe-Mo-Si-B amorphous alloy [J]. J. Non-Cryst. Solids, 2010, 356(33-34): 1703
32	Zhang C Q, Zhu Z W, Zhang H F. Effects of the addition of Co, Ni or Cr on the decolorization properties of Fe-Si-B amorphous all-oys [J]. J. Phys. Chem. Solids, 2017, 110: 152
33	Yang C, Zhang C, Chen Z J, et al. Three-dimensional hierarchical porous structures of metallic glass/copper composite catalysts by 3D printing for efficient wastewater treatments [J]. ACS Appl. Mater. Interfaces, 2021, 13(6): 7227

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