Please wait a minute...
Chin J Mater Res  2009, Vol. 23 Issue (4): 410-414    DOI:
论文 Current Issue | Archive | Adv Search |
High–temperature thermal stability research on SiC thin films by magnetron sputtering
ZHU Yuankun1;   ZHU Jiaqi1;   HAN Jiecai1;   LIANG Jun1;   ZHANG Yuanchun2  
1.Center for Composite Materials; Harbin Institute of Technology; Harbin 150001
2.China Automobile Industry Engineering Cooperation; Tianjin  300190
Cite this article: 

ZHU Yuankun ZHU Jiaqi HAN Jiecai LIANG Jun ZHANG Yuanchun. High–temperature thermal stability research on SiC thin films by magnetron sputtering. Chin J Mater Res, 2009, 23(4): 410-414.

Download:  PDF(806KB) 
Export:  BibTeX | EndNote (RIS)      
Abstract  

SiC thin films were grown on Si substrates by magnetron sputtering. The structural and component changes of the films, pre and post high temperature annealing at different temperature and atmosphere conditions, were studied. The results show that the films are characterized by the amorphous microstructure and mainly composed of Si–C bondings, C–C bondings as well as a small mount of oxide impurity consorted with Si; the content of the C–C bondings decreased after annealing in vacuum, meanwhile the Si–C bondings content increased, annealing in vacuum is beneficial to the formation of SiC; after annealing at 800℃ in air, a thin dense layer of SiO2 formed on the surface, which prevented the oxygen from contacting with the film and effectively protected the inner SiC from oxidizing. SiC films have good thermal stability at 800℃ in air.

Key words:  inorganic non--metallic materials      magnetron sputtering      thermal stability      high--temperature annealing      SiC films     
Received:  05 December 2008     
ZTFLH: 

TB33

 
Fund: 

Supported by National High Technology Research and Development Program of China No.2006AA0764.

URL: 

https://www.cjmr.org/EN/     OR     https://www.cjmr.org/EN/Y2009/V23/I4/410

1 H.Morkoe, S.Strite, G.B.Gao, Large–band–gap SiC, III–V nitride, and II–VI ZnSe–based semiconductor device technologies, Journal Applied Physics, 76, 1363(1994) 2 ZHAO Juan, WANG Gui, LIU Lang, Oxidation protective behavior of SiC coating for different carbon matrix, Surface Technology, 36(2), 123(2007) (赵娟, 王贵, 刘朗, SiC涂层对不同碳基体氧化防护行为的研究, 表面技术,  36(2), 123(2007)) 3 S.Zaima, K.Onoda, Y.Koide, Y.Yasuda, Effects of oxidation conditions on electrical properties of SiC–SiO2 interfaces, J. Appl. Phys., 68, 6304(1999) 4 R.M.Todi, K.B.Sundaram, A.P.Warren, K.Scammon, Investigation of oxygen annealing effects on RF sputter deposited SiC thin films, Solid–State Electronics, 50, 1189(2006) 5 A.K.Costa, S.S.Camargo, Jr., Amorphous SiC coatings for WC cutting tools, Surface and Coatings Technology, 163, 176(2003) 6 M.Zaytouni, J.P.Riviere, M.F.Denanot, J.Allain, Structural characterization of SiC films prepared by dynamic ion mixing, Thin Solid Films, 287(1), 1(2006) 7 T.Kaneko, Y.Hosokawa, T.Suga, Low–temperature growth of polycrystalline SiC by catalytic CVD from monomethylsilane, Micr. Eng., (83), 41(2006) 8 Inacio Regiani, Milton F. de Souza, Silicon carbide coating of mullite substrates by the CVD technique, Surface and Coatings Technology, 162, 131(2003) 9 S.M.Rajab, I.C.Oliveira, M.Massi, H.S.Maciel, S.G.dos Santos Filho, R.D.Mansano, Effect of the thermal annealing on the electrical and physical properties of SiC thin films produced by RF magnetron sputtering, Thin Solid Films, 515(1), 170 (2006) 10 Sergei A. Alekseev, Vladimir N. ZaitsevJacques Botsoa, Daniel Barbier, Fourier transform infrared spectroscopy and temperature–programmed desorption mass spectrometry study of surface chemistry of porous 6H–SiC, Chem. Mater., 19(9), 2189(2007) 11 Bibhu P. Swain, The analysis of carbon bonding environment in HWCVD deposited a–SiC:H films by XPS and Raman spectroscopy, Surface & Coatings Technology, 201, 1589(2006) 12 M.Mehregany, C.A.Zorman, SiC MEMS: opportunities and challenges for applications in harsh environments, Thin Solid Films, 355–356, 518(1999) 13 Yi Jian, He Xiaodong, Sun Yue, Electron beam–physical vapor deposition of SiC/SiO2 high emissivity thin film, Applied Surface Science, 253, 4361(2007) 14 G.Neuer, G.Jaroma–Weiland, Spectral and total emissivity of high–temperature materials, International Journal of Thermophysics, 19(3), 917(1998)
[1] JIANG Shuimiao, MING Kaisheng, ZHENG Shijian. A Review on Grain Boundary Segregation, Interfacial Phase and Mechanical Property Adjusting-controlling for Nanocrystalline Materials[J]. 材料研究学报, 2023, 37(5): 321-331.
[2] YAN Chunliang, GUO Peng, ZHOU Jingyuan, WANG Aiying. Electrical Properties and Carrier Transport Behavior of Cu Doped Amorphous Carbon Films[J]. 材料研究学报, 2023, 37(10): 747-758.
[3] SHAN Weiyao, WANG Yongli, LI Jing, XIONG Liangyin, DU Xiaoming, LIU Shi. High Temperature Oxidation Resistance of Cr Based Coating on Zirconium Alloy[J]. 材料研究学报, 2022, 36(9): 699-705.
[4] ZHANG Peng, HUANG Dong, ZHANG Fuquan, YE Chong, WU Xiao, WU Huang. Effect of Graphitization Degree of Mesophase Pitch-based Carbon Fibers on Carbon Fiber/Al Interface Damage[J]. 材料研究学报, 2022, 36(8): 579-590.
[5] MENG Xiangdong, ZHEN Chao, LIU Gang, CHENG Huiming. Controlled Synthesis of CuO Nanoarrays as Efficient Photocathodes for Photoelectrochemical (PEC) for Water Splitting[J]. 材料研究学报, 2022, 36(4): 241-249.
[6] YANG Yana, CHEN Wenge, XUE Yuanlin. Interficial Bonding within Cu-based Composites Reinforced with TiC- or Ni-coated Carbon Fiber[J]. 材料研究学报, 2021, 35(6): 467-473.
[7] ZHANG Zeling, WANG Shiqi, XU Bangli, ZHAO Yuhao, ZHANG Xuhai, FANG Feng. Electrocatalytic Oxygen Evolution Performance of High Entropy FeCoNiMoCr Alloy Thin Film Electrode[J]. 材料研究学报, 2021, 35(3): 193-200.
[8] SONG Guihong, LI Xiuyu, LI Guipeng, DU Hao, HU Fang. Thermoelectric Properties of Mg-rich Mg3Bi2 Films Prepared by Magnetron Sputtering[J]. 材料研究学报, 2021, 35(11): 835-842.
[9] XU Chunping, CHEN chunyue, ZHANG yonghang, Gong wei, BAN daming. Flame Retard Modification of Vinyl Ester Resin with Phosphorous Polymer Type Flame Retardant[J]. 材料研究学报, 2021, 35(11): 843-849.
[10] XIE Mingling, ZHANG Guang'an, SHI Xing, TAN Xi, GAO Xiaoping, SONG Yuzhe. Anti-oxidization and Electronic Properties of Ti Doped MoS2 Films[J]. 材料研究学报, 2021, 35(1): 59-64.
[11] TAN Xi, SONG Yuzhe, SHI Xin, QIANG Jin, WEI Tingxuan, LU Qihai. Magnetization Reversal Field and Magneto-Resistor of Spin Valve[J]. 材料研究学报, 2020, 34(4): 272-276.
[12] WANG Shiqi,HUO Wenyi,XU Zhengchao,ZHANG Xuhai,ZHOU Xuefeng,FANG Feng. Fabrication of Films of Co Doped TiO2 Nanotube Array and their Photocatalytic Reduction Performance[J]. 材料研究学报, 2020, 34(3): 176-182.
[13] DING Renhao, CAO Dan, XU Lu, WANG Ziqiang, LI Jianxi, MA Hongjuan. Effect of Electron-beam Radiation on Properties of Oriented Poly (ether-ether-ketone)[J]. 材料研究学报, 2020, 34(11): 822-828.
[14] SHI Congyun,WANG Jinfeng,CHEN Hongxiang,YANG Xumeng,DU Changjun,LI Guangyao,LIU Peng,CAI Haohao. Preparation and Properties of Epoxy Resin Composites Incorporated with Optical Fiber Preform Waste[J]. 材料研究学报, 2020, 34(1): 57-63.
[15] Fanfan FENG,Huibin WU,Xinpan YU. Thermal Stability of Nanoscale Bainite/Martensite Steel[J]. 材料研究学报, 2019, 33(8): 597-602.
No Suggested Reading articles found!