Microstructure and Property of Ti / Steel Composite Pipe Prepared by Hot Extrusion

doi:10.11901/1005.3093.2022.482

Chinese Journal of Materials Research

2023, Vol. 37

Issue (9): 713-720 DOI: 10.11901/1005.3093.2022.482

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Microstructure and Property of Ti / Steel Composite Pipe Prepared by Hot Extrusion

PAN Xinyuan, JIANG Jin, REN Yunfei, LIU Li, LI Jinghui, ZHANG Mingya(

)

School of Metallurgical Engineering, Anhui University of Technology, Ma'anshan 243002, China

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PAN Xinyuan, JIANG Jin, REN Yunfei, LIU Li, LI Jinghui, ZHANG Mingya. Microstructure and Property of Ti / Steel Composite Pipe Prepared by Hot Extrusion. Chinese Journal of Materials Research, 2023, 37(9): 713-720.

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Abstract

The titanium/steel composite pipe was prepared by hot extrusion at 1000℃ with low carbon steel Q235 as inner pipe and commercial pure titanium TA2 as cladding. The effect of interface microstructure on mechanical properties of titanium/steel composite pipe was studied by using metallographic microscope, field emission scanning electron microscope, X-ray diffractometer, microhardness tester and nano-indentation technology. The results show that the outer diameter of the extruded titanium/steel composite pipe is 22 mm, the inner and outer wall thicknesses are 3 mm and 0.2 mm respectively, the interface of steel/Ti pipes is well bonded, and the main phase of the interface is α-Fe, α-Ti, TiC and Fe₂Ti, etc. The grain at the interface junction of the hot extruded Ti clad steel pipe is obviously refined, and the average grain size of the interface is 1.5 μm. The grain refinement of the Ti side of the composite is higher than that of the steel side. At the same time, under high temperature hot extrusion, the dislocation density at the bonding interface of the clad pipe increases, the grains are refined, and the microhardness is also improved. Low temperature annealing has different effects on the mechanical properties of both sides of titanium/steel composite interface, weakens the work hardening degree of titanium/steel composite pipe, improves the stiffness of interface material, and has little effect on the reaction layer formed by interface intermetallic compound.

Key words: composite hot extrusion titanium/steel composite pipe microstructure mechanical property

Received: 07 September 2022

ZTFLH:

TG376.2

Fund: Anhui Province Key Laboratory of Metallurgical Engineering & Resource Recycling(SKF22-04);Natural Science Foundation Project of Colleges and Universities in Anhui Province(KJ2020A0272)

Corresponding Authors: ZHANG Mingya, Tel: 18855579770, E-mail: ahutzmh@163.com

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	PAN Xinyuan
	JIANG Jin
	REN Yunfei
	LIU Li
	LI Jinghui
	ZHANG Mingya

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https://www.cjmr.org/EN/10.11901/1005.3093.2022.482 OR https://www.cjmr.org/EN/Y2023/V37/I9/713

Table 1 Chemical composition of TA2 and Q235 (mass fraction,%)

Fig.1 Photo of original structure of steel/titanium pipe

Fig.2 Process flow chart of hot extrusion titanium / steel composite pipe

Fig.3 EBSD image of titanium / steel interface structure (a) IPF diagram; (b) grain boundary diagram; (c) image quality (IQ) diagram; (d) distribution of grain size at interface

Fig.4 SEM image and EDS energy spectrum of extruded titanium/steel composite pipe interface (a) interface morphology; (b) Fe surface scan; (c) Ti surface scan, (d) C surface scan; (e) EDS point scan results

Fig.5 XRD of titanium / steel peeling interface (a) steel side; (b) titanium side

Fig.6 Hardness distribution of titanium/steel composite interface (a) and forming mechanism of interface reaction layer (b, c)

Fig.7 Combined with nanoindentation test of interface (a) metallographic diagram of indentation point: left extruded state, right annealed state; (b) comparison results of Young's modulus; (c) load displacement diagram in extrusion state; (d) load displacement diagram of annealed state

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